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Safety Data Sheet
Issue Date: 27-Dec-2011
Revision Date: 12-Jul-2019
Version 3
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1. IDENTIFICATION
Product identifier
Product Name Buckeye Proclaim
Other means of identification
SDS # BE-5150
Product Code 5150
Recommended use of the chemical and restrictions on use
Recommended Use Floor Sealer, Water Based.
Details of the supplier of the safety data sheet
Supplier Address
Buckeye International, Inc.
2700 Wagner Place
Maryland Heights, MO 63043 USA
Emergency telephone number
Company Phone Number 1-314-291-1900
Emergency Telephone Transportation - INFOTRAC 1-352-323-3500 (International)
1-800-535-5053 (North America)
Medical - (International) 1-651-632-8956 (North America) 1-800-303-0441
2. HAZARDS IDENTIFICATION
Appearance White opaque solution
Physical state Liquid
Odor Sweet polymer scent No fragrance
added
Classification
This chemical does not meet the hazardous criteria set forth by the 2012 OSHA Hazard Communication Standard (29 CFR
1910.1200). However, this Safety Data Sheet (SDS) contains valuable information critical to the safe handling and proper use of
this product. This SDS should be retained and available for employees and other users of this product.
Other hazards
Harmful to aquatic life with long lasting effects
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical name CAS No Weight-%
tributoxyethyl phosphate 78-51-3 <3
**If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage
of composition has been withheld as a trade secret.**
BE-5150 - Buckeye Proclaim
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4. FIRST AID MEASURES
Description of first aid measures
General Advice If exposed or concerned: Get medical advice/attention.
Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Call
a physician if irritation persists.
Skin Contact Wash with soap and water. If skin irritation persists, call a physician. Take off contaminated
clothing. Wash contaminated clothing before reuse.
Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a
physician if you feel unwell.
Ingestion Drink 2-3 large glasses of water. Do NOT induce vomiting. Call a physician. Never give
anything by mouth to an unconscious person.
Most important symptoms and effects, both acute and delayed
Symptoms Eye contact may cause redness or burning sensation. May cause redness of skin or a
warming sensation.
Indication of any immediate medical attention and special treatment needed
Notes to Physician Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable Extinguishing Media Not determined.
Specific Hazards Arising from the Chemical
Combustion products may be toxic.
Hazardous combustion products Carbon oxides.
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal Precautions Use personal protective equipment as required.
Environmental precautions
Environmental precautions Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See
Section 12, Ecological Information. See Section 13: DISPOSAL CONSIDERATIONS. See
Section 12 for additional Ecological Information.
Methods and material for containment and cleaning up
Methods for Containment Prevent further leakage or spillage if safe to do so.
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Methods for Clean-Up Pick up with mop, wet/dry vac, or absorbent material. Wash spill area with a mild detergent.
Rinse affected area with water and allow area to dry before allowing traffic.
7. HANDLING AND STORAGE
Precautions for safe handling
Advice on Safe Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with
skin, eyes or clothing. Use personal protection recommended in Section 8.
Conditions for safe storage, including any incompatibilities
Storage Conditions Keep container tightly closed and store in a cool, dry and well-ventilated place. Keep
container closed when not in use. Keep from freezing. Store at room temperature. Do not
store above 110°F. Store locked up.
Incompatible Materials Acids. Strong alkalis. Heavy metal salts.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Guidelines This product, as supplied, does not contain any hazardous materials with occupational
exposure limits established by the region specific regulatory bodies
Appropriate engineering controls
Engineering Controls Ensure adequate ventilation, especially in confined areas. Eyewash stations. Showers.
Individual protection measures, such as personal protective equipment
Eye/Face Protection Risk of contact: Wear approved safety goggles.
Skin and Body Protection Rubber gloves. Suitable protective clothing.
Respiratory Protection Refer to 29 CFR 1910.134 for respiratory protection requirements.
General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical state Liquid
Appearance White opaque solution Odor Sweet polymer scent No
fragrance added
Color White opaque
Odor Threshold Not determined
Property Values
Remarks • Method
pH 7.4-7.8 (conc. and use dilution) Melting point / freezing point Not determined
Boiling point / boiling range 100 °C / 212 °F
Flash point None Tag Closed Cup Evaporation Rate 1.0
(n-BuAc =1)
Flammability (Solid, Gas) Liquid-Not Applicable Flammability Limit in Air
Upper flammability or explosive
limits
Not Applicable
Lower flammability or explosive
limits
Not Applicable
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Vapor Pressure Not determined Vapor Density Not determined
Relative Density 1.03 Water Solubility Miscible in water Solubility in other solvents Not determined
Partition Coefficient Not determined
Autoignition temperature Not determined Decomposition temperature Not determined
Kinematic viscosity Not determined Dynamic Viscosity Not determined Explosive Properties Not determined
Oxidizing Properties Not determined
10. STABILITY AND REACTIVITY
Reactivity
Not reactive under normal conditions.
Chemical stability
Stable under recommended storage conditions.
Possibility of hazardous reactions
None under normal processing.
Hazardous Polymerization Hazardous polymerization does not occur.
Conditions to Avoid
Keep separated from incompatible substances. Keep out of reach of children.
Incompatible materials
Acids. Strong alkalis. Heavy metal salts.
Hazardous decomposition products
Carbon oxides.
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Product Information The information below is for repeated and prolonged contact in an occupational setting. It
does not apply to normal product use
Eye Contact Avoid contact with eyes.
Skin Contact Avoid contact with skin.
Inhalation Avoid breathing vapors or mists.
Ingestion Do not ingest.
Component Information
Chemical name Oral LD50 Dermal LD50 Inhalation LC50
Di(ethylene glycol) ethyl ether
111-90-0
= 10502 mg/kg ( Rat ) = 9143 mg/kg ( Rabbit ) = 6 mL/kg
( Rat ) = 4200 µL/kg ( Rabbit )
> 5240 mg/m3 ( Rat ) 4 h
tributoxyethyl phosphate
78-51-3
= 3 g/kg ( Rat ) > 16 mL/kg ( Rabbit ) > 6.4 mg/L ( Rat ) 4 h
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Symptoms related to the physical, chemical and toxicological characteristics
Symptoms Please see section 4 of this SDS for symptoms.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Carcinogenicity Based on the information provided, this product does not contain any carcinogens or
potential carcinogens as listed by OSHA, IARC or NTP.
Numerical measures of toxicity
The following values are calculated based on chapter 3.1 of the GHS document .
Oral LD50 34,225.70 mg/kg
ATEmix (inhalation-dust/mist) 45.82 mg/L
12. ECOLOGICAL INFORMATION
Ecotoxicity
Harmful to aquatic life with long lasting effects.
Component Information
Chemical name Algae/aquatic plants Fish Crustacea
Di(ethylene glycol) ethyl ether
111-90-0 19100 - 23900: 96 h Lepomis
macrochirus mg/L LC50 flow-
through 10000: 96 h Lepomis macrochirus mg/L LC50 static
11400 - 15700: 96 h Oncorhynchus
mykiss mg/L LC50 flow-through
11600 - 16700: 96 h Pimephales
promelas mg/L LC50 flow-through 13400: 96 h Salmo gairdneri mg/L
LC50 flow-through
3940 - 4670: 48 h Daphnia magna
mg/L EC50
tributoxyethyl phosphate
78-51-3 10.4 - 12.0: 96 h Pimephales
promelas mg/L LC50 flow-through
Persistence/Degradability
Not determined.
Bioaccumulation
There is no data for this product.
Mobility
Chemical name Partition coefficient
tributoxyethyl phosphate
78-51-3
3.65 - 4.78
Other Adverse Effects
Not determined
13. DISPOSAL CONSIDERATIONS
Waste Treatment Methods
Disposal of Wastes Disposal should be in accordance with applicable regional, national and local laws and
regulations.
Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and
regulations.
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14. TRANSPORT INFORMATION
Note Please see current shipping paper for most up to date shipping information, including
exemptions and special circumstances.
DOT Not regulated
IATA Not regulated
IMDG Not regulated
15. REGULATORY INFORMATION
International Inventories
Chemical name TSCA TSCA Inventory
Status
DSL/NDSL EINECS/ELI
NCS
ENCS IECSC KECL PICCS AICS
Styrene-Acrylic Polymer X ACTIVE X X X X X X
Ethylene Copolymer
Emulsion
X ACTIVE X
Acrylate Copolymer X ACTIVE X X X X
Di(ethylene glycol) ethyl ether X ACTIVE X X X X X X X
tributoxyethyl phosphate X ACTIVE X X X X X X X
Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances
US Federal Regulations
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355).
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical
or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
Chemical name CAS No Weight-% SARA 313 - Threshold
Values %
Di(ethylene glycol) ethyl ether - 111-90-0 111-90-0 4.6 1.0
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)
US State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals.
BE-5150 - Buckeye Proclaim
Revision Date: 12-Jul-2019 _____________________________________________________________________________________________
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U.S. State Right-to-Know Regulations
Chemical name New Jersey Massachusetts Pennsylvania
Di(ethylene glycol) ethyl ether
111-90-0
X X
16. OTHER INFORMATION
NFPA
Health Hazards
1
Flammability
0
Instability
0
Special Hazards
Not determined
HMIS Health Hazards
Not determined
Flammability
Not determined
Physical hazards
Not determined
Personal Protection
Not determined
Issue Date: 27-Dec-2011
Revision Date: 12-Jul-2019
Revision Note: Reformulation
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
End of Safety Data Sheet