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Home My WebLink AboutHP 45 Black - 51645 SeriesSAFETY DATA SHEET 1. Identification Product identifier 51645 Series Other means of identification Not available. Recommended use Inkjet printing Recommended restrictions None known. Company identification Hewlett-Packard Company 3000 Hanover Street Palo Alto, CA 94304-1185 United States Telephone 650-857-5020 Hewlett-Packard health effects line (Toll-free within the US) 1-800-457-4209 (Direct) 1-760-710-0048 HP Customer Care Line (Toll-free within the US) 1-800-474-6836 (Direct) 1-208-323-2551 Email: hpcustomer.inquiries@hp.com 2. Hazard(s) identification Not classified.Physical hazards Not classified.Health hazards Not classified.Environmental hazards Not classified.OSHA defined hazards Label elements None.Hazard symbol Signal word None. Hazard statement Not available. Precautionary statement Prevention Not available. Response Not available. Storage Not available. Disposal Not available. Hazard(s) not otherwise classified (HNOC) Complete toxicity data are not available for this specific formulation Potential routes of overexposure to this product are skin and eye contact Inhalation of vapor and ingestion are not expected to be significant routes of exposure for this product under normal use conditions. Carbon black is classified by the IARC as a Group 2B carcinogen (the substance is possibly carcinogenic to humans). Carbon black in this preparation, due to its bound form, does not present this carcinogenic risk. None of the other ingredients in this preparation are classified as carcinogens according to ACGIH, EU, IARC, MAK, NTP or OSHA. Supplemental information None. 3. Composition/information on ingredients Mixtures CAS number %Chemical name Common name and synonyms 7732-18-5Water 75-85 616-45-52-pyrrolidone <15 1 / 8 Material name: 51645 Series 9235 Version #: 01 Issue date: 01-Apr-2015 SDS US CAS number %Chemical name Common name and synonyms 1333-86-4Carbon black <5 67-63-0Isopropyl alcohol <2.5 Composition comments This ink supply contains an aqueous ink formulation. This product has been evaluated using criteria specified in 29 CFR 1910.1200 (Hazard Communication Standard). Carbon black is present only in a bound form in this preparation. 4. First-aid measures Inhalation Move to fresh air. If symptoms persist, get medical attention. Skin contact Wash affected areas thoroughly with mild soap and water. If irritation persists get medical attention. Eye contact Do not rub eyes. Immediately flush with large amounts of clean, warm water (low pressure) for at least 15 minutes or until particles are removed. If irritation persists get medical attention. Ingestion If ingestion of a large amount does occur, seek medical attention. Most important symptoms/effects, acute and delayed Contact with skin and eyes may result in irritation. 5. Fire-fighting measures Notes No ignition, sustained combustion or flashing detected using the Sustained Combustibility Test (method in US 49CFR173, Appendix H). Suitable extinguishing media CO2, water, dry chemical, or foam Unsuitable extinguishing media None known. Specific hazards arising from the chemical Not applicable. Special protective equipment and precautions for firefighters None established. Specific methods None established. General fire hazards Contact with skin and eyes may result in irritation. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Wear appropriate personal protective equipment. Methods and materials for containment and cleaning up Dike the spilled material, where this is possible. Absorb with inert absorbent such as dry clay, sand or diatomaceous earth, commercial sorbents, or recover using pumps. Slowly vacuum or sweep the material into a bag or other sealed container. Dispose of in compliance with federal, state, and local regulations. Environmental precautions Do not let product enter drains. Do not flush into surface water or sanitary sewer system. 7. Handling and storage Precautions for safe handling Avoid contact with skin, eyes and clothing. Conditions for safe storage, including any incompatibilities Keep out of the reach of children. Keep away from excessive heat or cold. 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueComponents Type PEL 3.5 mg/m3Carbon black (CAS 1333-86-4) PEL 980 mg/m3Isopropyl alcohol (CAS 67-63-0) 2 / 8 Material name: 51645 Series 9235 Version #: 01 Issue date: 01-Apr-2015 SDS US US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueComponents Type 400 ppm US. ACGIH Threshold Limit Values ValueComponents FormType TWA 3 mg/m3 Inhalable fraction.Carbon black (CAS 1333-86-4) STEL 400 ppmIsopropyl alcohol (CAS 67-63-0) TWA 200 ppm US. NIOSH: Pocket Guide to Chemical Hazards ValueComponents Type TWA 0.1 mg/m3Carbon black (CAS 1333-86-4) STEL 1225 mg/m3Isopropyl alcohol (CAS 67-63-0) 500 ppm TWA 980 mg/m3 400 ppm Biological limit values ACGIH Biological Exposure Indices ValueComponents Determinant Specimen Sampling Time 40 mg/l Acetone Urine *Isopropyl alcohol (CAS 67-63-0) * - For sampling details, please see the source document. Exposure guidelines Exposure limits have not been established for this product. Appropriate engineering controls Use in a well ventilated area. Individual protection measures, such as personal protective equipment Eye/face protection Not available. Skin protection Hand protection Not available. Other Not available. Respiratory protection Not available. Thermal hazards Not available. General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. 9. Physical and chemical properties Appearance Physical state Liquid. Color Black. Odor Not available. Odor threshold Not available. pH 7.8 - 8.4 Melting point/freezing point Not available. Initial boiling point and boiling range 200 °F (93.33 °C) Flash point 131.0 - 136.0 °F (55.0 - 57.8 °C) Evaporation rate Not determined Flammability (solid, gas)Not available. 3 / 8 Material name: 51645 Series 9235 Version #: 01 Issue date: 01-Apr-2015 SDS US Upper/lower flammability or explosive limits Flammability limit - lower (%) Not available. Flammability limit - upper (%) Not available. Explosive limit - lower (%) Not available. Explosive limit - upper (%) Not available. Vapor pressure Not determined Solubility(ies) Solubility (water)Soluble in water Partition coefficient (n-octanol/water) Not determined Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity > 2 cp Other information Specific gravity 1 - 1.2 Other information For other VOC regulatory data/information see Section 15. VOC (Weight %)< 116.6 g/l 10. Stability and reactivity Reactivity Not available. Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions Will not occur. Conditions to avoid Not available. Incompatible materials Incompatible with strong bases and oxidizing agents. Hazardous decomposition products Upon decomposition, this product may yield gaseous nitrogen oxides, carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. 11. Toxicological information Symptoms related to the physical, chemical and toxicological characteristics Not available. Information on toxicological effects Acute toxicity Based on available data, the classification criteria are not met. Skin corrosion/irritation Based on available data, the classification criteria are not met. Serious eye damage/eye irritation Based on available data, the classification criteria are not met. Respiratory or skin sensitization Respiratory sensitization Based on available data, the classification criteria are not met. Skin sensitization Based on available data, the classification criteria are not met. Germ cell mutagenicity Based on available data, the classification criteria are not met. Carcinogenicity Based on available data, the classification criteria are not met. Carbon black is classified as a carcinogen by the IARC (possibly carcinogenic to humans, Group 2B) and by the State of California under Proposition 65. In their evaluations of carbon black, both organizations indicate that exposure to carbon black, per se, does not occur when it remains bound within a product matrix, specifically, rubber, ink, or paint. Carbon black is present only in a bound form in this preparation. IARC Monographs. Overall Evaluation of Carcinogenicity Carbon black (CAS 1333-86-4) 2B Possibly carcinogenic to humans. Reproductive toxicity Based on available data, the classification criteria are not met. 4 / 8 Material name: 51645 Series 9235 Version #: 01 Issue date: 01-Apr-2015 SDS US Specific target organ toxicity - single exposure Based on available data, the classification criteria are not met. Specific target organ toxicity - repeated exposure Based on available data, the classification criteria are not met. Aspiration hazard Based on available data, the classification criteria are not met. Further information Complete toxicity data are not available for this specific formulation Refer to Section 2 for potential health effects and Section 4 for first aid measures. Test ResultsComponents Species 2-pyrrolidone (CAS 616-45-5) LD50 Guinea pig Oral Acute 6500 mg/kg Rat 6500 mg/kg Carbon black (CAS 1333-86-4) LD50 Rat Oral Acute > 8000 mg/kg Isopropyl alcohol (CAS 67-63-0) LD50 Rabbit Dermal Acute 12800 mg/kg LD50 Dog Oral 4797 mg/kg Mouse 3600 mg/kg Rabbit 5.03 g/kg Rat 4.7 g/kg LD50 Mouse Other 1509 mg/kg Rat 1099 mg/kg 12. Ecological information Aquatic toxicity Not expected to be harmful to aquatic organisms. Ecotoxicity Product Test ResultsSpecies 51645 Series (CAS Mixture) Aquatic Acute LC50Fish > 750 mg/l, 96 hoursFathead minnow (Pimephales promelas) Components Test ResultsSpecies 2-pyrrolidone (CAS 616-45-5) Aquatic EC50Crustacea 13.21 mg/l, 48 hoursWater flea (Daphnia pulex) Isopropyl alcohol (CAS 67-63-0) Aquatic LC50Fish > 1400 mg/l, 96 hoursBluegill (Lepomis macrochirus) Acute EC50Algae > 1000 mg/l, 72 hoursAlgae EC50Crustacea 13299 mg/l, 48 hoursDaphnia LC50Fish 9460 mg/l, 96 hoursFathead minnow (Pimephales promelas) Persistence and degradability No data is available on the degradability of this product. 5 / 8 Material name: 51645 Series 9235 Version #: 01 Issue date: 01-Apr-2015 SDS US Bioaccumulative potential Not available. Partition coefficient n-octanol / water (log Kow) 2-pyrrolidone -0.85 Isopropyl alcohol 0.05 Mobility in soil Not available. Other adverse effects Not available. 13. Disposal considerations Disposal instructions Do not allow this material to drain into sewers/water supplies. Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations. HP's Planet Partners (trademark) supplies recycling program enables simple, convenient recycling of HP original inkjet and LaserJet supplies. For more information and to determine if this service is available in your location, please visit http://www.hp.com/recycle. Contaminated packaging No special precautions. 14. Transport information DOT Not regulated as dangerous goods. IATA Not regulated as dangerous goods. IMDG Not regulated as dangerous goods. ADR Not regulated as dangerous goods. Further information Not a dangerous good under DOT, IATA, ADR, IMDG, or RID. No ignition, sustained combustion, or flashing detected, using the Sustained Combustibility Test prescribed in the UN Manual of Tests and Criteria, Part III subsection 32.5.2. Refer to Dangerous Goods Regulations Section 3.3.1.3. No ignition, sustained combustion or flashing detected using the sustained combustibility test (method in US CFR173, Appendix H). 15. Regulatory information US federal regulations US TSCA 12(b): Does not contain listed chemicals. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous chemical No 6 / 8 Material name: 51645 Series 9235 Version #: 01 Issue date: 01-Apr-2015 SDS US Other federal regulations Safe Drinking Water Act (SDWA) Not regulated. US state regulations US. Massachusetts RTK - Substance List 2-pyrrolidone (CAS 616-45-5) Carbon black (CAS 1333-86-4) Isopropyl alcohol (CAS 67-63-0) US. New Jersey Worker and Community Right-to-Know Act Carbon black (CAS 1333-86-4) Isopropyl alcohol (CAS 67-63-0) US. Pennsylvania Worker and Community Right-to-Know Law 2-pyrrolidone (CAS 616-45-5) Carbon black (CAS 1333-86-4) Isopropyl alcohol (CAS 67-63-0) US. Rhode Island RTK Isopropyl alcohol (CAS 67-63-0) US. California Proposition 65 US - California Proposition 65 - CRT: Listed date/Carcinogenic substance CARBON BLACK (AIRBORNE, UNBOUND PARTICLES OF RESPIRABLE SIZE [<= 10 MICROMETERS]) (CAS 1333-86-4) Listed: February 21, 2003 Other information VOC content (less water, less exempt compounds) = <592.5 g/L (U.S. requirement, not for emissions) VOC data based on formulation (Organic compounds minus solids) Regulatory information All chemical substances in this HP product have been notified or are exempt from notification under chemical substances notification laws in the following countries: US (TSCA), EU (EINECS/ELINCS), Switzerland, Canada (DSL/NDSL), Australia, Japan, Philippines, South Korea, New Zealand, and China. 16. Other information, including date of preparation or last revision Issue date 01-Apr-2015 Version #01 Disclaimer This Safety Data Sheet document is provided without charge to customers of Hewlett-Packard Company. Data is the most current known to Hewlett-Packard Company at the time of preparation of this document and is believed to be accurate. It should not be construed as guaranteeing specific properties of the products as described or suitability for a particular application. This document was prepared to the requirements of the jurisdiction specified in Section 1 above and may not meet regulatory requirements in other countries. Revision Information Product and Company Identification: Product Uses Composition / Information on Ingredients Physical & Chemical Properties: Multiple Properties Toxicological Information: Toxicological Data Ecological Information: Ecotoxicity 15. Regulatory Information: Risk Phrases - Labeling GHS: Classification Manufacturer information Hewlett-Packard Company 3000 Hanover Street Palo Alto, California 94304-1112 US Direct 1-650-857-5020 7 / 8 Material name: 51645 Series 9235 Version #: 01 Issue date: 01-Apr-2015 SDS US Explanation of abbreviations ACGIH CAS DOT EPCRA CERCLA CFR COC IARC NIOSH NTP OSHA PEL RCRA REC REL SARA STEL TCLP TLV TSCA VOC American Conference of Governmental Industrial Hygienists Chemical Abstracts Service Comprehensive Environmental Response Compensation and Liability Act Code of Federal Regulations Cleveland Open Cup Department of Transportation Emergency Planning and Community Right-to-Know Act (aka SARA) International Agency for Research on Cancer National Institute for Occupational Safety and Health National Toxicology Program Occupational Safety and Health Administration Permissible Exposure Limit Resource Conservation and Recovery Act Recommended Recommended Exposure Limit Superfund Amendments and Reauthorization Act of 1986 Short-Term Exposure Limit Toxicity Characteristics Leaching Procedure Threshold Limit Value Toxic Substances Control Act Volatile Organic Compounds 8 / 8 Material name: 51645 Series 9235 Version #: 01 Issue date: 01-Apr-2015 SDS US