HomeMy WebLinkAbout2-in-1 Correction FluidNewellRubbermaid SAFETY DATA SHEET
Brands That Matter
Section 1.Identification
Product name
Material uses
Manufacturer
Emergency telephone
number (with hours of
operation)
: 2-in-1 Correction Fluid,Fast Dry Correction Fluid,PMOP Correction Fluid,Smooth
Coverage Correction Fluid
:Correction fluid
Newell Rubbermaid
3500 Lacey Road,10th Floor
Downers Grove,IL 60515
USA
800-323-0749 or 630-829-2500
CHEMTREC (U.S.and Canada)1-800-424-9300
Section 2.Hazards identification
OSHA/HCS status
Classification of the
substance or mixture
GHS label elements
Hazard pictograms
Signal word
Hazard statements
Precautionary statements
General
Prevention
Response
Storage
Disposal
Hazards not otherwise
classified
This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
FLAMMABLE LIQUIDS -Category 2
TOXIC TO REPRODUCTION (Fertility) -Category 2
Danger
Highlyflammable liquidand vapor.
Suspected of damaging fertility.
Read label before use.If medical advice is needed,have product container or label at
hand.
Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood.Use personal protective equipment as required.Wear
protective gloves. Wear eye orface protection. Keep away from heat, hot surfaces,
sparks,open flames and other ignition sources.No smoking.Use explosion-proof
electrical,ventilating, lighting and all material-handling equipment.Use only non-
sparking tools. Take precautionary measures against static discharge.Keep container
tightly closed.
IF exposed or concerned:Get medical attention. IF ON SKIN (or hair):Take off
immediately all contaminated clothing.Rinse skin with water or shower.
Store locked up.Store in a well-ventilated place.Keep cool.
Dispose of contents and container in accordance with all local, regional, national and
international regulations.
None known.
2-in-1 Correction Fluid, Fast Dry Correction Fluid,PMOP Correction Fluid,Smooth Coverage Correction Fluid
Section 3.Composition/information on ingredients
Substance/mixture :Mixture
Ingredient name %CAS number
n-hexane 2-5 110-54-3
Any concentration shown as a range is to protect confidentialityor is due to batch variation.
There are no additional ingredients present which,within the current knowledge ofthe supplier and in the
concentrations applicable,are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits,if available,are listed in Section 8.
Section 4.First aid measures
Description of necessary first aid measures
Eye contact
Inhalation
Skin contact
Ingestion
Immediatelyflush eyes with plentyofwater, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses.Continue to rinse for at least 10
minutes.Get medical attention if irritation occurs.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing,ifbreathing is irregular or ifrespiratoryarrest occurs, provide artificial
respirationor oxygen by trainedpersonnel. Itmay be dangerous to the person providing
aidto give mouth-to-mouth resuscitation.Get medical attention.If unconscious,place
in recovery position and get medical attention immediately.Maintain an open airway.
Loosen tightclothing such as a collar,tie, belt or waistband.
Flush contaminated skin with plentyofwater. Remove contaminated clothingand
shoes.Continue to rinse for at least 10 minutes.Get medical attention.Wash clothing
before reuse.Clean shoes thoroughly before reuse.
Wash out mouth withwater.Remove dentures ifany.Remove victim to fresh air and
keepat rest in a position comfortable for breathing.If material has been swallowed and
the exposed person is conscious,give small quantities ofwaterto drink.Stop if the
exposed person feels sick as vomiting may be dangerous.Do notinduce vomiting
unless directed todo so by medical personnel.If vomiting occurs,the head should be
kept low so that vomit does notenterthe lungs.Get medical attention.Nevergive
anything by mouth toan unconscious person.If unconscious,place in recovery position
and get medical attention immediately.Maintain an open airway.Loosen tight clothing
such as a collar, tie, belt or waistband.
Most important svmptoms/effects.acute and delayed
Potential acute health effects
Eye contact
Inhalation
Skin contact
Ingestion
Over-exposure siqns/svmptoms
Eye contact : No specific data.
Inhalation :Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Skin contact :Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Ingestion :Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
2-in-1Correction Fluid,Fast DryCorrection Fluid,PMOPCorrection Fluid,Smooth Coverage Correction Fluid
Section 4.First aid measures
Indication of immediate medical attention and special treatment needed,if necessary
Notes to physician
Specific treatments
Protection of first-aiders
Treat symptomatically. Contact poison treatment specialist immediately iflarge
quantities have been ingested or inhaled.
No specific treatment.
No action shall be taken involving any personal risk or without suitable training. Itmay
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Seetoxicological information (Section 11)
Section 5.Fire-fighting measures
Extinguishing media
Suitable extinguishing
media
Unsuitable extinguishing
media
Specific hazards arising
from the chemical
Hazardous thermal
decomposition products
Special protective actions
for fire-fighters
Special protective
equipment for fire-fighters
: Use drychemical,CO2,water spray (fog)or foam.
: Do not use water jet.
Highly flammable liquid and vapor.In a fire or if heated, a pressure increase will occur
and the containermayburst,with the riskofa subsequent explosion.Runoff to sewer
may create fire or explosion hazard.
Decomposition products may includethe following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides
Promptly isolate thescene by removing all persons from the vicinity ofthe incident if
there is a fire.Noaction shall be taken involving any personal riskor withoutsuitable
training.Move containers from fire area if this can bedone without risk.Usewater
spray to keep fire-exposed containers cool.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA)with a full face-piece operated in positive pressure mode.
Section 6.Accidental release measures
Personal precautions,protective eouipment and emergency procedures
No actionshall be taken involving any personal riskor without suitable training.
Evacuate surrounding areas.Keep unnecessary and unprotected personnelfrom
entering.Do nottouch orwalk through spilled material.Shut off all ignition sources.
No flares,smoking or flames in hazardarea.Avoid breathing vaporor mist.Provide
adequate ventilation.Wearappropriate respirator when ventilation is inadequate.Put
on appropriate personal protective equipment.
:If specialised clothing is required to deal with the spillage,take noteofany information
in Section 8 on suitable and unsuitable materials.See also the information in"For non
emergency personnel".
:Avoid dispersal ofspilled material and runoff and contact with soil,waterways,drains
and sewers.Informthe relevant authorities ifthe product has caused environmental
pollution (sewers,waterways, soil or air).
For non-emergency
personnel
For emergency responders
Environmental precautions
Methods and materials for containment and cleaning up
Small spill :Stop leak if without risk.Move containers from spill area.Use spark-proof tools and
explosion-proof equipment.Dilute with water and mop up if water-soluble.Alternatively,
or ifwater-insoluble,absorb withan inert dry material and place in an appropriate waste
disposal container. Dispose ofvia a licensed waste disposal contractor.
2-in-1 Correction Fluid, Fast DryCorrection Fluid, PMOP Correction Fluid,Smooth Coverage Correction Fluid
Section 6.Accidental release measures
Large spill Stop leak ifwithout risk. Move containers from spill area.Use spark-proof tools and
explosion-proof equipment.Approach release from upwind.Prevent entry into sewers,
water courses,basements or confined areas.Wash spillages into an effluent treatment
plant or proceed as follows.Contain and collect spillage with non-combustible,
absorbent material e.g.sand,earth,vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13).Dispose of via a
licensed waste disposal contractor.Contaminated absorbent material may pose the
same hazard as the spilled product.Note:see Section 1 for emergency contact
information and Section 13 for waste disposal.
Section 7.Handling and storage
Precautions for safe handling
Protective measures
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Put on appropriate personal protective equipment (see Section 8). Avoid exposure -
obtain special instructions before use.Avoid exposure during pregnancy.Do not
handle untilall safety precautions have been read and understood.Do not get in eyes
or on skin or clothing. Do not ingest. Avoidbreathing vapor or mist. Use onlywith
adequate ventilation.Wear appropriate respirator when ventilation is inadequate.Do
not enter storage areas and confined spaces unless adequately ventilated. Keep inthe
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use.Store and use away from heat,sparks,open flame or
any other ignition source.Use explosion-proof electrical (ventilating,lighting and
material handling) equipment. Use only non-sparking tools.Take precautionary
measures against electrostatic discharges.Empty containers retain product residue
and can be hazardous.Do not reuse container.
Eating,drinking and smoking should be prohibited in areas where this material is
handled,stored and processed.Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothingand protective equipment before
entering eating areas.See also Section 8 for additional informationon hygiene
measures.
Store in accordance with local regulations.Store ina segregated and approved area.
Store in original container protected from directsunlight in a dry,cool and well-ventilated
area, away from incompatible materials(see Section 10)and food and drink.Store
locked up.Eliminate all ignition sources.Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use.Containers that have been
opened mustbe carefully resealed and keptupright to preventleakage. Donotstore in
unlabeled containers.Use appropriate containment to avoid environmental
contamination.
Section 8.Exposure controls/personal protection
Control parameters
Occupational exposure limits
Ingredient name Exposure limits
n-hexane ACGIH TLV (United States,6/2013).
Absorbed through skin.
TWA:50 ppm 8 hours.
OSHA PEL 1989 (United States,3/1989).
TWA: 50 ppm 8 hours.
TWA:180mg/m38hours.
NIOSH REL (United States,10/2013).
TWA:50 ppm 10 hours.
TWA:180 mg/m310 hours.
OSHA PEL (United States,2/2013).
TWA:500 ppm 8 hours.
TWA:1800 mg/m3 8 hours.
2-in-1 Correction Fluid,FastDry Correction Fluid,PMOP Correction Fluid,Smooth CoverageCorrection Fluid
Section 8.Exposure controls/personal protection
Appropriate engineering
controls
Environmental exposure
controls
Use onlywith adequate ventilation.Use process enclosures,local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits.The engineering controls also need to keep gas,
vapor or dust concentrations belowany lowerexplosive limits.Use explosion-proof
ventilation equipment.
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements ofenvironmental protection legislation. Insome
cases,fume scrubbers,filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Individual protection measures
Hygiene measures :Wash hands,forearms and face thoroughly after handling chemical products,before
eating, smoking and using the lavatory and at the end ofthe working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing.Ensure that eyewash stations and safety
showers are close to the workstation location.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes,mists,
gases or dusts.If contact is possible, the following protection should be worn,unless
the assessment indicates a higher degree of protection:safety glasses with side-
shields.
Chemical-resistant,impervious gloves complying with an approved standard should be
worn at alltimes when handling chemical products ifa risk assessment indicates this is
necessary.Considering the parameters specified bythe glove manufacturer,check
during use thatthe gloves are still retaining theirprotective properties.It should be
noted that the time to breakthrough for any glove material may be differentfor different
glove manufacturers.In thecase ofmixtures,consisting ofseveral substances,the
protection timeofthe glovescannot be accurately estimated.
Personal protective equipment for the body should be selected based onthe task being
performed andthe risks involved and should be approved by a specialist before
handling this product.When thereisa risk of ignition from staticelectricity,wear anti
static protective clothing.For thegreatest protection from static discharges,clothing
should include anti-static overalls,boots and gloves.
Appropriate footwear and any additional skin protection measures should be selected
based onthe task being performed and the risks involved and shouldbe approved by a
specialist before handling this product.
Usea properly fitted,air-purifying orair-fed respirator complying with an approved
standard ifa risk assessment indicates this is necessary.Respirator selection must be
based on known or anticipated exposure levels,the hazards ofthe productand the safe
working limits of the selected respirator.
Eye/face protection
Skin protection
Hand protection
Body protection
Other skin protection
Respiratory protection
Section 9.Physical and chemical properties
Appearance
Physical state
Color
Odor
Odor threshold
pH
Melting point
Boiling point
Flash point
Burning time
Burning rate
Evaporation rate
: Liquid.
:White.
:Not available.
:Not available.
: Not applicable.
:Not available.
:Not available.
:Closed cup:-10°C(14°F)
: Not applicable.
: Not applicable.
:Not available.
2-in-1 Correction Fluid,Fast Dry Correction Fluid,PMOP Correction Fluid,Smooth CoverageCorrection Fluid
Section 9.Physical and chemical properties
Lower and upper explosive
(flammable)limits
Vapor pressure
Vapor density
Relative density
Solubility
Solubility in water
Partition coefficient:n-
octanol/water
Auto-ignition temperature
Decomposition temperature
SADT
Viscosity
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Section 10.Stability and reactivity
Reactivity
Chemical stability
Possibility of hazardous
reactions
Conditions to avoid
Incompatible materials
: No specific test data related to reactivity available for this product or its ingredients.
:The product is stable.
:Under normal conditions of storage and use,hazardous reactions will not occur.
: Avoid all possible sources of ignition (spark or flame). Do not pressurize,cut, weld,
braze, solder,drill,grind or expose containers to heat or sources of ignition.
:Reactive or incompatible with the following materials:
oxidizing materials
Hazardous decomposition : Undernormal conditions ofstorage and use, hazardous decomposition products should
products not be produced.
Section 11.Toxicological information
Information on toxicoloaical effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
n-hexane LC50 Inhalation Gas.
LD50 Oral
Rat
Rat
48000 ppm
15840 mg/kg
4 hours
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
n-hexane Eyes - Mild irritant Rabbit -10 milligrams -
Sensitization
No known significant effects or critical hazards.
Mutagenicity
No known significant effects or critical hazards.
Carcinogenicity
No known significant effects or critical hazards.
Reproductive toxicity
No known significant effects or critical hazards.
2-in-1 Correction Fluid,FastDry Correction Fluid,PMOP Correction Fluid,SmoothCoverageCorrection Fluid
Section 11.Toxicological information
Teratogenicity
No known significant effects or critical hazards.
Specific target organ toxicity (single exposure)
Name Category Route of
exposure
Target organs
n-hexane Category 3 Not applicable.Narcotic effects
Specific target organ toxicity (repeated exposure)
Name Category Route of
exposure
Target organs
n-hexane Category 2 Not determined Not determined
Aspiration hazard
Name Result
n-hexane ASPIRATION HAZARD -Category 1
Information on the likely
routes of exposure
:Not available.
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate :Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate :Not available.
effects
Potential delayed effects
Potential chronic health effects
General
Carcinogenicity
Mutagenicity
Teratogenicity
Developmental effects
Fertility effects
Suspected of damaging fertility.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
Suspected of damaging fertility.
Numerical measures of toxicity
Acute toxicity estimates
No known significant effects or critical hazards.
Section 12.Ecological information
Toxicity
Product/ingredient name Result Species Exposure
n-hexane Acute LC50 2500 ug/l Fresh water Fish -Pimephales promelas 96 hours
Persistence and degradabilitv
2-in-1 Correction Fluid,Fast Dry Correction Fluid, PMOP Correction Fluid,Smooth Coverage Correction Fluid
Section 12.Ecological information
Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
n-hexane 4 501.187 high
Other adverse effects No known significant effects or critical hazards.
Section 13.Disposal considerations
Disposal methods The generation of waste should be avoided or minimized wherever possible.Disposal
of this product,solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor.Waste should not be disposed of untreated to
the sewer unless fully compliant withthe requirements of all authorities withjurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is notfeasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from productresidues maycreate a highly flammableor explosiveatmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughlyinternally.Avoid dispersal ofspilled material and runoffand contact
with soil,waterways,drains and sewers.
Section 14.Transport information
DOT
Classification
TDG
Classification
Mexico
Classification
IMDG IATA
UN number UN1993 UN1993 UN1993 UN1993 UN1993
UN proper
shipping name
FLAMMABLE
LIQUIDS,N.O.S.
(Naphtha
(petroleum),
hydrotreated light,
n-hexane)
FLAMMABLE
LIQUIDS,N.O.S.
(Naphtha
(petroleum),
hydrotreated light,
n-hexane)
FLAMMABLE
LIQUIDS,N.O.S.
(Naphtha
(petroleum),
hydrotreated light,
n-hexane)
FLAMMABLE
LIQUIDS,N.O.S.
(Naphtha
(petroleum),
hydrotreated light,
n-hexane).Marine
pollutant (titanium
dioxide,n-hexane)
FLAMMABLE
LIQUIDS,N.O.S.
(Naphtha
(petroleum),
hydrotreated light,
n-hexane)
Transport
hazard class(es)
3 3 3 3 3
Packing group II II II II II
Environmental
hazards
No.No.No.Yes.No.
Additional
information
The marine
pollutant mark is
not required when
transported in
sizes of <5 L or <5
kg.
The
environmentally
hazardous
substance mark
may appear if
required by other
transportation
regulations.
2-in-1 CorrectionFluid, Fast DryCorrection Fluid, PMOP Correction Fluid,Smooth Coverage Correction Fluid
Section 14.Transport information
Special precautions for user Transport within user's premises:always transport in closed containers that are
upright and secure.Ensure that persons transporting the product know what to do inthe
event of an accident or spillage.
Section 15.Regulatory information
United States inventory (TSCA 8b):All components are listed or exempted.U.S.Federal regulations
SARA 311/312
Classification :Fire hazard
Delayed (chronic)health hazard
Composition/information on ingredients
Name %Fire
hazard
Sudden
release of
pressure
Reactive Immediate
(acute)
health
hazard
Delayed
(chronic)
health
hazard
n-hexane 2-5 Yes.No.No.Yes.Yes.
SARA 313
Product name CAS number %
Form R -Reporting
requirements
n-hexane 110-54-3 2-5
Supplier notification n-hexane 110-54-3 2-5
SARA 313 notifications must not be detached from the SDS and any copying and redistributionof the SDS shall include
copying and redistribution of the notice attached to copies ofthe SDS subsequently redistributed.
California Prop.65
This product does not contain Chemicals known to State of California to cause cancer,birth defects,orreproductive
harm.
Canada
WHMIS (Canada)
Canadian lists
Canadian NPRI
CEPA Toxic substances
Canada inventory
Class B-2:Flammable liquid
Class D-2A:Material causing other toxiceffects (Very toxic).
The following components are listed:n-Hexane;Heavy alkylate naphtha
None of the components are listed.
All components are listed or exempted.
Section 16.Other information
History
Date of issue/Date of
revision
Date of previous issue
Version
Prepared by
Key to abbreviations
5/28/2015.
5/27/2015.
2
Product Safety.
ATE =Acute Toxicity Estimate
BCF =Bioconcentration Factor
GHS =Globally Harmonized System of Classification and Labelling ofChemicals
IATA=International Air Transport Association
IMDG =International Maritime Dangerous Goods
LogPow=logarithm of the octanol/water partition coefficient
UN =United Nations
vindicates information that has changed from previously issued version.
2-in-1Correction Fluid,Fast DryCorrection Fluid,PMOPCorrection Fluid,Smooth Coverage Correction Fluid
Section 16.Other information
Since the user's working conditions are not known by us, the information supplied on this safety data sheet is
based on our current level of knowledge and on national and community regulations.The mixture must not be
used for other uses than those specified in section 1without having first obtained written handling instructions.It
isat all timesthe responsibility ofthe user totake allnecessary measures to comply with legalrequirementsand
local regulations.The information inthis safety datasheet must be regardedas a descriptionofthe safety
requirements relating to the mixture and not as a guarantee of the properties thereof.
Dateofissue/Dateofrevision :5/28/2015.Dateofpreviousissue :5/27/2015.Version :2 10/10