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HomeMy WebLinkAboutSafetec Hand SanitizerMaterial name: ABHC Fresh Scent® 2128 Version #: 01 Issue date: 01-30-2015 SDS US 1 / 8 SAFETY DATA SHEET 1. Identification Product identifier Instant Hand Sanitizer Fresh Scent® Other means of identification Not available. Recommended use Not available. Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Manufacturer Manufacturer: Safetec of America, Inc. 887 Kensington Avenue Buffalo, NY 14215 Company Telephone: 1-716-895-1822 E-mail Address: www.safetec.com Emergency Telephone: 1-800-255-3924 Supplier Refer to Manufacturer 2. Hazard(s) identification Physical hazards Health hazards Flammable liquids Serious eye damage/eye irritation Specific target organ toxicity, single exposure Category 3 Category 2A Category 3 narcotic effects Environmental hazards OSHA defined hazards Label elements This mixture does not meet the classification criteria according to OSHA HazCom 2012. This mixture does not meet the classification criteria according to OSHA HazCom 2012. Signal word Danger Hazard statement Flammable liquid and vapor. Causes serious eye irritation. May cause drowsiness or dizziness. Precautionary statement Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing mist or vapor. Wash hands thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. Response If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a poison center/doctor if you feel unwell. If eye irritation persists: Get medical advice/attention. In case of fire: Use appropriate media for extinction. Storage Keep cool. Store in a well-ventilated place. Keep container tightly closed. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise classified (HNOC) None known. Supplemental information None. 3. Composition/information on ingredients Mixtures Chemical name Common name and synonyms CAS number % Ethanol Alcohol Ethyl Alcohol 64-17-5 60 - 73 Material name: ABHC Fresh Scent® 2128 Version #: 01 Issue date: 01-30-2015 SDS US 2 / 8 Chemical name Common name and synonyms CAS number % Triethanolamine 2,2',2''-Nitrilotriethanol Tris(2-hydroxyethyl)amine 102-71-6 < 0.30 4. First-aid measures Inhalation If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if symptoms persist. Skin contact Wash off with warm water and soap. Get medical attention if symptoms occur. Eye contact If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if symptoms persist. Ingestion If swallowed, rinse mouth with water (only if the person is conscious). Do not induce vomiting without advice from poison control center. Get medical attention. Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed 5. Fire-fighting measures Causes serious eye irritation. Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. May cause drowsiness or dizziness. Treat symptomatically. Suitable extinguishing media Dry chemicals. Foam. Carbon dioxide (CO2). Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire fighting equipment/instructions Do not use water jet as an extinguisher, as this will spread the fire. The product is combustible, and heating may generate vapors which may form explosive vapor/air mixtures. Thermal decomposition or combustion may liberate toxic gases or fumes. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Cool containers exposed to heat with water spray and remove container, if no risk is involved. General fire hazards Flammable liquid and vapor. Hazardous combustion products Carbon oxides. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep unnecessary personnel away. Wear appropriate personal protective equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. For personal protection, see section 8 of the SDS. Absorb spill with vermiculite or other inert material, then place in a sealed container for chemical waste. Large Spills: Flush with plenty of water. Prevent entry into waterways, sewer, basements or confined areas. Dike for later disposal. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Environmental precautions Avoid discharge into drains, water courses or onto the ground. 7. Handling and storage Precautions for safe handling Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Eliminate all sources of ignition. Take precautionary measures against static discharges. Ground/bond container and receiving equipment. Use explosion-proof equipment. Use only non-sparking tools. When using, do not eat, drink or smoke. Wear appropriate personal protective equipment. Avoid breathing mist or vapor. Avoid contact with eyes, skin, and clothing. Use only with adequate ventilation. Wash thoroughly after handling. Conditions for safe storage, including any incompatibilities Do not store around flammable or combustible materials. Store in tightly closed original container in a well-ventilated place. Keep cool. Store locked up. Material name: ABHC Fresh Scent® 2128 Version #: 01 Issue date: 01-30-2015 SDS US 3 / 8 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value Ethanol (CAS 64-17-5) US. ACGIH Threshold Limit Values PEL 1900 mg/m3 1000 ppm Components Type Value Ethanol (CAS 64-17-5) Triethanolamine (CAS 102-71-6) STEL 1000 ppm TWA 5 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value Ethanol (CAS 64-17-5) TWA 1900 mg/m3 1000 ppm Biological limit values No biological exposure limits noted for the ingredient(s). Appropriate engineering controls Explosion-proof general and local exhaust ventilation. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin protection Hand protection Chemical resistant gloves recommended. Other Wear chemical-resistant gloves, footwear, and protective clothing appropriate for the risk of exposure. Contact health or safety professional or manufacturer for specific information. Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. Contact health and safety professional or manufacturer for specific information. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Gel. Physical state Liquid. Form Gel. Color Light green. Odor Fresh Odor threshold Not available. pH 6.3 - 8.1 Melting point/freezing point Not available. Initial boiling point and boiling range Not available. Flash point 81.0 °F (27.2 °C) Closed Cup Evaporation rate Not available. Flammability (solid, gas) Not applicable. Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) 3.3 % 19 % Explosive limit - lower (%) Not available. Material name: ABHC Fresh Scent® 2128 Version #: 01 Issue date: 01-30-2015 SDS US 4 / 8 Explosive limit - upper (%) Not available. Vapor pressure Not available. Vapor density Not available. Relative density Not available. Solubility(ies) Solubility (water) Complete. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. Other information Specific gravity 0.89 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Stable at normal conditions. Possibility of hazardous reactions Hazardous polymerization does not occur. Conditions to avoid Keep away from heat, sparks and open flame. High temperatures. Incompatible materials Strong oxidizing agents. Acids. Hazardous decomposition products Carbon oxides. 11. Toxicological information Information on likely routes of exposure Inhalation May cause drowsiness or dizziness. Skin contact Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. Eye contact Causes serious eye irritation. Ingestion Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Most important symptoms/effects, acute and delayed Causes serious eye irritation. Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. May cause drowsiness or dizziness. Information on toxicological effects Acute toxicity Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Components Species Ethanol (CAS 64-17-5) Acute Dermal LD50 Rabbit Inhalation LC50 Rat Oral LD50 Rat Triethanolamine (CAS 102-71-6) Acute Dermal LD50 Rabbit Inhalation LC50 Rat Test Results > 15800 mg/kg > 32380 ppm, 4 hours (vapor) > 61 mg/l, 4 hours (vapor) 7060 mg/kg > 19870 mg/kg No data in literature Material name: ABHC Fresh Scent® 2128 Version #: 01 Issue date: 01-30-2015 SDS US 5 / 8 Components Species Oral LD50 Rat Test Results 6110 mg/kg Skin corrosion/irritation Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. Serious eye damage/eye irritation Respiratory or skin sensitization Causes serious eye irritation. Respiratory sensitization This product is not expected to cause respiratory sensitization. Skin sensitizer This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity Triethanolamine (CAS 102-71-6) 3 Not classifiable as to carcinogenicity to humans. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity This product is not expected to cause reproductive effects. Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure May cause drowsiness or dizziness. Not classified as a specific target organ toxicity -repeated exposure. Aspiration toxicity Not expected to be an aspiration hazard. 12. Ecological information Ecotoxicity The product is not classified as environmentally hazardous. Components Ethanol (CAS 64-17-5) Aquatic Acute Algae Crustacea EC50 EC50 Species Green algae (Selenastrum capricornutum) Water flea (Daphnia magna) Test Results 1000 mg/l, 96 hours 5012 mg/l, 48 hours Fish LC50 Fathead minnow (Pimephales promelas) > 100 mg/l, 96 hours Triethanolamine (CAS 102-71-6) Aquatic Acute Algae Crustacea EC50 EC50 Green algae (Desmodesmus subspicatus) Water flea (Ceriodaphnia affinis) 512 mg/l, 72 hours 609.88 mg/l, 48 hours Fish Chronic LC50 Fathead minnow (Pimephales promelas) 11800 mg/l, 96 hours Crustacea NOEC Water flea (Daphnia magna) 16 mg/l, 21 days Persistence and degradability Not available. Bioaccumulative potential Not available. Partition coefficient n-octanol / water (log Kow) Ethanol -0.31 Triethanolamine -1 Mobility in soil Not available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Material name: ABHC Fresh Scent® 2128 Version #: 01 Issue date: 01-30-2015 SDS US 6 / 8 Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused products Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transport information DOT UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Label(s) Packing group UN1170 Ethanol solution (Ethanol RQ = 147 LBS) 3 - 3 III Special precautions for user Not available. Special provisions Packaging exceptions Packaging non bulk Packaging bulk IATA UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Packing group Environmental hazards ERG Code 24, B1, IB3, T2, TP1 4b, 150 203 242 UN1170 Ethanol Solution (Ethanol) 3 - III No. 3L Special precautions for user Not available. Other information IMDG Passenger and cargo aircraft Cargo aircraft only Allowed. Allowed. UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Packing group Environmental hazards Marine pollutant EmS UN1170 Ethanol Solution (Ethanol) 3 - III No. F-E, S-D Special precautions for user Not available. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not available. Material name: ABHC Fresh Scent® 2128 Version #: 01 Issue date: 01-30-2015 SDS US 7 / 8 DOT IATA; IMDG 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Ethanol (CAS 64-17-5) Listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous chemical SARA 313 (TRI reporting) Not regulated. Yes Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA) US state regulations Not regulated. US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. Massachusetts RTK - Substance List Ethanol (CAS 64-17-5) Triethanolamine (CAS 102-71-6) Material name: ABHC Fresh Scent® 2128 Version #: 01 Issue date: 01-30-2015 SDS US 8 / 8 US. New Jersey Worker and Community Right-to-Know Act Ethanol (CAS 64-17-5) Triethanolamine (CAS 102-71-6) US. Pennsylvania Worker and Community Right-to-Know Law Ethanol (CAS 64-17-5) Triethanolamine (CAS 102-71-6) US. Rhode Island RTK Not regulated. US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. US - California Proposition 65 - CRT: Listed date/Carcinogenic substance Ethanol (CAS 64-17-5) Listed: April 29, 2011 Listed: July 1, 1988 US - California Proposition 65 - CRT: Listed date/Developmental toxin Ethanol (CAS 64-17-5) Listed: October 1, 1987 International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Domestic Substances List (DSL) Canada Non-Domestic Substances List (NDSL) China Inventory of Existing Chemical Substances in China (IECSC) Europe European Inventory of Existing Commercial Chemical Substances (EINECS) Europe European List of Notified Chemical Substances (ELINCS) Japan Inventory of Existing and New Chemical Substances (ENCS) Korea Existing Chemicals List (ECL) New Zealand New Zealand Inventory Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) No No No No Yes No No No Yes No No A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 01-30-2015 Version # 01 Disclaimer Prepared by: ICC The Compliance Center Inc. 1-888-442-9628 http://www.thecompliancecenter.com Disclaimer This Safety Data Sheet was prepared by ICC The Compliance Center Inc. using information provided by / obtained from and CCOHS’ Web Information Service. The information in the Safety Data Sheet is offered for your consideration and guidance when exposed to this product. ICC The Compliance Center Inc. and expressly disclaim all expressed or implied warranties and assume no responsibilities for the accuracy or completeness of the data contained herein. The data in this SDS does not apply to use with any other product or in any other process. This Safety Data Sheet may not be changed, or altered in any way without the expressed knowledge and permission of ICC The Compliance Center Inc. and Bibliography ACGIH Documentation of the Threshold Limit Values and Biological Exposure Indices (2014) Canadian Centre for Occupational Health and Safety, CCInfoWeb Databases, 2014 (Chempendium, RTECs, HSDB, INCHEM) European Chemicals Bureau, Existing Chemicals Work Area, EINECS Information System, 2014. Material Safety Data Sheet from manufacturer. OECD - The Global Portal to Information on Chemical Substances - eChemPortal, 2014.