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SAFETY DATA SHEET
Issuing Date: 26-December-2007 Revision Date: 1-April -2015 Product name: LC11M, LC16M, LC38M, LC39M, LC60M, LC61M, LC67M, LC975M, LC980M, LC985M, LC990M, LC1100M, LC65HYM,
LC67HYM, LC990HYM, LC1100HYM Ink
Version: 13 SDS No: BHM018-01-EUUSOTHER
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SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier Product name (code) LC11M (LK3638001, LK4691001), LC16M (LK3534001, LK4711001),
LC38M (LK3662001, LK4197001), LC39M (LK5406001), LC60M (LK5730001), LC61M (LK3367001, LK4298001), LC67M (LK3670001, LK4223001), LC975M (LK5671001), LC980M (LK3375001, LK4049001), LC985M (LK4622001, LK5402001), LC990M (LK4462001), LC1100M (LK3573001, LK3986001), LC65HYM (LK3292001, LK4331001),
LC67HYM (LK3532001, LK4278001), LC990HYM (LK3533001, LK4482001), LC1100HYM (LK3531001, LK4022001) 1.2 Relevant identified uses of the substance or mixture and uses advised against Relevant Identified Use(s) These products are dark red ink in a cartridge for Brother Industries, Ltd. inkjet multifunction devices and fax receivers. The cartridge should be used as supplied by Brother and for use in the products
stated. Information provided on this SDS is only consistent with the use specified by Brother. 1.3 Details of the supplier of the safety data sheet
Manufacturer Brother Industries, Ltd. 15-1 Naeshiro-cho, Mizuho-ku, Nagoya 467-8561, Japan Telephone (for information): +81-52-824-2735
Importer (USA) Brother International Corporation 200 Crossing Boulevard, Bridgewater, NJ 08807, USA Telephone (for information): +1-877-276-8437 Importer (Canada) Brother International Corporation (Canada) Ltd. 1 Hotel de Ville, Dollard des Ormeaux, Quebec, H9B 3H6, Canada
Telephone (for information): +1-514-685-0600 Importer (Europe) Brother International Europe Ltd. Brother House, 1 Tame Street, Guide Bridge, Audenshaw, Manchester M34 5JE, UK
Telephone (for information): +44-161-330-6531 Importer (Australia) Brother International (Aust.) Pty. Ltd. ACN 001 393 835
Level 3, Building A, 11 Talavera Road, Macquarie Park, NSW 2113, Australia Telephone (for information): +61-2-9887-4344 E-mail Address sds.info@brother.co.jp
1.4 Emergency telephone number Emergency Telephone (24 hours) CHEMTREC +1-703-527-3887 (International)
+1-800-424-9300 (North America) For France only: Antipoison Center telephone number: ORFILA +33-1-45-425-959
SAFETY DATA SHEET
Issuing Date: 26-December-2007 Revision Date: 1-April -2015 Product name: LC11M, LC16M, LC38M, LC39M, LC60M, LC61M, LC67M, LC975M, LC980M, LC985M, LC990M, LC1100M, LC65HYM,
LC67HYM, LC990HYM, LC1100HYM Ink
Version: 13 SDS No: BHM018-01-EUUSOTHER
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EN
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SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Not classified as hazardous
Classification according to Directive 1999/45/EC Not classified as hazardous
Australia Classification
Not classified as hazardous according to the criteria of NOHSC
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008
Hazard pictograms None
Signal Word None Hazard Statements EUH208 - Contains water soluble heterocyclic magenta azo dye compounds, 1,2-benzisothiazol-3(2H)-one. May produce an allergic reaction.
Precautionary statements None 2.3 Other hazards This product contains no substance considered to be persistent, bioaccumulating nor toxic (PBT). This product contains no substance
considered to be very persistent nor very bioaccumulating (vPvB).
SAFETY DATA SHEET
Issuing Date: 26-December-2007 Revision Date: 1-April -2015 Product name: LC11M, LC16M, LC38M, LC39M, LC60M, LC61M, LC67M, LC975M, LC980M, LC985M, LC990M, LC1100M, LC65HYM,
LC67HYM, LC990HYM, LC1100HYM Ink
Version: 13 SDS No: BHM018-01-EUUSOTHER
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SECTION 3: Composition/information on ingredients
3.2 Mixtures
Description of the mixture: Water based inkjet ink (Mixture).
Chemical Name CAS-No EC-No w/w% Classification (67/548/EEC) Classification (EU Reg. 1272/2008)
Glycerol 56-81-5 200-289-5 10-20 Not classified Not classified Diethylene glycol 111-46-6 203-872-2 1-5 Xn; R22 Acute Tox. 4 (H302)
Magenta Dye 1 (FJM-001B) * * <2 Xi; R36 - R43 N; R51/53 Eye Irrit. 2 (H319) Skin Sens. 1 (H317) Aquatic Chronic 2 (H411)
Magenta Dye 2 * * <2 N; R51/53 Aquatic Chronic 2 (H411)
Water 7732-18-5 231-791-2 65-75 Not classified Not classified
1,2-benzisothiazol-3(2H)-one 2634-33-5 220-120-9 < 0.05 Xn; R22 Xi; R41 Xi; R38 R43
N; R50
Acute Tox. 4 (Oral), H302 Skin Irrit. 2, H315 Eye Dam. 1, H318 Skin Sens. 1, H317
Aquatic Acute 1, H400
For the full text of R-phrases and H-Statements see Section 16
* Registered
SECTION 4: First aid measures
4.1 Description of first aid measures
General advice If symptoms persist, obtain medical attention.
Inhalation Obtain medical attention. In case of accident by inhalation remove casualty to fresh air and keep at rest.
Skin contact Remove contaminated clothing immediately and wash affected skin with plenty of water or soap and water.
Eye contact Obtain medical attention. If substance has got into the eyes, immediately wash out with plenty of water for at least 15 minutes.
Ingestion Obtain immediate medical attention. Wash out mouth with water and give 100-200 ml of water to drink. 4.2 Most important symptoms and effects, both acute and delayed Skin contact: Repeated and/or prolonged skin contact may cause irritation. May produce an allergic reaction. Eye contact: May cause eye irritation. Ingestion: Ingestion may cause irritation of the gastrointestinal tract. Unlikely route of exposure. Inhalation: Unlikely route of exposure.
4.3 Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SAFETY DATA SHEET
Issuing Date: 26-December-2007 Revision Date: 1-April -2015 Product name: LC11M, LC16M, LC38M, LC39M, LC60M, LC61M, LC67M, LC975M, LC980M, LC985M, LC990M, LC1100M, LC65HYM,
LC67HYM, LC990HYM, LC1100HYM Ink
Version: 13 SDS No: BHM018-01-EUUSOTHER
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SECTION 5: Firefighting measures
5.1 Extinguishing media Suitable Extinguishing Media Extinguish preferably with dry chemical, carbon dioxide, water spray, foam.
Unsuitable Extinguishing Media None.
5.2 Special hazards arising from the substance or mixture Thermal decomposition of organic components may result in occurrence of oxides of carbon. Toxic
gases may be formed upon combustion and represents a hazard to firefighters. Combustion products: See Section: 10. 5.3 Advice for firefighters Use appropriate respirator for carbon monoxide and carbon dioxide. Wear positive pressure self-contained breathing apparatus (SCBA) during the attack phase of firefighting operations and during cleanup in enclosed or poorly ventilated areas immediately after a fire. Personnel not having suitable respiratory protection must leave the area to prevent significant exposure to toxic combustion gases from any source.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Ensure adequate ventilation. Avoid contact with eyes.
6.2 Environmental precautions Prevent substance entering sewers. Washings must be prevented from entering surface water drains.
6.3 Methods and materials for containment and cleaning up Wipe up with absorbent towel. Wash with water to remove remaining traces of ink.
6.4 Reference to other sections For personal protection: See section 8. For disposal considerations: See section 13.
SECTION 7: Handling and storage
7.1 Precautions for safe handling Keep out of the reach of children. Avoid contact with skin and eyes.
7.2 Conditions for safe storage, including any incompatibilities Keep away from oxidizing agents.
7.3 Specific end use(s) These products are dark red ink in a cartridge for Brother Industries, Ltd. inkjet multifunction devices and fax receivers. This cartridge should be used as supplied by Brother and for use in the products stated.
SECTION 8: Exposure controls/personal protection
8.1 Control Parameters
Occupational Exposure Limits
Chemical Name Glycerol 56-81-5
ACGIH TLV TWA: 10 mg/m3 mist
OSHA PEL TWA: 15 mg/m3 mist, total particulate TWA: 5 mg/m3 mist, respirable fraction
European Union -
The United Kingdom STEL: 30 mg/m3
TWA: 10 mg/m3
SAFETY DATA SHEET
Issuing Date: 26-December-2007 Revision Date: 1-April -2015 Product name: LC11M, LC16M, LC38M, LC39M, LC60M, LC61M, LC67M, LC975M, LC980M, LC985M, LC990M, LC1100M, LC65HYM,
LC67HYM, LC990HYM, LC1100HYM Ink
Version: 13 SDS No: BHM018-01-EUUSOTHER
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France TWA: 10 mg/m3
Spain TWA: 10 mg/m3
Germany TWA: 50 mg/m3 Ceiling / Peak: 100 mg/m3
Portugal TWA: 10 mg/m3
Finland TWA: 20 mg/m3
Switzerland STEL: 100 mg/m3 TWA: 50 mg/m3
Poland TWA: 10 mg/m3
Ireland TWA: 10 mg/m3
Chemical Name Diethylene glycol 111-46-6
ACGIH TLV -
OSHA PEL -
European Union -
The United Kingdom STEL: 69 ppm STEL: 303 mg/m3 TWA: 23 ppm TWA: 101 mg/m3 Germany TWA: 10 ppm TWA: 44 mg/m3 Ceiling / Peak: 40 ppm Ceiling / Peak: 176 mg/m3
Denmark TWA: 2.5 ppm TWA: 11 mg/m3
Austria STEL 40 ppm STEL 176 mg/m3 TWA: 10 ppm TWA: 44 mg/m3
Switzerland STEL: 40 ppm STEL: 176 mg/m3 TWA: 10 ppm TWA: 44 mg/m3
Poland TWA: 10 mg/m3
Ireland TWA: 23 ppm TWA: 100 mg/m3
8.2 Exposure controls
Appropriate engineering controls Good general ventilation should be sufficient under normal use.
Personal protective equipment Not normally required. For use other than in normal operating procedures (such as in the event of large spill), the following should be applied: Eye Protection Safety goggles.
Hand Protection Protective gloves.
Skin and body protection Long sleeved clothing and long pants.
Respiratory protection Large spillages: Wear suitable respiratory protective equipment.
Environmental Exposure Controls Avoid release to the environment.
SAFETY DATA SHEET
Issuing Date: 26-December-2007 Revision Date: 1-April -2015 Product name: LC11M, LC16M, LC38M, LC39M, LC60M, LC61M, LC67M, LC975M, LC980M, LC985M, LC990M, LC1100M, LC65HYM,
LC67HYM, LC990HYM, LC1100HYM Ink
Version: 13 SDS No: BHM018-01-EUUSOTHER
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SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties Appearance Physical state Liquid
Color Dark red
Odor Slight
Odor Threshold No information available pH 7 - 9 Melting point/freezing point - / < -5 °C Initial boiling point and boiling range > 100 °C Flash Point Does not flash >93.3°C
( Tag closed cup; Cleveland open cup ) Evaporation rate No information available Flammability (solid, gas) Not applicable Upper/lower flammability or explosive limits No information available
Vapor pressure No information available Vapor density No information available Relative density 1.0 - 1.1 (H2O=1) Solubility(ies) Soluble (water) Partition coefficient: n-octanol/water No information available
Auto-ignition temperature >400 °C Decomposition temperature No information available Viscosity 1 - 5 mPa·s Explosive properties Not explosive Oxidizing properties No information available
9.2 Other information
No information available.
SECTION 10: Stability and reactivity
10.1 Reactivity No information available. 10.2 Chemical stability Stable.
10.3 Possibility of hazardous reactions No information available.
10.4 Conditions to avoid No information available. 10.5 Incompatible materials Strong oxidizing agents. 10.6 Hazardous decomposition products Contains: Carbon monoxide (CO). Carbon dioxide (CO2).
SAFETY DATA SHEET
Issuing Date: 26-December-2007 Revision Date: 1-April -2015 Product name: LC11M, LC16M, LC38M, LC39M, LC60M, LC61M, LC67M, LC975M, LC980M, LC985M, LC990M, LC1100M, LC65HYM,
LC67HYM, LC990HYM, LC1100HYM Ink
Version: 13 SDS No: BHM018-01-EUUSOTHER
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SECTION 11: Toxicological information
11.1 Information on toxicological effects Acute toxicity Inhalation No information available.
Eye contact No information available.
Skin contact No information available.
Ingestion LD50 > 2000 mg/kg (Method OECD#420)
Skin corrosion/irritation Non-irritant. (Method: OECD#404)
Serious eye damage/irritation Minimal irritant to the eye. (Method: OECD#405)
Respiratory or skin sensitisation It is not a skin sensitizer. (Method: OECD#429)
Mutagenicity Negative. (Method: OECD#471)
Carcinogenicity Ingredients of this product have not been classified as carcinogens according to IARC monographs, NTP and OSHA
SECTION 12: Ecological information
12.1 Toxicity
Chemical Name Toxicity to algae Toxicity to fish Toxicity to daphnia and other aquatic invertebrates
Glycerol
56-81-5 LC50: 51 - 57 mL/L 96 h
static (Oncorhynchus mykiss)
EC50: >500 mg/L 24 h
(Daphnia magna)
Diethylene glycol 111-46-6 LC50: 75200 mg/L 96 h flow-through (Pimephales promelas)
EC50: 84000 mg/L 48 h (Daphnia magna)
12.2 Persistance and degradability No information available. 12.3 Bioaccumulative potential
Chemical Name log Pow
Glycerol -1.76 Diethylene glycol -1.98
12.4 Mobility in soil No information available. 12.5 Results of PBT and vPvB assessment This product contains no substance considered to be persistent, bioaccumulating nor toxic (PBT). This product contains no substance considered to be very persistent nor very bioaccumulating (vPvB).
12.6 Other adverse effects No information available.
SAFETY DATA SHEET
Issuing Date: 26-December-2007 Revision Date: 1-April -2015 Product name: LC11M, LC16M, LC38M, LC39M, LC60M, LC61M, LC67M, LC975M, LC980M, LC985M, LC990M, LC1100M, LC65HYM,
LC67HYM, LC990HYM, LC1100HYM Ink
Version: 13 SDS No: BHM018-01-EUUSOTHER
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Page 8 / 9
SECTION 13: Disposal considerations
13.1 Waste treatment methods Dispose of in accordance with Federal, State, and local regulations.
SECTION 14: Transport information
Not classified according to the United Nations "Recommendations on the Transport of Dangerous Goods" 14.1 UN Number None
14.2 UN proper shipping name None
14.3 Transport hazard class(es) None 14.4 Packing Group None 14.5 Environmental hazards None
14.6 Special precautions for user None 14.7 Transport in bulk according to
Annex II of Marpol 73/78 and the IBC Code
Not applicable
Not regulated under DOT, IMDG, IATA.
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU:Not classified as dangerous for supply/use. (1999/45/EC) But ink has to bear the inscription: "Contains water soluble heterocyclic magenta azo dye
compounds. May produce an allergic reaction" USA: All chemical substances contained in this product are and had been listed on the TSCA Chemical Substances Inventory, and none is subject to any of the following TSCA requirements: section 4 test rules; proposed or final section 5(a)(2) significant new use rules; section 5(e) consent orders; section 8(a) preliminary assessment information rules; and section 8(d) health and safety
data reporting rules. Canada: WHMIS: Not applicable. (Manufactured article) 15.2 Chemical Safety Assessment No.
SAFETY DATA SHEET
Issuing Date: 26-December-2007 Revision Date: 1-April -2015 Product name: LC11M, LC16M, LC38M, LC39M, LC60M, LC61M, LC67M, LC975M, LC980M, LC985M, LC990M, LC1100M, LC65HYM,
LC67HYM, LC990HYM, LC1100HYM Ink
Version: 13 SDS No: BHM018-01-EUUSOTHER
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SECTION 16: Other information
Full text of R-phrases referred to under sections 2 and 3 R22 - Harmful if swallowed R36 - Irritating to eyes
R41 - Risk of serious damage to eyes R38 - Irritating to skin R43 - May cause sensitization by skin contact R50 - Very toxic to aquatic organisms R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment Full text of H-Statements referred to under sections 2 and 3 H302 - Harmful if swallowed H315 - Causes skin irritation H318 - Causes serious eye damage H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H400 - Very toxic to aquatic life H411 - Toxic to aquatic life with long lasting effects Additional information The information relates only to this product. It may not be valid, if used in combination with any other materials or in any other process, and it is based on our best knowledge as of the date of preparation
(revision). Revision Note SECTION 2, 3.
References: U.S. 29CFR Part 1910 ACGIH Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices
IARC Monographs on the Evaluation Carcinogenic Risks to Humans World Health Organization EU Directive 91/322/EEC and 2000/39/EC NTP 11th Report on Carcinogens Abbreviations: ACGIH: American Conference of Governmental Industrial Hygienists DOT: Department Of Transportation (US) IARC: International Agency for Research on Cancer IATA: International Air Transport Association IMDG: International Maritime Dangerous Goods
NOHSC: National Occupational Health and Safety Commission (Australia) NTP: National Toxicology Program (US) OSHA: Occupational Safety and Health Administration (US) PEL: Permissible Exposure Limit STEL: Short Term Exposure Limit TLV: Threshold Limit Value (ACGIH) TSCA: Toxic Substances Control Act (US) TWA: Time Weighted Average WHMIS: Workplace Hazardous Material Information System (Canada)