HomeMy WebLinkAboutVarathane-Ultimate-Polyurethane-semi-glossDate Printed: 2/20/2019
Safety Data Sheet
* Trusted Quality Since 1921 *
www.rustoleum.com
1. Identification
Product Name:WDCARE SSPR 6PK VARA INT WTR BN S-
GLS Revision Date:2/20/2019
Product Identifier:200181 Supercedes Date:5/22/2017
Recommended Use:Wood Care/Aerosol
Supplier:Rust-Oleum Corporation
11 Hawthorn Parkway
Vernon Hills, IL 60061
USA
Manufacturer:Rust-Oleum Corporation
11 Hawthorn Parkway
Vernon Hills, IL 60061
USA
Preparer:Regulatory Department
24 Hour Hotline: 847-367-7700Emergency Telephone:
2. Hazard Identification
Classification
Symbol(s) of Product
Signal Word
Danger
Possible Hazards
41% of the mixture consists of ingredient(s) of unknown acute toxicity.
GHS HAZARD STATEMENTS
Compressed Gas H280 Contains gas under pressure; may explode if heated.
Eye Irritation, category 2 H319 Causes serious eye irritation.
Flammable Aerosol, category 1 H222 Extremely flammable aerosol.
Reproductive Toxicity, category 1B H360 May damage fertility or the unborn child.
GHS LABEL PRECAUTIONARY
STATEMENTS
P201 Obtain special instructions before use.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Do not pierce or burn, even after use.
P264 Wash hands thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
Page 1 / 6
Date Printed: 2/20/2019
P405 Store locked up.
P410+P403 Protect from sunlight. Store in a well-ventilated place.
P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50°C / 122°F.
P501 Dispose of contents/container in accordance with local, regional and national regulations.
3. Composition / Information On Ingredients
HAZARDOUS SUBSTANCES
Chemical Name CAS-No.Wt.%
Range
GHS Symbols GHS Statements
Dimethyl Ether 115-10-6 25-50 Not Available Not Available
Ethylene Glycol Monobutyl Ether 111-76-2 2.5-10 GHS07 H302-312-315-319-332
2-Propanol 67-63-0 2.5-10 GHS02-GHS07 H225-302-319-336
N-Methyl 2-Pyrrolidone 872-50-4 1.0-2.5 GHS07-GHS08 H315-319-332-335-360
Dipropylene Glycol Monomethyl Ether 34590-94-8 0.1-1.0 Not Available Not Available
2,4,7,9-Tetramethyl-5-Decyne-4,7-Diol 126-86-3 0.1-1.0 GHS05-GHS07 H302-312-317-318
Aqueous Ammonia 1336-21-6 0.1-1.0 GHS05-GHS07 H302-314-335
Triethylamine 121-44-8 0.1-1.0 GHS02-GHS05-
GHS06 H225-302-311-314-331-335
4. First-Aid Measures
FIRST AID -EYE CONTACT:Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical
attention. Do NOT allow rubbing of eyes or keeping eyes closed.
FIRST AID -SKIN CONTACT:Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation
develops or persists.
FIRST AID -INHALATION:Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the
area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately.
FIRST AID -INGESTION:Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the
lungs and cause severe lung damage. Get immediate medical attention. If swallowed, get medical attention.
5. Fire-Fighting Measures
EXTINGUISHING MEDIA:Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Dry Sand, Water Fog
UNUSUAL FIRE AND EXPLOSION HAZARDS:FLASH POINT IS LESS THAN 20°F. EXTREMELY FLAMMABLE LIQUID AND
VAPOR!Water spray may be ineffective. Closed containers may explode when exposed to extreme heat due to buildup of steam.
Closed containers may explode when exposed to extreme heat. Vapors may form explosive mixtures with air. Vapors can travel to
a source of ignition and flash back. Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame.
Perforation of the pressurized container may cause bursting of the can. No unusual fire or explosion hazards noted.
SPECIAL FIREFIGHTING PROCEDURES:Water may be used to cool closed containers to prevent pressure buildup and possible
autoignition or explosion. Full protective equipment including self-contained breathing apparatus should be used. Evacuate area
and fight fire from a safe distance. Use water spray to keep fire-exposed containers cool. Containers may explode when heated.
Special Fire and Explosion Hazard (Combustible Dust):No Information
6. Accidental Release Measures
Page 2 / 6
Date Printed: 2/20/2019
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:Contain spilled liquid with sand or earth. DO NOT use
combustible materials such as sawdust. Isolate the hazard area and deny entry to unnecessary and unprotected personnel.
Remove all sources of ignition, ventilate area and remove with inert absorbent and non-sparking tools. Dispose of according to
local, state (provincial) and federal regulations. Do not incinerate closed containers. Ventilate area, isolate spilled material, and
remove with inert absorbent. Dispose of contaminated absorbent, container, and unused contents in accordance with local, state,
and federal regulations.
7. Handling and Storage
HANDLING:Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and launder before reuse.
Use only with adequate ventilation. Follow all SDS and label precautions even after container is emptied because it may retain
product residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes, skin and clothing.
STORAGE:Store in a dry, well ventilated place. Keep container tightly closed when not in use. Keep containers tightly closed.
Isolate from heat, electrical equipment, sparks and open flame. Contents under pressure. Do not store above 120 ° F. Store large
quantities in buildings designed and protected for storage of flammable aerosols. Keep away from heat, sparks, flame and sources
of ignition. Avoid excess heat. Product should be stored in tightly sealed containers and protected from heat, moisture, and foreign
materials.
Advice on Safe Handling of Combustible Dust:No Information
8. Exposure Controls / Personal Protection
Chemical Name CAS-No.Weight %
Less Than
ACGIH TLV-
TWA
ACGIH TLV-
STEL OSHA PEL-TWA OSHA PEL-
CEILING
Dimethyl Ether 115-10-6 45.0 N.E.N.E.N.E.N.E.
Ethylene Glycol Monobutyl Ether 111-76-2 10.0 20 ppm N.E.50 ppm N.E.
2-Propanol 67-63-0 5.0 200 ppm 400 ppm 400 ppm N.E.
N-Methyl 2-Pyrrolidone 872-50-4 5.0 N.E.N.E.N.E.N.E.
Dipropylene Glycol Monomethyl
Ether 34590-94-8 1.0 100 ppm 150 ppm 100 ppm N.E.
2,4,7,9-Tetramethyl-5-
Decyne-4,7-Diol 126-86-3 1.0 N.E.N.E.N.E.N.E.
Aqueous Ammonia 1336-21-6 1.0 N.E.N.E.N.E.N.E.
Triethylamine 121-44-8 1.0 0.5 ppm 1 ppm 25 ppm N.E.
PERSONAL PROTECTION
ENGINEERING CONTROLS:Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne
levels below recommended exposure limits. Use explosion-proof ventilation equipment. Provide general dilution of local exhaust
ventilation in volume and pattern to keep TLV of hazardous ingredients below acceptable limits. Prevent build-up of vapors by
opening all doors and windows to achieve cross-ventilation.
RESPIRATORY PROTECTION:A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must
be followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying respirator with
organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to
exceed exposure limits.
SKIN PROTECTION:Use gloves to prevent prolonged skin contact. Nitrile or Neoprene gloves may afford adequate skin
protection.
EYE PROTECTION:Use safety eyewear designed to protect against splash of liquids.
OTHER PROTECTIVE EQUIPMENT:Refer to safety supervisor or industrial hygienist for further guidance regarding types of
personal protective equipment and their applications.
HYGIENIC PRACTICES:Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing
immediately and launder before reuse.
Engineering Measures for Combustible Dust:No Information
Page 3 / 6
Date Printed: 2/20/2019
9. Physical and Chemical Properties
Appearance:Aerosolized Mist Physical State:Liquid
Odor:Solvent Like Odor Threshold:N.E.
Relative Density:0.830 pH:N.A.
Freeze Point, °C:N.D.Viscosity:N.D.
Solubility in Water:Miscible Partition Coefficient, n-
octanol/water:N.D.Decompostion Temp., °C:N.D.
Boiling Range, °C:-24 - 202 Explosive Limits, vol%:1.9 - 12.0
Flammability:Supports Combustion Flash Point, °C:-41
Evaporation Rate:Faster than Ether Auto-ignition Temp., °C:N.D.
Vapor Density:Heavier than Air Vapor Pressure:N.D.
(See "Other information" Section for abbreviation legend)
10. Stability and Reactivity
CONDITIONS TO AVOID:Avoid temperatures above 120°F (49°C). Avoid all possible sources of ignition.
INCOMPATIBILITY:Incompatible with strong oxidizing agents, strong acids and strong alkalies.
HAZARDOUS DECOMPOSITION:By open flame, carbon monoxide and carbon dioxide. When heated to decomposition, it emits
acrid smoke and irritating fumes. Contains solvents which may form carbon monoxide, carbon dioxide, and formaldehyde.
HAZARDOUS POLYMERIZATION:Will not occur under normal conditions.
STABILITY:This product is stable under normal storage conditions.
11. Toxicological Information
EFFECTS OF OVEREXPOSURE -EYE CONTACT:Causes Serious Eye Irritation
EFFECTS OF OVEREXPOSURE -SKIN CONTACT:May cause skin irritation. Allergic reactions are possible.
EFFECTS OF OVEREXPOSURE -INHALATION:Harmful if inhaled. High gas, vapor, mist or dust concentrations may be harmful
if inhaled. Avoid breathing fumes, spray, vapors, or mist. High vapor concentrations are irritating to the eyes, nose, throat and
lungs. Prolonged or excessive inhalation may cause respiratory tract irritation.
EFFECTS OF OVEREXPOSURE -INGESTION:Harmful if swallowed.
EFFECTS OF OVEREXPOSURE -CHRONIC HAZARDS:May cause central nervous system disorder (e.g., narcosis involving a
loss of coordination, weakness, fatigue, mental confusion, and blurred vision) and/or damage. High concentrations may lead to
central nervous system effects (drowsiness, dizziness, nausea, headaches, paralysis, and blurred vision) and/or damage. Reports
have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage.
PRIMARY ROUTE(S) OF ENTRY:Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact
ACUTE TOXICITY VALUES
The acute effects of this product have not been tested. Data on individual components are tabulated below:
CAS-No.Chemical Name Oral LD50 Dermal LD50 Vapor LC50
111-76-2 Ethylene Glycol Monobutyl Ether 470 mg/kg Rat 1,060 mg/kg Rabbit 11 mg/L
67-63-0 2-Propanol 1870 mg/kg Rat 4059 mg/kg Rabbit 72.6 mg/L Rat
872-50-4 N-Methyl 2-Pyrrolidone 3914 mg/kg Rat 8000 mg/kg Rabbit 20 mg/L Rat
34590-94-8 Dipropylene Glycol Monomethyl Ether 5350 mg/kg Rat 9500 mg/kg Rabbit >20 mg/L
126-86-3 2,4,7,9-Tetramethyl-5-Decyne-4,7-Diol >500 mg/kg Rat >1000 mg/kg Rabbit N.E.
1336-21-6 Aqueous Ammonia 350 mg/kg Rat N.E.N.E.
121-44-8 Triethylamine 460 mg/kg Rat 415 mg/kg Rabbit N.E.
N.E. - Not Established
12. Ecological Information
ECOLOGICAL INFORMATION:Product is a mixture of listed components.
13. Disposal Information
DISPOSAL INFORMATION:Do not incinerate closed containers. This product as supplied is a USEPA defined ignitable hazardous
waste. Dispose of unusable product as a hazardous waste (D001) in accordance with local, state, and federal regulation.
Page 4 / 6
Date Printed: 2/20/2019
14. Transport Information
Domestic (USDOT)International (IMDG)Air (IATA)TDG (Canada)
UN Number:N.A.1950 1950 N.A.
Proper Shipping Name:Paint and Related Spray
Products in Ltd Qty Aerosols Aerosols, flammable Aerosols
Hazard Class:N.A.2 2.1 N.A.
Packing Group:N.A.N.A.N.A.N.A.
Limited Quantity:Yes Yes Yes Yes
15. Regulatory Information
U.S. Federal Regulations:
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:
Gas under pressure, Reproductive toxicity, Serious eye damage or eye irritation
Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name CAS-No.
Ethylene Glycol Monobutyl Ether 111-76-2
N-Methyl 2-Pyrrolidone 872-50-4
Aqueous Ammonia 1336-21-6
Triethylamine 121-44-8
Toxic Substances Control Act:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(b) if exported
from the United States:
No TSCA 12(b) components exist in this product.
U.S. State Regulations:
California Proposition 65:
WARNING:Reproductive Harm - www.P65Warnings.ca.gov.
Page 5 / 6
Date Printed: 2/20/2019
16. Other Information
HMIS RATINGS
Health:2*Flammability:4 Physical Hazard:0 Personal Protection:X
NFPA RATINGS
Health:2 Flammability:4 Instability 0
Maximum Incremental Reactivity 0.53
SDS REVISION DATE:2/20/2019
REASON FOR REVISION:Product Composition Changed
Substance and/or Product Properties Changed in Section(s):
01 - Identification
02 - Hazard Identification
14 - Transport Information
15 - Regulatory Information
16 - Other Information
Revision Statement(s) Changed
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to be
accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of
these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred
by the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracy or
reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with
caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and
examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all
applicable international, federal, state, and local laws and regulations.
Page 6 / 6