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HomeMy WebLinkAbout2-in-1 Correction FluidNewellRubbermaid SAFETY DATA SHEET Brands That Matter Section 1.Identification Product name Material uses Manufacturer Emergency telephone number (with hours of operation) : 2-in-1 Correction Fluid,Fast Dry Correction Fluid,PMOP Correction Fluid,Smooth Coverage Correction Fluid :Correction fluid Newell Rubbermaid 3500 Lacey Road,10th Floor Downers Grove,IL 60515 USA 800-323-0749 or 630-829-2500 CHEMTREC (U.S.and Canada)1-800-424-9300 Section 2.Hazards identification OSHA/HCS status Classification of the substance or mixture GHS label elements Hazard pictograms Signal word Hazard statements Precautionary statements General Prevention Response Storage Disposal Hazards not otherwise classified This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). FLAMMABLE LIQUIDS -Category 2 TOXIC TO REPRODUCTION (Fertility) -Category 2 Danger Highlyflammable liquidand vapor. Suspected of damaging fertility. Read label before use.If medical advice is needed,have product container or label at hand. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood.Use personal protective equipment as required.Wear protective gloves. Wear eye orface protection. Keep away from heat, hot surfaces, sparks,open flames and other ignition sources.No smoking.Use explosion-proof electrical,ventilating, lighting and all material-handling equipment.Use only non- sparking tools. Take precautionary measures against static discharge.Keep container tightly closed. IF exposed or concerned:Get medical attention. IF ON SKIN (or hair):Take off immediately all contaminated clothing.Rinse skin with water or shower. Store locked up.Store in a well-ventilated place.Keep cool. Dispose of contents and container in accordance with all local, regional, national and international regulations. None known. 2-in-1 Correction Fluid, Fast Dry Correction Fluid,PMOP Correction Fluid,Smooth Coverage Correction Fluid Section 3.Composition/information on ingredients Substance/mixture :Mixture Ingredient name %CAS number n-hexane 2-5 110-54-3 Any concentration shown as a range is to protect confidentialityor is due to batch variation. There are no additional ingredients present which,within the current knowledge ofthe supplier and in the concentrations applicable,are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits,if available,are listed in Section 8. Section 4.First aid measures Description of necessary first aid measures Eye contact Inhalation Skin contact Ingestion Immediatelyflush eyes with plentyofwater, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses.Continue to rinse for at least 10 minutes.Get medical attention if irritation occurs. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing,ifbreathing is irregular or ifrespiratoryarrest occurs, provide artificial respirationor oxygen by trainedpersonnel. Itmay be dangerous to the person providing aidto give mouth-to-mouth resuscitation.Get medical attention.If unconscious,place in recovery position and get medical attention immediately.Maintain an open airway. Loosen tightclothing such as a collar,tie, belt or waistband. Flush contaminated skin with plentyofwater. Remove contaminated clothingand shoes.Continue to rinse for at least 10 minutes.Get medical attention.Wash clothing before reuse.Clean shoes thoroughly before reuse. Wash out mouth withwater.Remove dentures ifany.Remove victim to fresh air and keepat rest in a position comfortable for breathing.If material has been swallowed and the exposed person is conscious,give small quantities ofwaterto drink.Stop if the exposed person feels sick as vomiting may be dangerous.Do notinduce vomiting unless directed todo so by medical personnel.If vomiting occurs,the head should be kept low so that vomit does notenterthe lungs.Get medical attention.Nevergive anything by mouth toan unconscious person.If unconscious,place in recovery position and get medical attention immediately.Maintain an open airway.Loosen tight clothing such as a collar, tie, belt or waistband. Most important svmptoms/effects.acute and delayed Potential acute health effects Eye contact Inhalation Skin contact Ingestion Over-exposure siqns/svmptoms Eye contact : No specific data. Inhalation :Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations Skin contact :Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations Ingestion :Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. 2-in-1Correction Fluid,Fast DryCorrection Fluid,PMOPCorrection Fluid,Smooth Coverage Correction Fluid Section 4.First aid measures Indication of immediate medical attention and special treatment needed,if necessary Notes to physician Specific treatments Protection of first-aiders Treat symptomatically. Contact poison treatment specialist immediately iflarge quantities have been ingested or inhaled. No specific treatment. No action shall be taken involving any personal risk or without suitable training. Itmay be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Seetoxicological information (Section 11) Section 5.Fire-fighting measures Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Hazardous thermal decomposition products Special protective actions for fire-fighters Special protective equipment for fire-fighters : Use drychemical,CO2,water spray (fog)or foam. : Do not use water jet. Highly flammable liquid and vapor.In a fire or if heated, a pressure increase will occur and the containermayburst,with the riskofa subsequent explosion.Runoff to sewer may create fire or explosion hazard. Decomposition products may includethe following materials: carbon dioxide carbon monoxide metal oxide/oxides Promptly isolate thescene by removing all persons from the vicinity ofthe incident if there is a fire.Noaction shall be taken involving any personal riskor withoutsuitable training.Move containers from fire area if this can bedone without risk.Usewater spray to keep fire-exposed containers cool. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA)with a full face-piece operated in positive pressure mode. Section 6.Accidental release measures Personal precautions,protective eouipment and emergency procedures No actionshall be taken involving any personal riskor without suitable training. Evacuate surrounding areas.Keep unnecessary and unprotected personnelfrom entering.Do nottouch orwalk through spilled material.Shut off all ignition sources. No flares,smoking or flames in hazardarea.Avoid breathing vaporor mist.Provide adequate ventilation.Wearappropriate respirator when ventilation is inadequate.Put on appropriate personal protective equipment. :If specialised clothing is required to deal with the spillage,take noteofany information in Section 8 on suitable and unsuitable materials.See also the information in"For non emergency personnel". :Avoid dispersal ofspilled material and runoff and contact with soil,waterways,drains and sewers.Informthe relevant authorities ifthe product has caused environmental pollution (sewers,waterways, soil or air). For non-emergency personnel For emergency responders Environmental precautions Methods and materials for containment and cleaning up Small spill :Stop leak if without risk.Move containers from spill area.Use spark-proof tools and explosion-proof equipment.Dilute with water and mop up if water-soluble.Alternatively, or ifwater-insoluble,absorb withan inert dry material and place in an appropriate waste disposal container. Dispose ofvia a licensed waste disposal contractor. 2-in-1 Correction Fluid, Fast DryCorrection Fluid, PMOP Correction Fluid,Smooth Coverage Correction Fluid Section 6.Accidental release measures Large spill Stop leak ifwithout risk. Move containers from spill area.Use spark-proof tools and explosion-proof equipment.Approach release from upwind.Prevent entry into sewers, water courses,basements or confined areas.Wash spillages into an effluent treatment plant or proceed as follows.Contain and collect spillage with non-combustible, absorbent material e.g.sand,earth,vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13).Dispose of via a licensed waste disposal contractor.Contaminated absorbent material may pose the same hazard as the spilled product.Note:see Section 1 for emergency contact information and Section 13 for waste disposal. Section 7.Handling and storage Precautions for safe handling Protective measures Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Put on appropriate personal protective equipment (see Section 8). Avoid exposure - obtain special instructions before use.Avoid exposure during pregnancy.Do not handle untilall safety precautions have been read and understood.Do not get in eyes or on skin or clothing. Do not ingest. Avoidbreathing vapor or mist. Use onlywith adequate ventilation.Wear appropriate respirator when ventilation is inadequate.Do not enter storage areas and confined spaces unless adequately ventilated. Keep inthe original container or an approved alternative made from a compatible material, kept tightly closed when not in use.Store and use away from heat,sparks,open flame or any other ignition source.Use explosion-proof electrical (ventilating,lighting and material handling) equipment. Use only non-sparking tools.Take precautionary measures against electrostatic discharges.Empty containers retain product residue and can be hazardous.Do not reuse container. Eating,drinking and smoking should be prohibited in areas where this material is handled,stored and processed.Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothingand protective equipment before entering eating areas.See also Section 8 for additional informationon hygiene measures. Store in accordance with local regulations.Store ina segregated and approved area. Store in original container protected from directsunlight in a dry,cool and well-ventilated area, away from incompatible materials(see Section 10)and food and drink.Store locked up.Eliminate all ignition sources.Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use.Containers that have been opened mustbe carefully resealed and keptupright to preventleakage. Donotstore in unlabeled containers.Use appropriate containment to avoid environmental contamination. Section 8.Exposure controls/personal protection Control parameters Occupational exposure limits Ingredient name Exposure limits n-hexane ACGIH TLV (United States,6/2013). Absorbed through skin. TWA:50 ppm 8 hours. OSHA PEL 1989 (United States,3/1989). TWA: 50 ppm 8 hours. TWA:180mg/m38hours. NIOSH REL (United States,10/2013). TWA:50 ppm 10 hours. TWA:180 mg/m310 hours. OSHA PEL (United States,2/2013). TWA:500 ppm 8 hours. TWA:1800 mg/m3 8 hours. 2-in-1 Correction Fluid,FastDry Correction Fluid,PMOP Correction Fluid,Smooth CoverageCorrection Fluid Section 8.Exposure controls/personal protection Appropriate engineering controls Environmental exposure controls Use onlywith adequate ventilation.Use process enclosures,local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.The engineering controls also need to keep gas, vapor or dust concentrations belowany lowerexplosive limits.Use explosion-proof ventilation equipment. Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements ofenvironmental protection legislation. Insome cases,fume scrubbers,filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Individual protection measures Hygiene measures :Wash hands,forearms and face thoroughly after handling chemical products,before eating, smoking and using the lavatory and at the end ofthe working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing.Ensure that eyewash stations and safety showers are close to the workstation location. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes,mists, gases or dusts.If contact is possible, the following protection should be worn,unless the assessment indicates a higher degree of protection:safety glasses with side- shields. Chemical-resistant,impervious gloves complying with an approved standard should be worn at alltimes when handling chemical products ifa risk assessment indicates this is necessary.Considering the parameters specified bythe glove manufacturer,check during use thatthe gloves are still retaining theirprotective properties.It should be noted that the time to breakthrough for any glove material may be differentfor different glove manufacturers.In thecase ofmixtures,consisting ofseveral substances,the protection timeofthe glovescannot be accurately estimated. Personal protective equipment for the body should be selected based onthe task being performed andthe risks involved and should be approved by a specialist before handling this product.When thereisa risk of ignition from staticelectricity,wear anti static protective clothing.For thegreatest protection from static discharges,clothing should include anti-static overalls,boots and gloves. Appropriate footwear and any additional skin protection measures should be selected based onthe task being performed and the risks involved and shouldbe approved by a specialist before handling this product. Usea properly fitted,air-purifying orair-fed respirator complying with an approved standard ifa risk assessment indicates this is necessary.Respirator selection must be based on known or anticipated exposure levels,the hazards ofthe productand the safe working limits of the selected respirator. Eye/face protection Skin protection Hand protection Body protection Other skin protection Respiratory protection Section 9.Physical and chemical properties Appearance Physical state Color Odor Odor threshold pH Melting point Boiling point Flash point Burning time Burning rate Evaporation rate : Liquid. :White. :Not available. :Not available. : Not applicable. :Not available. :Not available. :Closed cup:-10°C(14°F) : Not applicable. : Not applicable. :Not available. 2-in-1 Correction Fluid,Fast Dry Correction Fluid,PMOP Correction Fluid,Smooth CoverageCorrection Fluid Section 9.Physical and chemical properties Lower and upper explosive (flammable)limits Vapor pressure Vapor density Relative density Solubility Solubility in water Partition coefficient:n- octanol/water Auto-ignition temperature Decomposition temperature SADT Viscosity Not available. Not available. Not available. Not available. Not available. Not available. Not available. Not available. Not available. Not available. Not available. Section 10.Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials : No specific test data related to reactivity available for this product or its ingredients. :The product is stable. :Under normal conditions of storage and use,hazardous reactions will not occur. : Avoid all possible sources of ignition (spark or flame). Do not pressurize,cut, weld, braze, solder,drill,grind or expose containers to heat or sources of ignition. :Reactive or incompatible with the following materials: oxidizing materials Hazardous decomposition : Undernormal conditions ofstorage and use, hazardous decomposition products should products not be produced. Section 11.Toxicological information Information on toxicoloaical effects Acute toxicity Product/ingredient name Result Species Dose Exposure n-hexane LC50 Inhalation Gas. LD50 Oral Rat Rat 48000 ppm 15840 mg/kg 4 hours Irritation/Corrosion Product/ingredient name Result Species Score Exposure Observation n-hexane Eyes - Mild irritant Rabbit -10 milligrams - Sensitization No known significant effects or critical hazards. Mutagenicity No known significant effects or critical hazards. Carcinogenicity No known significant effects or critical hazards. Reproductive toxicity No known significant effects or critical hazards. 2-in-1 Correction Fluid,FastDry Correction Fluid,PMOP Correction Fluid,SmoothCoverageCorrection Fluid Section 11.Toxicological information Teratogenicity No known significant effects or critical hazards. Specific target organ toxicity (single exposure) Name Category Route of exposure Target organs n-hexane Category 3 Not applicable.Narcotic effects Specific target organ toxicity (repeated exposure) Name Category Route of exposure Target organs n-hexane Category 2 Not determined Not determined Aspiration hazard Name Result n-hexane ASPIRATION HAZARD -Category 1 Information on the likely routes of exposure :Not available. Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Potential immediate :Not available. effects Potential delayed effects : Not available. Long term exposure Potential immediate :Not available. effects Potential delayed effects Potential chronic health effects General Carcinogenicity Mutagenicity Teratogenicity Developmental effects Fertility effects Suspected of damaging fertility. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. Suspected of damaging fertility. Numerical measures of toxicity Acute toxicity estimates No known significant effects or critical hazards. Section 12.Ecological information Toxicity Product/ingredient name Result Species Exposure n-hexane Acute LC50 2500 ug/l Fresh water Fish -Pimephales promelas 96 hours Persistence and degradabilitv 2-in-1 Correction Fluid,Fast Dry Correction Fluid, PMOP Correction Fluid,Smooth Coverage Correction Fluid Section 12.Ecological information Bioaccumulative potential Product/ingredient name LogPow BCF Potential n-hexane 4 501.187 high Other adverse effects No known significant effects or critical hazards. Section 13.Disposal considerations Disposal methods The generation of waste should be avoided or minimized wherever possible.Disposal of this product,solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.Waste should not be disposed of untreated to the sewer unless fully compliant withthe requirements of all authorities withjurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is notfeasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from productresidues maycreate a highly flammableor explosiveatmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughlyinternally.Avoid dispersal ofspilled material and runoffand contact with soil,waterways,drains and sewers. Section 14.Transport information DOT Classification TDG Classification Mexico Classification IMDG IATA UN number UN1993 UN1993 UN1993 UN1993 UN1993 UN proper shipping name FLAMMABLE LIQUIDS,N.O.S. (Naphtha (petroleum), hydrotreated light, n-hexane) FLAMMABLE LIQUIDS,N.O.S. (Naphtha (petroleum), hydrotreated light, n-hexane) FLAMMABLE LIQUIDS,N.O.S. (Naphtha (petroleum), hydrotreated light, n-hexane) FLAMMABLE LIQUIDS,N.O.S. (Naphtha (petroleum), hydrotreated light, n-hexane).Marine pollutant (titanium dioxide,n-hexane) FLAMMABLE LIQUIDS,N.O.S. (Naphtha (petroleum), hydrotreated light, n-hexane) Transport hazard class(es) 3 3 3 3 3 Packing group II II II II II Environmental hazards No.No.No.Yes.No. Additional information The marine pollutant mark is not required when transported in sizes of <5 L or <5 kg. The environmentally hazardous substance mark may appear if required by other transportation regulations. 2-in-1 CorrectionFluid, Fast DryCorrection Fluid, PMOP Correction Fluid,Smooth Coverage Correction Fluid Section 14.Transport information Special precautions for user Transport within user's premises:always transport in closed containers that are upright and secure.Ensure that persons transporting the product know what to do inthe event of an accident or spillage. Section 15.Regulatory information United States inventory (TSCA 8b):All components are listed or exempted.U.S.Federal regulations SARA 311/312 Classification :Fire hazard Delayed (chronic)health hazard Composition/information on ingredients Name %Fire hazard Sudden release of pressure Reactive Immediate (acute) health hazard Delayed (chronic) health hazard n-hexane 2-5 Yes.No.No.Yes.Yes. SARA 313 Product name CAS number % Form R -Reporting requirements n-hexane 110-54-3 2-5 Supplier notification n-hexane 110-54-3 2-5 SARA 313 notifications must not be detached from the SDS and any copying and redistributionof the SDS shall include copying and redistribution of the notice attached to copies ofthe SDS subsequently redistributed. California Prop.65 This product does not contain Chemicals known to State of California to cause cancer,birth defects,orreproductive harm. Canada WHMIS (Canada) Canadian lists Canadian NPRI CEPA Toxic substances Canada inventory Class B-2:Flammable liquid Class D-2A:Material causing other toxiceffects (Very toxic). The following components are listed:n-Hexane;Heavy alkylate naphtha None of the components are listed. All components are listed or exempted. Section 16.Other information History Date of issue/Date of revision Date of previous issue Version Prepared by Key to abbreviations 5/28/2015. 5/27/2015. 2 Product Safety. ATE =Acute Toxicity Estimate BCF =Bioconcentration Factor GHS =Globally Harmonized System of Classification and Labelling ofChemicals IATA=International Air Transport Association IMDG =International Maritime Dangerous Goods LogPow=logarithm of the octanol/water partition coefficient UN =United Nations vindicates information that has changed from previously issued version. 2-in-1Correction Fluid,Fast DryCorrection Fluid,PMOPCorrection Fluid,Smooth Coverage Correction Fluid Section 16.Other information Since the user's working conditions are not known by us, the information supplied on this safety data sheet is based on our current level of knowledge and on national and community regulations.The mixture must not be used for other uses than those specified in section 1without having first obtained written handling instructions.It isat all timesthe responsibility ofthe user totake allnecessary measures to comply with legalrequirementsand local regulations.The information inthis safety datasheet must be regardedas a descriptionofthe safety requirements relating to the mixture and not as a guarantee of the properties thereof. Dateofissue/Dateofrevision :5/28/2015.Dateofpreviousissue :5/27/2015.Version :2 10/10