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HomeMy WebLinkAboutbuckeye-juggernaut-floor-stripperSafety Data Sheet Issue Date: 27-Dec-2011 Revision Date: 11-Nov-2016 Version 1 _____________________________________________________________________________________________ EN / HGHS Page 1 / 10 1. IDENTIFICATION Product Identifier Product Name Buckeye Juggernaut Other means of identification SDS # BE-5028-CA Product Code 5028 Synonyms None UN/ID No UN1760 Recommended use of the chemical and restrictions on use Recommended Use Floor finish stripper, water based Uses Advised Against No information available Details of the supplier of the safety data sheet United States Supplier Address Buckeye International, Inc. 2700 Wagner Place Maryland Heights, MO 63043 USA 1-314-291-1900 Initial Supplier Identifier 24 hr Emergency Telephone Numbers TRANSPORTATION - INFOTRAC 1-352-323-3500 (International) 1-800-535-5053 (North America) MEDICAL - 1-651-632-8956 (International) 1-800-303-0441 (North America) 2. HAZARDS IDENTIFICATION Appearance Clear purple solution Physical state Liquid Odour Mild scent No fragrance added Classification Acute toxicity - Inhalation (Dusts/Mists) Category 4 Skin corrosion/irritation Category 1 Sub-category B Serious eye damage/eye irritation Category 1 Label Elements BE-5028-CA - Buckeye Juggernaut Revision Date: 11-Nov-2016 _____________________________________________________________________________________________ _____________________________________________________________________________________________ EN / HGHS Page 2 / 10 Signal word Danger Hazard statements Harmful if inhaled Causes severe skin burns and eye damage Precautionary Statements - Prevention Use only outdoors or in a well-ventilated area Do not breathe dust/fume/gas/mist/vapours/spray Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Precautionary Statements - Response Immediately call a POISON CENTRE or doctor IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTRE or doctor IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower] Wash contaminated clothing before reuse IF INHALED: Remove person to fresh air and keep comfortable for breathing Call a POISON CENTRE or doctor if you feel unwell Immediately call a POISON CENTRE or doctor IF SWALLOWED: rinse mouth. Do NOT induce vomiting Precautionary Statements - Storage Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Other Information Harmful to aquatic life with long lasting effects BE-5028-CA - Buckeye Juggernaut Revision Date: 11-Nov-2016 _____________________________________________________________________________________________ _____________________________________________________________________________________________ EN / HGHS Page 3 / 10 3. COMPOSITION/INFORMATION ON INGREDIENTS Mixture Chemical Name CAS No Weight-% Hazardous Material Information Review Act registry number (HMIRA registry #) Date HMIRA filed and date exemption granted (if applicable) Benzyl alcohol 100-51-6 20 - - Monoethanolamine 141-43-5 10 - - Ethylene glycol monophenyl ether 122-99-6 10 - - Di(ethylene glycol) ethyl ether 111-90-0 10 - - Octanoic Acid 124-07-2 5 - - Sodium metasilicate 6834-92-0 2 - - Sodium hydroxide 1310-73-2 1 - - 4. FIRST AID MEASURES First Aid Measures Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison centre or doctor/physician. Skin contact IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. Inhalation IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a poison centre or doctor/physician. Ingestion IF SWALLOWED: rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Seek immediate medical attention. Most important symptoms and effects Symptoms Causes severe skin burns and eye damage. Ingestion may cause nausea and headache. Can cause defatting of skin tissue. Indication of any immediate medical attention and special treatment needed Note to doctors Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media CAUTION: Use of water spray when fighting fire may be inefficient. Specific hazards arising from the chemical Combustion products may be toxic. Hazardous Combustion Products Carbon oxides. Oxides of sulphur. Nitrogen oxides (NOx). Silicon oxides. BE-5028-CA - Buckeye Juggernaut Revision Date: 11-Nov-2016 _____________________________________________________________________________________________ _____________________________________________________________________________________________ EN / HGHS Page 4 / 10 Explosion Data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Special protective equipment for fire-fighters Firefighters should wear self-contained breathing apparatus and full firefighting turnout gear. Use personal protection equipment. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Use personal protective equipment as required. Environmental precautions Environmental precautions Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information. See Section 13: DISPOSAL CONSIDERATIONS. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Pick up with mop, wet/dry vac, or absorbent material. Rinse area with clear water and allow floor to dry before allowing traffic. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Wear protective gloves/protective clothing and eye/face protection. Wash face, hands and any exposed skin thoroughly after handling. Use only outdoors or in a well-ventilated area. Do not breathe dust/fume/gas/mist/vapours/spray. Conditions for safe storage, including any incompatibilities Storage Conditions Keep container tightly closed and store in a cool, dry and well-ventilated place. Keep container closed when not in use. Store at room temperature. Store away from incompatible materials. Store on low shelves. Store locked up. Packaging materials Rinse container before discarding. Incompatible materials Chlorine bleach Acids 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Limits . Chemical Name Canada - Alberta - Occupational Exposure Limits - Ceilings Canada - British Columbia - Occupational Exposure Limits - Ceilings Canada - Ontario - Occupational Exposure Limits - Ceilings Quebec Monoethanolamine 141-43-5 TWA: 3 ppm TWA: 7.5 mg/m3 STEL: 6 ppm TWA: 3 ppm STEL: 6 ppm TWA: 3 ppm STEL: 6 ppm TWA: 3 ppm TWA: 7.5 mg/m3 STEL: 6 ppm BE-5028-CA - Buckeye Juggernaut Revision Date: 11-Nov-2016 _____________________________________________________________________________________________ _____________________________________________________________________________________________ EN / HGHS Page 5 / 10 STEL: 15 mg/m3 STEL: 15 mg/m3 Ethylene glycol monophenyl ether 122-99-6 TWA: 25 ppm TWA: 141 mg/m3 Skin Di(ethylene glycol) ethyl ether 111-90-0 TWA: 30 ppm TWA: 165 mg/m3 Sodium hydroxide 1310-73-2 Ceiling: 2 mg/m3 Ceiling: 2 mg/m3 CEV: 2 mg/m3 Ceiling: 2 mg/m3 Appropriate engineering controls Engineering controls Showers Eyewash stations Ventilation systems. Individual protection measures, such as personal protective equipment Eye/face protection Wear goggles or chemical safety glasses. Skin and body protection Rubber gloves. Normal work clothing (long sleeved shirts and long pants) is recommended. Wear water or chemical resistant footwear when scrubbing floors. Respiratory protection Ensure adequate ventilation, especially in confined areas. General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid Appearance Clear purple solution Colour Clear purple Odour Mild scent No fragrance added Odour Threshold No information available Property Values Remarks • Method pH 12.8-13.2 (conc.) 12.1-12.5 (1:4 dilution) Melting Point/Freezing Point Not determined Boiling Point/Boiling Range 100 °C / 212 °F Flash Point None Tag Closed Cup Evaporation Rate 1.0 (Water = 1) Flammability (Solid, Gas) Liquid-Not Applicable Flammability Limits in Air Upper Flammability Limits Not Applicable Lower Flammability Limit Not Applicable Vapour Pressure Not determined Vapour Density Not determined Relative Density 1.05 Water Solubility Infinite Solubility in other solvents Not determined Partition Coefficient Not determined Auto-ignition Temperature Not determined Decomposition Temperature Not determined Kinematic Viscosity Not determined Dynamic Viscosity Not determined Explosive properties No information available. Oxidising properties No information available. BE-5028-CA - Buckeye Juggernaut Revision Date: 11-Nov-2016 _____________________________________________________________________________________________ _____________________________________________________________________________________________ EN / HGHS Page 6 / 10 Other Information Softening Point No information available Molecular weight No information available VOC Content (%) No information available Density No information available Bulk Density No information available 10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical Stability Stable under normal conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerisation Hazardous polymerisation does not occur. Conditions to Avoid Incompatible Materials. Keep out of reach of children. Incompatible Materials Chlorine bleach. Acids. Hazardous Decomposition Products Carbon oxides. Nitrogen oxides (NOx). Sulphur oxides. Silicon oxides. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Eye contact Causes severe eye damage. Skin contact Causes severe skin burns. May be harmful in contact with skin. Inhalation Harmful if inhaled. Ingestion May be harmful if swallowed. Information on physical, chemical and toxicological effects Symptoms Please see section 4 of this SDS for symptoms. Numerical measures of toxicity Not determined Acute Toxicity Unknown acute toxicity No information available Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Benzyl alcohol 100-51-6 = 1230 mg/kg ( Rat ) = 2 g/kg ( Rabbit ) = 8.8 mg/L ( Rat ) 4 h Monoethanolamine 141-43-5 = 1720 mg/kg ( Rat ) = 1 mL/kg ( Rabbit ) = 1000 mg/kg ( Rabbit ) - Ethylene glycol monophenyl = 1260 mg/kg ( Rat ) = 5 mL/kg ( Rabbit ) - BE-5028-CA - Buckeye Juggernaut Revision Date: 11-Nov-2016 _____________________________________________________________________________________________ _____________________________________________________________________________________________ EN / HGHS Page 7 / 10 ether 122-99-6 Di(ethylene glycol) ethyl ether 111-90-0 = 10502 mg/kg ( Rat ) = 6 mL/kg ( Rat ) = 9143 mg/kg ( Rabbit ) = 4200 µL/kg ( Rabbit ) > 5240 mg/m3 ( Rat ) 4 h Octanoic Acid 124-07-2 = 10080 mg/kg ( Rat ) > 5 g/kg ( Rabbit ) - Sodium metasilicate 6834-92-0 = 1153 mg/kg ( Rat ) - - Sodium hydroxide 1310-73-2 - = 1350 mg/kg ( Rabbit ) - Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity Based on available data, the classification criteria are not met. 12. ECOLOGICAL INFORMATION Ecotoxicity Harmful to aquatic life with long lasting effects. Chemical Name Algae/aquatic plants Fish Toxicity to microorganisms Crustacea Benzyl alcohol 100-51-6 35: 3 h Anabaena variabilis mg/L EC50 460: 96 h Pimephales promelas mg/L LC50 static 10: 96 h Lepomis macrochirus mg/L LC50 static EC50 = 50 mg/L 5 min EC50 = 63.7 mg/L 15 min EC50 = 63.7 mg/L 5 min EC50 = 71.4 mg/L 30 min 23: 48 h water flea mg/L EC50 Monoethanolamine 141-43-5 15: 72 h Desmodesmus subspicatus mg/L EC50 227: 96 h Pimephales promelas mg/L LC50 flow-through 200: 96 h Oncorhynchus mykiss mg/L LC50 flow-through 300 - 1000: 96 h Lepomis macrochirus mg/L LC50 static 114 - 196: 96 h Oncorhynchus mykiss mg/L LC50 static 3684: 96 h Brachydanio rerio mg/L LC50 static - 65: 48 h Daphnia magna mg/L EC50 Ethylene glycol monophenyl ether 122-99-6 500: 72 h Desmodesmus subspicatus mg/L EC50 366: 96 h Pimephales promelas mg/L LC50 static 337 - 352: 96 h Pimephales promelas mg/L LC50 flow-through 220 - 460: 96 h Leuciscus idus mg/L LC50 static EC50 = 32.4 mg/L 5 min EC50 = 880 mg/L 17 h 500: 48 h Daphnia magna mg/L EC50 Di(ethylene glycol) ethyl ether 111-90-0 - 11400 - 15700: 96 h Oncorhynchus mykiss mg/L LC50 flow-through 11600 - 16700: 96 h Pimephales promelas mg/L LC50 flow-through 13400: 96 h Salmo gairdneri mg/L LC50 flow- through 10000: 96 h Lepomis macrochirus - 3940 - 4670: 48 h Daphnia magna mg/L EC50 BE-5028-CA - Buckeye Juggernaut Revision Date: 11-Nov-2016 _____________________________________________________________________________________________ _____________________________________________________________________________________________ EN / HGHS Page 8 / 10 mg/L LC50 static 19100 - 23900: 96 h Lepomis macrochirus mg/L LC50 flow-through Octanoic Acid 124-07-2 - 110: 96 h Brachydanio rerio mg/L LC50 semi- static 310: 96 h Oryzias latipes mg/L LC50 semi- static - 170: 24 h Daphnia magna mg/L EC50 Sodium metasilicate 6834-92-0 - 210: 96 h Brachydanio rerio mg/L LC50 210: 96 h Brachydanio rerio mg/L LC50 semi-static - 216: 96 h Daphnia magna mg/L EC50 Sodium hydroxide 1310-73-2 - 45.4: 96 h Oncorhynchus mykiss mg/L LC50 static - - Persistence/Degradability No information available. Bioaccumulation No information available. Mobility . Chemical Name Partition Coefficient Benzyl alcohol 100-51-6 1.1 Monoethanolamine 141-43-5 -1.91 Ethylene glycol monophenyl ether 122-99-6 1.13 Di(ethylene glycol) ethyl ether 111-90-0 -0.8 Octanoic Acid 124-07-2 2.92 Other Adverse Effects No information available. 13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Waste from residues/unused products Dispose of in accordance with local regulations. Dispose of waste in accordance with environmental legislation. Contaminated packaging Do not reuse empty containers. 14. TRANSPORT INFORMATION DOT UN/ID No UN1760 Proper Shipping Name Corrosive liquid, n.o.s. (Ethanolamine, Sodium hydroxide) Hazard Class 8 Packing Group II Reportable Quantity (RQ) 1000 lb TDG UN/ID No UN1760 BE-5028-CA - Buckeye Juggernaut Revision Date: 11-Nov-2016 _____________________________________________________________________________________________ _____________________________________________________________________________________________ EN / HGHS Page 9 / 10 Proper Shipping Name Corrosive liquid, n.o.s. (Ethanolamine, Sodium hydroxide) Hazard Class 8 Packing Group II IATA UN/ID No UN1760 Proper Shipping Name Corrosive liquid, n.o.s. (Ethanolamine, Sodium hydroxide) Hazard Class 8 Packing Group II IMDG UN/ID No UN1760 Proper Shipping Name Corrosive liquid, n.o.s. (Ethanolamine, Sodium hydroxide) Hazard Class 8 Packing Group II 15. REGULATORY INFORMATION REGULATORY INFORMATION International Regulations Ozone-depleting substances (ODS) Not applicable Persistent Organic Pollutants Not applicable Export Notification requirements Not applicable International Inventories Chemical Name TSCA DSL/NDSL EINECS/ELI NCS ENCS IECSC KECL PICCS AICS Benzyl alcohol X X X Present X Present X X Monoethanolamine X X X Present X Present X X Ethylene glycol monophenyl ether X X X Present X Present X X Di(ethylene glycol) ethyl ether X X X Present X Present X X Octanoic Acid X X X Present X Present X X Sodium metasilicate X X X Present X Present X X Sodium hydroxide X X X Present X Present X X Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances BE-5028-CA - Buckeye Juggernaut Revision Date: 11-Nov-2016 _____________________________________________________________________________________________ _____________________________________________________________________________________________ EN / HGHS Page 10 / 10 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION NFPA Health Hazards 3 Flammability 0 Instability 0 Special Hazards - HMIS Health Hazards 3 Flammability 0 Physical hazards 0 Personal Protection X Legend Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION TWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit) Ceiling Maximum limit value * Skin designation Issue Date: 27-Dec-2011 Revision Date: 11-Nov-2016 Revision Note: Canadian format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet