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HomeMy WebLinkAbout3M Desk & Office Cleaner 5733M(TM) DESK & OFFICE CLEANER 573 02/22/16 __________________________________________________________________________________________ Page 1 of 11 Safety Data Sheet Copyright,2016,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group:23-3022-3 Version Number:4.01 Issue Date:02/22/16 Supercedes Date: 07/28/14 SECTION 1: Identification 1.1. Product identifier 3M(TM) DESK & OFFICE CLEANER 573 Product Identification Numbers 70-0051-5274-2, 70-0714-9577-7 1.2. Recommended use and restrictions on use Recommended use Aerosol foam cleaner for office surfaces. 1.3. Supplier’s details MANUFACTURER: 3M DIVISION: Stationery and Office Supplies Division ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone:1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification 2.1. Hazard classification Flammable Aerosol: Category 2. Gas Under Pressure: Liquefied gas. Simple Asphyxiant. Specific Target Organ Toxicity (single exposure): Category 1. 2.2. Label elements Signal word Danger Symbols Flame | Gas cylinder | Health Hazard | Pictograms 3M(TM) DESK & OFFICE CLEANER 573 02/22/16 __________________________________________________________________________________________ Page 2 of 11 Hazard Statements Flammable aerosol. Contains gas under pressure; may explode if heated. May displace oxygen and cause rapid suffocation. Causes damage to organs: cardiovascular system | Precautionary Statements Prevention: Keep away from heat/sparks/open flames/hot surfaces. -No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Response: IF exposed: Call a POISON CENTER or doctor/physician. Specific treatment (see Notes to Physician on this label). Storage: Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store in a well-ventilated place. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. Notes to Physician: Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. 2.3. Hazards not otherwise classified May cause frostbite. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No.% by Wt WATER 7732-18-5 80 - 95 ISOBUTANE PROPELLANT 75-28-5 1 - 5 Trade Secret * ISOPROPYL ALCOHOL 67-63-0 3 - 5 Trade Secret * ETHOXYLATED ALCOHOLS 68439-46-3 1 - 3 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. 3M(TM) DESK & OFFICE CLEANER 573 02/22/16 __________________________________________________________________________________________ Page 3 of 11 SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. Get medical attention. Skin Contact: Thaw frosted skin with lukewarm water. Do not rub affected area. Get medical attention. Eye Contact: Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media Use a fire fighting agent suitable for the surrounding fire. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Hazardous Decomposition or By-Products Substance Condition Hydrocarbons During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. -No smoking. Use only non-sparking tools. Ventilate the area with fresh air. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up 3M(TM) DESK & OFFICE CLEANER 573 02/22/16 __________________________________________________________________________________________ Page 4 of 11 If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with detergent and water. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Do not use in a confined area with minimal air exchange. Keep away from heat/sparks/open flames/hot surfaces. -No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) 7.2. Conditions for safe storage including any incompatibilities Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store away from heat. Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No.Agency Limit type Additional Comments ISOPROPYL ALCOHOL 67-63-0 ACGIH TWA:200 ppm;STEL:400 ppm A4: Not class. as human carcin ISOPROPYL ALCOHOL 67-63-0 OSHA TWA:980 mg/m3(400 ppm) ISOBUTANE PROPELLANT 75-28-5 ACGIH STEL:1000 ppm ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor -Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Do not remain in area where available oxygen may be reduced. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Safety Glasses with side shields Skin/hand protection 3M(TM) DESK & OFFICE CLEANER 573 02/22/16 __________________________________________________________________________________________ Page 5 of 11 Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Butyl Rubber Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors Half facepiece or full facepiece supplied-air respirator Organic vapor respirators may have short service life. For questions about suitability for a specific application, consult with your respirator manufacturer. Thermal hazards Wear cold insulating gloves/face shield/eye protection. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Specific Physical Form: Foam Odor, Color, Grade: White foam, Clean/Fresh Scent Odor threshold No Data Available pH 11 -12 Melting point Not Applicable Boiling Point 10 -213 ºF Flash Point <=0 ºF [Details: Propellent] Evaporation rate >=1 [Ref Std: WATER=1] [Details: product as applied (without propellant)] Flammability (solid, gas)Not Applicable Flammable Limits(LEL)1.80 % Flammable Limits(UEL)12.7 % [Details: for propellent] Vapor Pressure 31 -43 psi [@ 70 ºF] [Details: (aerosol can pressure)] Vapor Density No Data Available Density 1 g/ml Specific Gravity Approximately 1 [Ref Std: WATER=1] Solubility In Water No Data Available Solubility-non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity Not Applicable Volatile Organic Compounds 5.77 % weight Percent volatile 96 -98 % weight VOC Less H2O & Exempt Solvents No Data Available SECTION 10: Stability and reactivity 10.1. Reactivity This material is considered to be non reactive under normal use conditions. 3M(TM) DESK & OFFICE CLEANER 573 02/22/16 __________________________________________________________________________________________ Page 6 of 11 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Heat Sparks and/or flames 10.5. Incompatible materials Not determined 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Intentional concentration and inhalation may be harmful or fatal. Simple Asphyxiation: Signs/symptoms may include increased heart rate, rapid respirations, drowsiness, headache, incoordination, altered judgement, nausea, vomiting, lethargy, seizures, coma, and may be fatal. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause additional health effects (see below). Skin Contact: Frostbite: Signs/symptoms may include intense pain, discoloration of skin, and tissue destruction. Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Eye Contact: Frostbite: Signs/symptoms may include intense pain, clouding of the cornea, redness, swelling, and blindness. 3M(TM) DESK & OFFICE CLEANER 573 02/22/16 __________________________________________________________________________________________ Page 7 of 11 Contact with the eyes during product use is not expected to result in significant irritation. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Additional Health Effects: Single exposure may cause target organ effects: Single exposure, above recommended guidelines, may cause: Cardiac Sensitization: Signs/symptoms may include irregular heartbeat (arrhythmia), faintness, chest pain, and may be fatal. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg ISOPROPYL ALCOHOL Dermal Rabbit LD50 12,870 mg/kg ISOPROPYL ALCOHOL Inhalation- Vapor (4 hours) Rat LC50 72.6 mg/l ISOPROPYL ALCOHOL Ingestion Rat LD50 4,710 mg/kg ISOBUTANE PROPELLANT Inhalation- Gas (4 hours) Rat LC50 276,000 ppm ETHOXYLATED ALCOHOLS Dermal Rabbit LD50 > 2,000 mg/kg ETHOXYLATED ALCOHOLS Ingestion Rat LD50 1,378 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value ISOPROPYL ALCOHOL Multiple animal species No significant irritation ISOBUTANE PROPELLANT Professio nal judgeme nt No significant irritation ETHOXYLATED ALCOHOLS Rabbit Irritant Serious Eye Damage/Irritation Name Species Value ISOPROPYL ALCOHOL Rabbit Severe irritant ISOBUTANE PROPELLANT Professio nal judgeme nt No significant irritation ETHOXYLATED ALCOHOLS Professio nal judgeme nt Corrosive Skin Sensitization Name Species Value ISOPROPYL ALCOHOL Guinea pig Not sensitizing ETHOXYLATED ALCOHOLS Guinea Not sensitizing 3M(TM) DESK & OFFICE CLEANER 573 02/22/16 __________________________________________________________________________________________ Page 8 of 11 pig Respiratory Sensitization For the component/components, either no data are currently available or the data are not sufficient for classification. Germ Cell Mutagenicity Name Route Value ISOPROPYL ALCOHOL In Vitro Not mutagenic ISOPROPYL ALCOHOL In vivo Not mutagenic ISOBUTANE PROPELLANT In Vitro Not mutagenic ETHOXYLATED ALCOHOLS In Vitro Not mutagenic Carcinogenicity Name Route Species Value ISOPROPYL ALCOHOL Inhalation Rat Some positive data exist, but the data are not sufficient for classification Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration ISOPROPYL ALCOHOL Ingestion Some positive developmental data exist, but the data are not sufficient for classification Rat NOAEL 400 mg/kg/day during organogenesi s ISOPROPYL ALCOHOL Inhalation Some positive developmental data exist, but the data are not sufficient for classification Rat LOAEL 9 mg/l during gestation ETHOXYLATED ALCOHOLS Dermal Not toxic to female reproduction Rat NOAEL 250 mg/kg/day 2 generation ETHOXYLATED ALCOHOLS Dermal Not toxic to development Rat NOAEL 250 mg/kg/day 2 generation ETHOXYLATED ALCOHOLS Dermal Some positive male reproductive data exist, but the data are not sufficient for classification Rat NOAEL 100 mg/kg/day 2 generation Target Organ(s) Specific Target Organ Toxicity -single exposure Name Route Target Organ(s)Value Species Test Result Exposure Duration ISOPROPYL ALCOHOL Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available ISOPROPYL ALCOHOL Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available ISOPROPYL ALCOHOL Inhalation auditory system Some positive data exist, but the data are not sufficient for classification Guinea pig NOAEL 13.4 mg/l 24 hours ISOPROPYL ALCOHOL Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available poisoning and/or abuse ISOBUTANE PROPELLANT Inhalation cardiac sensitization Causes damage to organs Multiple animal species NOAEL Not available ISOBUTANE PROPELLANT Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available ISOBUTANE PROPELLANT Inhalation respiratory irritation All data are negative Mouse NOAEL Not available ETHOXYLATED ALCOHOLS Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Not available NOAEL Not available not available 3M(TM) DESK & OFFICE CLEANER 573 02/22/16 __________________________________________________________________________________________ Page 9 of 11 Specific Target Organ Toxicity -repeated exposure Name Route Target Organ(s)Value Species Test Result Exposure Duration ISOPROPYL ALCOHOL Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 12.3 mg/l 24 months ISOPROPYL ALCOHOL Inhalation nervous system All data are negative Rat NOAEL 12 mg/l 13 weeks ISOPROPYL ALCOHOL Ingestion kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 400 mg/kg/day 12 weeks ISOBUTANE PROPELLANT Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 4,500 ppm 13 weeks ETHOXYLATED ALCOHOLS Dermal kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 125 mg/kg/day 13 weeks ETHOXYLATED ALCOHOLS Dermal hematopoietic system All data are negative Rat NOAEL 125 mg/kg/day 13 weeks Aspiration Hazard For the component/components, either no data are currently available or the data are not sufficient for classification. Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Dispose of waste product in a permitted industrial waste facility. Facility must be capable of handling aerosol cans. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. EPA Hazardous Waste Number (RCRA): D001 (Ignitable) SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 3M(TM) DESK & OFFICE CLEANER 573 02/22/16 __________________________________________________________________________________________ Page 10 of 11 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard -Yes Pressure Hazard -Yes Reactivity Hazard -No Immediate Hazard -Yes Delayed Hazard -No 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 3 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. HMIS Hazard Classification Health:2 Flammability:3 Physical Hazard:0 Personal Protection:X -See PPE section. Hazardous Material Identification System (HMIS® IV) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS® IV ratings are to be used with a fully implemented HMIS® IV program. HMIS® is a registered mark of the American Coatings Association (ACA). Document Group:23-3022-3 Version Number:4.01 Issue Date:02/22/16 Supercedes Date: 07/28/14 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M(TM) DESK & OFFICE CLEANER 573 02/22/16 __________________________________________________________________________________________ Page 11 of 11 3M USA SDSs are available at www.3M.com