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HomeMy WebLinkAboutVi-Jon Germ-X Hand Sanitizer - with fragranceProduct Number:089AA Issuing Date:January 12,2016 Product Name:Germ-X Aloe Hand Sanitizer -with Fragrance Revision Date:None Revision Number: 0 VIJON Safety Data Sheet ©The supplier identified below generated this SDS using the UL SDS template.UL did not test,certify,or approve the substance described in this SDS andallinformationinthisSDSwasprovidedbythesupplierorwasreproducedfrompublicallyavailableregulatorydatasources.UL makes no representations or warranties regarding the completeness or accuracy ofthe information in this SDS and disclaims all liability in connection with the useofthis informationorthesubstancedescribedinthisSDS.The layout,appearance and format ofthis SDS is©2014 UL LLC.All rights reserved 1.IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product identifier Product Name Other means of identification Synonyms None Recommended use of the chemical and restrictions on use Recommended Use Hand sanitizer Uses advised against Use onlyas directed. Details ofthe supplier ofthe safety data sheet Supplier Name Supplier Address Supplier Phone Number Supplier Email Emergency telephone number © 089AA Germ-XAloe Hand Sanitizer- With Fragrance Vi-Jon Inc. Vi-Jon Inc. 8800 Page Avenue Saint Louis MO 63114 US Phone:314-427-1000 (M-F 8am-4pm CST) Fax:3144271010 info@vijon.com Chemtrec:1-800-424-9300 (24-Hour) Page 1/11 Product Number:089AA Issuing Date:January 12, 2016 Product Name:Germ-X Aloe Hand Sanitizer -with Fragrance Revision Date:None Revision Number:0 2.HAZARDS IDENTIFICATION Classification This chemical isconsidered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). Flammable liquids GHS Label elements,including precautionary statements Emergency Overview Signal word: Flammable liquid and vapor Warning Category 3 ZI Z3 Appearance:Clear to SlightlyHazy, Pale Green,Slightly Viscous Gel-like Liquid Physical state:Gel-Like Liquid Odor:Alcohol,Floral Precautionary Statements -Prevention Keep away from heat/sparks/open flames/hot surfaces.-No smoking Keep containertightly closed Ground/bond container and receiving equipment Use explosion-proof electrical/ventilating/lighting/equipment Use only non-sparking tools Take precautionary measures against static discharge Wear protective gloves/protective clothing/eyeprotection/face protection Precautionary Statements -Response Skin IF ON SKIN (orhair):Remove/Take offimmediately all contaminated clothing.Rinse skin with water/shower Fire Incase of fire: Use C02,dry chemical,or foam for extinction Precautionary Statements -Storage Store ina well-ventilated place. Keep cool Precautionary Statements -Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Unknown Toxicity 2E-06 % of the mixture consists of ingredient(s)of unknown toxicity Other information Toxic to aquatic life PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION May cause slight eye irritation Interactions with Other Chemicals No information available. ®Page 2/11 Product Number:089AA Issuing Date:January 12, 2016 Product Name:Germ-X Aloe Hand Sanitizer -with Fragrance Revision Date:None RevisionNumber:0 3.COMPOSITION/INFORMATION ON INGREDIENTS Water Fragrance Chemical name Ethyl Alcohol 62%v/v Glycerin Aloe Barbadensis Leaf Juice CAS No 64-17-5 7732-18-5 56-81-5 Proprietary Weight-% 50-100 10-50 0-10 Trade Secret 0-10 Acrylates/C 10-30Alky!Acrylate Crosspolymer Maltodextrin 94349-62-9 Proprietary 0-10 0-10 Propylene Glycol Triethanolamine Blue 1 Yellow 5 9050-36-6 57-55-6 102-71-6 3844-45-9 0-10 0-10 0-10 1934-21-0 0-10 0-10'The exact percentage (concentration)of composition has been withheld asa trade secret First aid measures Eye contact Skin contact Inhalation Ingestion Self-protection of the first aider 4.FIRST AID MEASURES Rinse immediately with plenty of water,also under the eyelids,for at least 15 minutes Keep eye wide open while rinsing.Do not rub affected area.Remove contact lenses if present and easy to do. Continuerinsing. Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Remove to fresh air. Rinse mouth immediately and drink plenty of water.Never give anything by mouth to an unconscious person. Remove all sources of ignition.Ensure that medical personnel are aware of the material(s) involved,take precautions to protect themselves and prevent spread ofcontamination.Use personal protective equipment as required.Wear personal protective clothing (see section 8)- Most important symptoms and effects,both acute and delayed Most Important Symptoms and No information available. Effects Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. 5.FIRE-FIGHTING MEASURES Suitable Extinguishing Media Useextinguishing measures thatare appropriate to local circumstances andthe surrounding environment.Dry chemical.Carbon dioxide (C02).Water spray.Alcohol resistant foam. Unsuitable extinguishing media CAUTION:Use of water spray when fighting fire may be inefficient. Specific hazards arising from the chemical Risk of ignition. Keep product and empty container away from heat and sources of ignition. In the event of fire,cool tanks with water spray. Fire residues and contaminated fire extinguishingwater must be disposed of in accordance with local regulations. Uniform Fire Code Flammable Liquid:l-C Explosion Data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge Yes. Protective equipment and precautions for firefighters As in any fire,wear self-contained breathing apparatus pressure-demand,MSHA/NIOSH (approved or equivalent)and full protective gear. ®Page 3/11 Product Number:089AA Issuing Date:January 12,2016 Product Name: Revision Date:None Germ-X Aloe Hand Sanitizer-with Fragrance Revision Number:0 6.ACCIDENTAL RELEASE MEASURES Personal precautions,protective equipment and emergency procedures Personal precautions Evacuate personnel to safeareas.Use personal protective equipment as required.See section8formore information.Avoid contactwith skin,eyes or clothing.Ensureadequate ventilation.Keeppeople away from and upwind of spill/leak.ELIMINATE all ignition sources (no smoking, flares, sparks or flames inimmediate area).Pay attention to flashback. Take precautionarymeasures against static discharges.All equipment used when handling the product must be grounded.Do not touch or walk through spilled material. Other Information Ventilate the area. Environmental precautions Environmental precautions Refer to protective measures listed in Sections 7 and 8.Prevent further leakage or spillage ifsafe to do so. Prevent product from entering drains. Methods and material for containment and cleaning up Methods forcontainment Prevent further leakage orspillage if safetodoso.Do not touch orwalk through spilled material.Avaporsuppressing foam maybe used to reduce vapors.Dike farahead ofspill to collect runoff water. Keepout ofdrains, sewers, ditches and waterways. Methods for cleaning up Take precautionary measures against static discharges.Dam up.Soak up with inert absorbent material. Pick up and transfer to properly labeled containers. 7.HANDLING AND STORAGE Precautions for safe handling Handling Handle in accordance with good industrial hygiene and safety practice.Avoid contact with skin,eyes orclothing.Use personal protection equipment.Avoid breathing vapors or mists. Keep away from heat/sparks/open flames/hot surfaces.-No smoking.Use grounding and bonding connection when transferring this material toprevent static discharge,fire or explosion.Use with local exhaust ventilation.Use spark-proof tools and explosion-proof equipment.Keep in an area equipped with sprinklers.Use according to package label instructions. Conditions for safe storage,including any incompatibilities Storage KeeP containers tightly closed in a dry,cool and well-ventilated place.Keep away from heat,sparks,flame and other sources of ignition (i.e.,pilot lights,electric motors and static electricity).Keep in properly labeled containers.Do not store nearcombustible materials. Keep in an area equipped with sprinklers.Store in accordance with the particular national regulations.Store in accordancewith local regulations. Incompatible Products None known based on information supplied. ®Page 4/11 Product Number:089AA Issuing Date:January 12, 2016 Product Name: Revision Date:None Germ-X Aloe HandSanitizer -with Fragrance Revision Number:0 8.EXPOSURE CONTROLS/PERSONAL PROTECTION ZIControlparameters Exposure Guidelines Chemical name Ethyl Alcohol 62%v/v 64-17-5 Glycerin 56-81-5 Triethanolamine 102-71-6 There isno exposure data pertaining to the Product.This section reflects exposure data pertaining to individual ingredients. ACGIH TLV STEL:1000ppm TWA:10 mg/m3 mist TWA:5 mg/mJ OSHA PEL TWA:1000 ppm TWA:1900mg/m3 (vacated)TWA:1000 ppm (vacated)TWA:1900 mg/m3 TWA:15 mg/m"mist, total particulate TWA:5 mg/m3 mist,respirable fraction (vacated)TWA:10 mg/m3 total particulate (vacated)TWA:5 mg/m3 respirable fraction mist, mist. NIOSH IDLH IDLH:3300 ppm 10% LEL TWA:1000 ppm TWA:1900 mg/m3 ACGIH TLV:American Conference of Governmental Industrial Hygienists -Threshold Limit Value OSHA PEL Occupational Safety and HealthAdministration-Permissible Exposure Limits NIOSH IDLH Immediately Dangerous toLife or Health Vacatedlimits revoked bythe Court ofAppeals decision in AFL-CIO v.OSHA 965F2d 962 (11th Cir., 1992) Other Exposure Guidelines Appropriate engineering controls Engineering Measures Showers Eyewash stations Ventilation systems Individual protection measures,such as personal protective eguipment Eye/face protection Skin and body protection Respiratory protection Hygiene Measures ® Tight sealing safety goggles. Wear protective gloves and protective clothing.Long sleeved clothing.Chemical resistant apron.Impervious gloves.Antistatic boots. Ifexposure limits are exceeded or irritation is experienced,NIOSH/MSHA approved respiratory protection should be worn.Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations.Respiratory protection must be provided in accordance with current local regulations. Handle in accordance withgood industrial hygiene and safety practice. Do not eat,drinkor smoke when using this product.Contaminated work clothing should not be allowed out of the workplace.Regular cleaning of equipment,work area and clothing is recommended. Wash hands before breaks and immediately after handling the product. Page 5/11 Product Number:089AA Issuing Date:January 12,2016 Product Name: Revision Date:None Germ-X Aloe Hand Sanitizer - with Fragrance Revision Number:0 9.PHYSICAL AND CHEMICAL PROPERTIES Gel-like Liquid Clear to Slightly Hazy,Pale Green, Slightly Viscous Gel-like Liquid Colorless Values 7.0 No data available 78 °C /172 ° 23 C /73 F No data available No data available Physical and Chemical Properties Physical state Appearance Color Property pH Melting /freezing point Boiling point/boiling range Flash Point Evaporation Rate Flammability (solid,gas) Flammability Limit in Air Upper flammability limit Lower flammability limit Vapor pressure Vapor density Specific Gravity Water Solubility Solubility in other solvents No data available No data available No data available No data available 0.90 Miscible in water No data available Partition coefficient:n-octanol/waterNo data available Autoignition temperature No data available Decomposition temperature No data available Kinematic viscosity No data available Dynamic viscosity No data available Explosive properties No data available Oxidizing properties No data available Other Information Softening Point VOC Content (%) Particle Size Particle Size Distribution No data available No data available No data available No data available Odor Odor Threshold Remarks Method None known None known None known None known None known None known None None None None None None None None None None known known known known known known known known known known 10.STABILITY AND REACTIVITY Alcohol,Floral No information available Reactivity No data available. Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization Hazardous polymerization does not occur. Conditions to avoid Heat,flames,and sparks. Incompatible materials None known. Hazardous Decomposition Products None known. When used in accordance with the directions. ®Page 6/11 Product Number:089AA Issuing Date:January 12, 2016 Product Name:Germ-X Aloe Hand Sanitizer -with Fragrance Revision Date: None Revision Number:0 11.TOXICOLOGICAL INFORMATION There is no data for this product.The information included inthissection describes the potential hazards ofthe individual ingredients. Information on likely routes of exposure Product Information Inhalation Specifictest data forthe substance or mixture is not available. Eye contact Specific test data forthe substance or mixture is not available. Skin contact Specific test data for thesubstance or mixture is not available. Ingestion Specifictest data forthe substance or mixture is not available. Component Information Chemical name Oral LD50 Dermal LD50 Inhalation LC50 Ethyl Alcohol 62%v/v 64-17-5 =7060 mg/kg (Rat)-=124.7mg/L (Rat)4 h Uater 7732-18-5 >90mL/kg (Rat)-- Glycerin 56-81-5 =12600 mg/kg (Rat)>10g/kg (Rabbit)> 570 mg/mJ (Rat)1 h Propylene Glycol 57-55-6 =20g/kg (Rat)=20800 mg/kg (Rabbit)- Triethanolamine 102-71-6 =4190 mg/kg (Rat)> 20 mUkg (Rabbit)>16 mL/kg (Rat) - Information on toxicological effects Symptoms No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Mutagenic Effects No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient asa carcinogen. Ethanolhas been shownto be carcinogenicinlong-termstudies ONLY when consumed as alcoholic beverage. Chemical name ACGIH IARC NTP OSHA Ethyl Alcohol 62%v/v 64-17-5 A3 Group 1 Known X Maltodextrin 9050-36-6 -- Triethanolamine 102-71-6 Group 3 Blue 1 3844-45-9 Group 3 A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 1 -Carcinogenic to Humans Group3 - Not Classifiable as to Carcinogenicityin Humans NTP (National Toxicology Program) Known - Known Carcinogen OSHA (Occupational Safety and Health Administration of the USDepartment of Labor) X -Present Reproductive toxicity STOT -single exposure STOT -repeated exposure Chronic Toxicity Target Organ Effects Aspiration Hazard ® No information available. No information available. No information available. No known effect based on information supplied. None known. No information available. Page 7/11 Product Number:089AA Issuing Date:January 12,2016 Product Name:Germ-X Aloe Hand Sanitizer -with Fragrance Revision Date:None Revision Number:0 Numerical measures oftoxicity Product Information The following values are calculated based on chapter 3.1 of the GHSdocument ATEmix (oral) 13,058.00 mg/kg ATEmix (inhalation-dust/mist) 230.60 mg/l 12.ECOLOGICAL INFORMATION There is no ecologicaldataon the Product.The Product ingredientsareexpected to be safe forthe environment at concentrations predicted under normal use and accidental spill scenarios.Packaging components are compatible with the conventional solid waste management practices. Ecotoxicitv Toxic to aquatic organisms. Persistence and Degradabilitv No information available. Bioaccumulation No information available. Other adverse effects No information available. 13.DISPOSAL CONSIDERATIONS Waste treatment methods Disposal methods This material,as supplied,is a hazardous waste according to federal regulations (40 CFR 261). Contaminated Packaging Dispose of contents/containers in accordance with local regulations. US EPA Waste Number D001 California Hazardous Waste Codes 311 This product contains one or more substances that are listed with the State of California as a hazardous waste. DOT Proper Shipping Name Hazard Class Description Emergency Response Guide Number TDG UN-No. Proper Shipping Name Hazard Class Packing Group Description MEX UN-No. Proper Shipping Name Hazard Class Packing Group Description 14.TRANSPORT INFORMATION CONSUMER COMMODITY ORM-D CONSUMER COMMODITY,ORM-D 127 UN1170 ETHANOL SOLUTION 3 III UN1170,ETHANOL SOLUTION,3, UN1170 ETHANOL SOLUTION 3 III UN1170,ETHANOL SOLUTION,3, n ©Page 8/11 Product Number:089AA Issuing Date:January 12, 2016 ICAO UN-No. Proper Shipping Name Hazard Class Packing Group Description IATA UN-No. Proper Shipping Name Hazard Class Packing Group ERG Code Description IMDG/IMO UN-No. Proper Shipping Name Hazard Class Packing Group EmS-No. Description RID UN-No. Proper Shipping Name Hazard Class Packing Group Classification code Description ADR UN-No. Proper Shipping Name Hazard Class Packing Group Classification code Tunnel restriction code Description ADN UN-No. Proper Shipping Name Hazard Class Packing Group Classification code Special Provisions Description Hazard Labels Limited Quantity Ventilation ® Product Name:Germ-X Aloe Hand Sanitizer -with Fragrance Revision Date:None Revision Number: 0 UN1170 ETHANOL SOLUTION 3 III UN1170,ETHANOL SOLUTION,3, UN1170 ETHANOL SOLUTION 3 III 3L UN1170,ETHANOL SOLUTION,3, UN1170 ETHANOL SOLUTION F-E,S-D UN1170,ETHANOL SOLUTION,3,III,(23°C C.C. UN1170 ETHANOL SOLUTION 3 F1 UN1170,ETHANOL SOLUTION,3,III,ENVIRONMENTALLY HAZARDOUS UN1170 ETHANOL SOLUTION 3 III F1 D/E UN1170,ETHANOL SOLUTION,3,III,ENVIRONMENTALLY HAZARDOUS UN1170 ETHANOL SOLUTION 3 F1 144,601 UN1170,ETHANOL SOLUTION,3, 3 5L VE01 I,ENVIRONMENTALLY HAZARDOUS Page 9/11 Product Number:089AA Issuing Date:January 12,2016 Product Name:Germ-X Aloe Hand Sanitizer - with Fragrance Revision Date:None Revision Number:0 International Inventories TSCA DSL IECSC 15.REGULATORY INFORMATION Complies All components are listed either on the DSL or NDSL. TSCA - United States Toxic Substances Control Act Section 8(b)Inventory DSL/NDSL -Canadian Domestic Substances List/Non-Domestic Substances List US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA).This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations,Part 372 SARA 311/312 Hazard Categories Acute Health Hazard No Chronic Health Hazard No Fire Hazard Yes Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material,as supplied,does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA)(40 CFR 302)or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355).There may be specific reporting requirements at the local,regional,or state level pertaining to releases of this material US State Regulations California Proposition 65 -NONE This product does not contain any Proposition 65 chemicals. U.S.State Right-to-Know Regulations Chemical name New Jersey Massachusetts Pennsylvania Rhode Island Illinois Ethyl Alcohol 62%v/v 64-17-5 X X Glycerin 56-81-5 X X X X Propylene Glycol 57-55-6 X X Triethanolamine 102-71-6 X X X Bluel 3844-45-9 X International Regulations Mexico National occupational exposure limits Component Carcinogen Status Exposure Limits Ethyl Alcohol 62%v/v 64-17-5(50-100) Mexico:TWA 1000 ppm Mexico:TWA 1900mg/m3 Glycerin 56-81-5(0-10) -10mg/mJ (mist)TWA Mexico -Occupational Exposure Limits-Carcinogens Canada WHMIS Hazard Class Not determined ®Page 10/11 Product Number:089AA Issuing Date:January 12,2016 Product Name: Revision Date:None Germ-X AloeHand Sanitizer-with Fragrance Revision Number:0 NFPA HMIS Prepared By Issuing Date Revision Date Revision Note 16.OTHER INFORMATION Health Hazards 1 Flammability 3 Instability 0 Physicaland Chemical Hazards N/A Health Hazards 1 Flammability 3 Physical Hazard 0 Personal Protection X Product Stewardship 23 British American Blvd. Latham,NY 12110 1-800-572-6501 January 12,2016 None None General Disclaimer Theinformationprovidedinthis Safety DataSheet is correctto the best ofour knowledge,information and beliefat the date ofits publication.The information given is designed only as guidance for safehandling,use,processing,storage,transportation,disposal and release andisnottobeconsidered awarranty orquality specification.The information relates only tothespecific material designated and may notbe valid forsuch material used incombination with anyother materials or inanyprocess, unlessspecifiedinthe text. Approved and Updated by Vi-Jon,Inc. Disclaimer: The information and recommendationscontained inthe SafetyDataSheet (SDS)are supplied pursuant to 29 CFR 1910.1200 ofthe OccupationalSafetyand Health Standards Hazard Communication Rule.The information and recommendations setforth hereinare presented in good faith and believed to be correct as ofthis date hereof. Vi-Jon,however,makes norepresentation as tothe completeness oraccuracy thereof,and information is supplied upon the express condition thatthepersons receiving the information will be required tomake their own determination astoitssuitability for their purposespriortouse.In no event will Vi-Jon beresponsible for any damages ofany nature whatsoever resulting from the useof,reliance upon,or the misuse ofthis information. No representations orwarranties,either expressed orimplied,ofmerchantability,fitness for a particular purpose,orofany other nature,aremadehereunderwithrespecttoinformationortheproducttowhichtheinformationrefers.The information assupplied herein issimply to beinformative and intended solely to alert theuserofthesubstance which isthesubject matter ofthisSDS.The ultimate compliance withfederal,stateorlocal regulations concerning the useofthis compound,orcompliance with respect toproduct liability,rests solely upon the purchaser thereof. End of Safety Data Sheet ©Page 11/11