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Safety Data Sheet
Issue Date: 27-Dec-2011
Revision Date: 26-Nov-2014
Version 1
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1. IDENTIFICATION
Product Identifier
Product Name Buckeye Verde
Other means of identification
SDS # BE-5103
Product Code 5103
Recommended use of the chemical and restrictions on use
Recommended Use Floor Finish, Water Based.
Details of the supplier of the safety data sheet
Supplier Address
Buckeye International, Inc.
2700 Wagner Place
Maryland Heights, MO 63043 USA
Emergency Telephone Number
Company Phone Number 1-651-632-8956 (International)
1-800-303-0441 (North America)
Emergency Telephone (24 hr) INFOTRAC 1-352-323-3500 (International)
1-800-535-5053 (North America)
2. HAZARDS IDENTIFICATION
Appearance White opaque solution
Physical State Liquid
Odor No scent No fragrance added
Classification
This chemical does not meet the hazardous criteria set forth by the 2012 OSHA Hazard Communication Standard (29 CFR
1910.1200). However, this Safety Data Sheet (SDS) contains valuable information critical to the safe handling and proper use of
this product. This SDS should be retained and available for employees and other users of this product.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No Weight-%
tributoxyethyl phosphate 78-51-3 <3
**If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage
of composition has been withheld as a trade secret.**
BE-5103 - Buckeye Verde
Revision Date: 26-Nov-2014 _____________________________________________________________________________________________
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4. FIRST-AID MEASURES
First Aid Measures
Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get
medical attention if irritation persists.
Skin Contact Wash with soap and water. If skin irritation persists, call a physician.
Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a
physician if you feel unwell.
Ingestion Drink 2-3 large glasses of water. Do not induce vomiting. Call a physician. Never give
anything by mouth to an unconscious person.
Most important symptoms and effects
Symptoms May cause eye and skin irritation.
Indication of any immediate medical attention and special treatment needed
Notes to Physician Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable Extinguishing Media Not determined.
Specific Hazards Arising from the Chemical
Combustion products may be toxic.
Hazardous Combustion Products Carbon oxides. Phosphorus oxides. Nitrogen oxides (NOx).
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal Precautions Use personal protection recommended in Section 8.
Environmental Precautions Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See
Section 12, Ecological Information. See Section 13: DISPOSAL CONSIDERATIONS.
Methods and material for containment and cleaning up
Methods for Containment Prevent further leakage or spillage if safe to do so.
Methods for Clean-Up Pick up with mop, wet/dry vac, or absorbent material. Rinse area with clear water and allow
floor to dry before allowing traffic.
BE-5103 - Buckeye Verde
Revision Date: 26-Nov-2014 _____________________________________________________________________________________________
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7. HANDLING AND STORAGE
Precautions for safe handling
Advice on Safe Handling Handle in accordance with good industrial hygiene and safety practice. Use personal
protection recommended in Section 8. Avoid contact with skin, eyes or clothing. Use only in
well-ventilated areas.
Conditions for safe storage, including any incompatibilities
Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Keep container
closed when not in use. Keep from freezing. Store at room temperature. Do not store above
110°F.
Incompatible Materials Acids. Strong alkalis. Heavy metal salts.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Guidelines
No exposure limits noted for ingredient(s). The following information is given as general guidance.
Appropriate engineering controls
Engineering Controls Ensure adequate ventilation, especially in confined areas. Eyewash stations. Showers.
Individual protection measures, such as personal protective equipment
Eye/Face Protection Risk of contact: Wear approved safety goggles.
Skin and Body Protection Wear suitable protective clothing.
Respiratory Protection Ensure adequate ventilation, especially in confined areas.
General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Wash hands
thoroughly after handling.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical State Liquid
Appearance White opaque solution
Odor No scent No fragrance
added
Color White
Odor Threshold Not determined
Property Values Remarks • Method
pH 7.6 ± 0.2 (conc and use dilution)
Melting Point/Freezing Point Not determined
Boiling Point/Boiling Range 100 °C / 212 °F
Flash Point None
Tag Closed Cup
Evaporation Rate 1.0
(Water = 1)
Flammability (Solid, Gas) Liquid-Not applicable
Upper Flammability Limits Not applicable
Lower Flammability Limit Not applicable
Vapor Pressure Not determined
Vapor Density Not determined
Specific Gravity 1.02
Water Solubility Miscible in water
Solubility in other solvents Not determined
Partition Coefficient Not determined
Auto-ignition Temperature Not determined
Decomposition Temperature Not determined
Kinematic Viscosity Not determined
Dynamic Viscosity Not determined
Explosive Properties Not determined
Oxidizing Properties Not determined
BE-5103 - Buckeye Verde
Revision Date: 26-Nov-2014 _____________________________________________________________________________________________
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10. STABILITY AND REACTIVITY
Reactivity
Not reactive under normal conditions.
Chemical Stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None under normal processing.
Hazardous Polymerization Hazardous polymerization does not occur.
Conditions to Avoid
Keep separated from incompatible substances. Keep out of reach of children.
Incompatible Materials
Acids. Strong alkalis. Heavy metal salts.
Hazardous Decomposition Products
Carbon oxides. Nitrogen oxides (NOx). Phosphorous oxides.
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Product Information
Eye Contact Avoid contact with eyes.
Skin Contact Avoid contact with skin.
Inhalation Avoid breathing vapors or mists.
Ingestion Do not ingest.
Component Information
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
tributoxyethyl phosphate
78-51-3
= 3000 mg/kg ( Rat ) > 5000 mg/kg ( Rabbit ) > 6.4 mg/L ( Rat ) 4 h
Di(ethylene glycol) ethyl ether
111-90-0
= 1920 mg/kg ( Rat ) = 4200 µL/kg ( Rabbit ) = 6 mL/kg
( Rat )
> 5240 mg/m3 ( Rat ) 4 h
Information on physical, chemical and toxicological effects
Symptoms Please see section 4 of this SDS for symptoms.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Carcinogenicity This product does not contain any carcinogens or potential carcinogens as listed by OSHA,
IARC or NTP.
Numerical measures of toxicity
Not determined
BE-5103 - Buckeye Verde
Revision Date: 26-Nov-2014 _____________________________________________________________________________________________
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12. ECOLOGICAL INFORMATION
Ecotoxicity
The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent
spills can have a harmful or damaging effect on the environment.
Component Information
Chemical Name Algae/aquatic plants Fish Toxicity to
microorganisms
Crustacea
tributoxyethyl phosphate
78-51-3 10.4 - 12.0: 96 h Pimephales
promelas mg/L LC50
flow-through
Di(ethylene glycol) ethyl
ether
111-90-0
11400 - 15700: 96 h
Oncorhynchus mykiss mg/L
LC50 flow-through 11600 -
16700: 96 h Pimephales
promelas mg/L LC50
flow-through 10000: 96 h
Lepomis macrochirus mg/L
LC50 static 19100 - 23900:
96 h Lepomis macrochirus
mg/L LC50 flow-through
13400: 96 h Salmo gairdneri
mg/L LC50 flow-through
3940 - 4670: 48 h Daphnia
magna mg/L EC50
Persistence/Degradability
Not determined.
Bioaccumulation
Not determined.
Mobility
Chemical Name Partition Coefficient
tributoxyethyl phosphate
78-51-3
4.78
Other Adverse Effects
Not determined
13. DISPOSAL CONSIDERATIONS
Waste Treatment Methods
Disposal of Wastes Disposal should be in accordance with applicable regional, national and local laws and
regulations.
Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and
regulations.
14. TRANSPORT INFORMATION
Note Please see current shipping paper for most up to date shipping information, including
exemptions and special circumstances.
DOT Not regulated
IATA Not regulated
IMDG Not regulated
BE-5103 - Buckeye Verde
Revision Date: 26-Nov-2014 _____________________________________________________________________________________________
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15. REGULATORY INFORMATION
International Inventories
Chemical Name TSCA DSL NDSL EINECS ELINCS ENCS IECSC KECL PICCS AICS
tributoxyethyl phosphate Present X Present Present X Present X X
Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances
US Federal Regulations
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355).
SARA 313
Chemical Name CAS No Weight-% SARA 313 - Threshold
Values %
Di(ethylene glycol) ethyl ether - 111-90-0 111-90-0 2.7 1.0
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)
US State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals.
U.S. State Right-to-Know Regulations
Chemical Name New Jersey Massachusetts Pennsylvania
Di(ethylene glycol) ethyl ether
111-90-0
X X
BE-5103 - Buckeye Verde
Revision Date: 26-Nov-2014 _____________________________________________________________________________________________
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16. OTHER INFORMATION
NFPA
Health Hazards
0
Flammability
0
Instability
0
Special Hazards
Not determined
HMIS
Health Hazards
Not determined
Flammability
Not determined
Physical Hazards
Not determined
Personal Protection
Not determined
Issue Date: 27-Dec-2011
Revision Date: 26-Nov-2014
Revision Note: New format
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
End of Safety Data Sheet