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Home My WebLink AboutTriple-S-Graffiti-Remover-pro-grade-wipes-57003 SAFETY DATA SHEET Issuing Date 24-Sep-2013 Revision Date 24-Sep-2013 Revision Number 0 _____________________________________________________________________________________________ Page 1 / 9 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING GHS product identifier Product Name Triple S Graffiti Remover Wipes Other means of identification Product Code(s) 57003 Synonyms None Recommended use of the chemical and restrictions on use Recommended Use Graffiti Remover Uses advised against None reasonably foreseeable Distributor's details Distributor Address Triple S 2 Executive Park Drive Billerica, MA 01862 TEL: 1-978-667-7900 Emergency telephone number Emergency Telephone Number 1-888-779-1339 2. HAZARDS IDENTIFICATION Classification This chemical is considered hazardous according to the OSHA Hazard Communication Standard 2012 (29 CFR 1910.1200) Serious Eye Damage/Eye Irritation Category 2 Specific Target Organ Systemic Toxicity (Single Exposure) Category 3 Flammable liquids Category 2 GHS Label elements, including precautionary statements Emergency Overview Signal Word Danger Hazard Statements • Causes serious eye irritation • May cause drowsiness or dizziness • Highly flammable liquid and vapor. 57003 - Triple S Graffiti Remover Wipes Revision Date 24-Sep-2013 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 2 / 9 Appearance Colorless Physical State Liquid. Odor Plumeria Precautionary Statements Prevention • Wash face, hands and any exposed skin thoroughly after handling • Avoid breathing dust/fume/gas/mist/vapors/spray • Use only outdoors or in a well-ventilated area • Keep away from heat/sparks/open flames/hot surfaces - No smoking • Keep container tightly closed • Ground/bond container and receiving equipment • Use explosion-proof electrical/ventilating/lighting/equipment • Use only non-sparking tools • Take precautionary measures against static discharge • Wear protective gloves/protective clothing/eye protection/face protection • Keep cool. General Advice • None Eyes • IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing • If eye irritation persists: Get medical advice/attention. Skin • IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Inhalation • IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing • Call a POISON CENTER or doctor/physician if you feel unwell. Fire • In case of fire: Use CO2, dry chemical, or foam for extinction. Storage • Store in a well-ventilated place. Keep container tightly closed • Store locked up. Disposal • Dispose of contents/container to an approved waste disposal plant. Hazard Not Otherwise Classified (HNOC) Not applicable Other information Harmful to aquatic life with long lasting effects 3. COMPOSITION/INFORMATION ON INGREDIENTS 57003 - Triple S Graffiti Remover Wipes Revision Date 24-Sep-2013 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 3 / 9 Chemical Name CAS-No Weight % Trade secret Dimethyl adipate 627-93-0 10-30 * Dimethyl glutarate 1119-40-0 10-30 * Tripropylene glycol monomethyl ether 25498-49-1 10-30 * Propylene glycol monomethyl ether 107-98-2 7-13 * Acetone 67-64-1 5-10 * 2-Butoxyethanol 111-76-2 5-10 * n-Amyl acetate 628-63-7 1-5 * Dimethyl succinate 106-65-0 1-5 * *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of necessary first-aid measures Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If irritation persists, call a physician. Skin Contact Wash off immediately with soap and plenty of water removing all contaminated clothes and shoes. In the case of skin irritation or allergic reactions see a physician. Inhalation Move to fresh air. If breathing is difficult, give oxygen. If symptoms persist, call a physician. Ingestion Not an expected route of exposure. If swallowed: Call a physician or Poison Control Center immediately. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. Most important symptoms/effects, acute and delayed Most Important Symptoms/Effects No information available. Indication of immediate medical attention and special treatment needed, if necessary Notes to Physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Carbon dioxide (CO 2 ). Dry chemical. Water fog. Foam. Fire may float as if an oil fire. Unsuitable Extinguishing Media None Specific Hazards Arising from the Chemical No information available. Hazardous Combustion Products Soot. Smoke, Fume, Incomplete combustion products, Oxides of carbon Explosion Data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective Equipment and Precautions for Firefighters Use water spray to cool surrounding containers. Wear self contained breathing apparatus for fire fighting if necessary. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Use personal protective equipment. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). 57003 - Triple S Graffiti Remover Wipes Revision Date 24-Sep-2013 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 4 / 9 Environmental Precautions Environmental Precautions Prevent entry into waterways, sewers, basements or confined areas. Avoid release to the environment. See Section 12 for additional Ecological Information Dispose of contents/container to an approved waste disposal plant. Methods and materials for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for Cleaning Up Small spillage: Wipe up with absorbent material (e.g. cloth, fleece) Large spillage: Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. 7. HANDLING AND STORAGE Precautions for safe handling Handling Avoid contact with skin, eyes and clothing. Do not smoke. Use only with adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Take precautionary measures against static discharges. To avoid ignition of vapors by static electricity discharge, all metal parts of the equipment must be grounded. Keep away from open flames, hot surfaces and sources of ignition. Use only in an area containing flame proof equipment. Conditions for safe storage, including any incompatibilities Storage Store in cool/well-ventilated place. Keep out of the reach of children. Keep container closed when not in use. Keep away from heat and sources of ignition. Do not contaminate food or feed stuffs. Incompatible Products Strong alkalis. Acids. Oxidizing agents. Alkali metal hydroxides. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Control parameters Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Propylene glycol monomethyl ether 107-98-2 STEL: 150 ppm TWA: 100 ppm (vacated) TWA: 100 ppm (vacated) TWA: 360 mg/m3 (vacated) STEL: 150 ppm (vacated) STEL: 540 mg/m3 TWA: 100 ppm TWA: 360 mg/m3 STEL: 150 ppm STEL: 540 mg/m3 Acetone 67-64-1 STEL: 750 ppm TWA: 500 ppm TWA: 1000 ppm TWA: 2400 mg/m3 (vacated) TWA: 750 ppm (vacated) TWA: 1800 mg/m3 (vacated) STEL: 2400 mg/m3 The acetone STEL does not apply to the cellulose acetate fiber industry. It is in effect for all other sectors (vacated) STEL: 1000 ppm IDLH: 2500 ppm 10% LEL TWA: 250 ppm TWA: 590 mg/m3 2-Butoxyethanol 111-76-2 TWA: 20 ppm TWA: 50 ppm TWA: 240 mg/m3 (vacated) TWA: 25 ppm (vacated) TWA: 120 mg/m3 (vacated) S* S* IDLH: 700 ppm TWA: 5 ppm TWA: 24 mg/m3 57003 - Triple S Graffiti Remover Wipes Revision Date 24-Sep-2013 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 5 / 9 n-Amyl acetate 628-63-7 STEL: 100 ppm TWA: 50 ppm TWA: 100 ppm TWA: 525 mg/m3 (vacated) TWA: 100 ppm (vacated) TWA: 525 mg/m3 IDLH: 1000 ppm TWA: 100 ppm TWA: 525 mg/m3 Appropriate engineering controls Engineering Measures Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/Face Protection Risk of contact, wear: Safety glasses with side-shields. Skin and Body Protection Risk of contact: Impervious gloves. Respiratory Protection None required under normal usage. If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State Liquid Appearance Colorless Odor Plumeria Odor Threshold No information available Property Values Remarks/ - Method pH 6.3 None known Melting Point/Range No data available None known Boiling Point/Boiling Range 100 °C / 212 °F None known Flash Point 16.67 °C / 62 °F None known Evaporation rate No data available None known Flammability (solid, gas) No data available None known Flammability Limits in Air upper flammability limit No data available lower flammability limit No data available Vapor Pressure No data available None known Vapor Density > 1 None known Relative Density No data available None known Specific Gravity 0.986 None known Water Solubility Miscible with water None known Solubility in other solvents No data available None known Partition coefficient: n-octanol/water No data available None known Autoignition Temperature No data available None known Decomposition Temperature No data available None known Viscosity No data available None known Flammable Properties Highly flammable liquid and vapor. Explosive Properties No data available Oxidizing Properties No data available Other information VOC Content (%) 30 10. STABILITY AND REACTIVITY Reactivity No data available. 57003 - Triple S Graffiti Remover Wipes Revision Date 24-Sep-2013 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 6 / 9 Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions None under normal processing. Conditions to avoid Incompatible products. Heat. Incompatible materials Strong alkalis. Acids. Oxidizing agents. Alkali metal hydroxides. Hazardous decomposition products Carbon monoxide, carbon dioxide and unburned hydrocarbons (smoke) Soot. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Inhalation May be harmful if inhaled. Eye Contact Causes serious eye irritation. May cause eye irritation including redness, tearing, itching, and swollen eyes. Skin Contact May cause irritation. Ingestion Not an expected route of exposure. Harmful if swallowed. Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation Acetone = 5800 mg/kg ( Rat ) 1700mg/kg (rabbit) 18892 mg/m3 2-Butoxyethanol = 470 mg/kg ( Rat ) = 400 mg/kg ( Rabbit ) = 2270 mg/kg ( Rat ) = 2.21 mg/L ( Rat ) 4 h = 450 ppm ( Rat ) 4 h n-Amyl acetate > 1600 mg/kg ( Rat ) - - Symptoms related to the physical, chemical and toxicological characteristics Symptoms No information available. Delayed and immediate effects and also chronic effects from short and long term exposure Sensitization No information available. Mutagenic Effects No information available. Carcinogenicity Contains no ingredients above reportable quantities listed as a carcinogen. Chemical Name ACGIH IARC NTP OSHA 2-Butoxyethanol A3 Group 3 ACGIH: (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC: (International Agency for Research on Cancer) Group 3: Not Classifiable as to its Carcinogenicity to Humans Reproductive Toxicity No information available. STOT - single exposure No information available. STOT - repeated exposure No information available. Aspiration Hazard No information available. Numerical measures of toxicity - Product The following values are calculated based on chapter 3.1 of the GHS document: 57003 - Triple S Graffiti Remover Wipes Revision Date 24-Sep-2013 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 7 / 9 LD50 Oral 2190 mg/kg; Acute toxicity estimate LD50 Dermal 5149 mg/kg; Acute toxicity estimate Inhalation gas 1581 dust/mist 5.9 mg/L; Acute toxicity estimate Vapor 27 mg/L; Acute toxicity estimate 12. ECOLOGICAL INFORMATION Ecotoxicity Harmful to aquatic life with long lasting effects. Chemical Name Toxicity to Algae Toxicity to Fish Toxicity to Microorganisms Daphnia Magna (Water Flea) Dimethyl glutarate 1119-40-0 LC50 96 h: 19.6-26.2 mg/L static (Pimephales promelas) EC50 48 h: 122.1 - 163.5 mg/L (Daphnia magna) Tripropylene glycol monomethyl ether 25498-49-1 LC50 96 h: = 11619 mg/L static (Pimephales promelas) EC50 48 h: > 10 mg/L (Daphnia magna) Propylene glycol monomethyl ether 107-98-2 LC50 96 h: 4600-10000 mg/L static (Leuciscus idus) LC50 96 h: = 20.8 g/L static (Pimephales promelas) EC50 48 h: = 23300 mg/L (Daphnia magna) Acetone 67-64-1 LC50 96 h: 4.74 - 6.33 mL/L (Oncorhynchus mykiss) LC50 96 h: 6210 - 8120 mg/L static (Pimephales promelas) LC50 96 h: = 8300 mg/L (Lepomis macrochirus) EC50 = 14500 mg/L 15 min EC50 48 h: 10294 - 17704 mg/L Static (Daphnia magna) EC50 48 h: 12600 - 12700 mg/L (Daphnia magna) 2-Butoxyethanol 111-76-2 LC50 96 h: = 1490 mg/L static (Lepomis macrochirus) LC50 96 h: = 2950 mg/L (Lepomis macrochirus) EC50 24 h: 1698 - 1940 mg/L (Daphnia magna) EC50 48 h: > 1000 mg/L (Daphnia magna) n-Amyl acetate 628-63-7 LC50 96 h: = 650 mg/L static (Lepomis macrochirus) Dimethyl succinate 106-65-0 LC50 96 h: 50-100 mg/L static (Brachydanio rerio) Persistence and Degradability No information available. Bioaccumulation No information available. Chemical Name Log Pow Propylene glycol monomethyl ether -0.437 Acetone -0.24 2-Butoxyethanol 0.81 Dimethyl succinate 0.19 Other Adverse Effects No information available. 13. DISPOSAL CONSIDERATIONS Waste Disposal Methods Dispose of in accordance with federal, state, and local regulations Contaminated Packaging Do not re-use empty containers. Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes Acetone - 67-64-1 Included in waste stream: F039 U002 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Acetone Ignitable n-Amyl acetate Toxic Ignitable 57003 - Triple S Graffiti Remover Wipes Revision Date 24-Sep-2013 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 8 / 9 14. TRANSPORT INFORMATION DOT Proper shipping name Consumer commodity Hazard Class ORM-D Description Consumer commodity, ORM-D 15. REGULATORY INFORMATION International Inventories TSCA Complies Legend TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List U.S. Federal Regulations Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372: Chemical Name CAS-No Weight % SARA 313 - Threshold Values % Tripropylene glycol monomethyl ether 25498-49-1 10-30 1.0 2-Butoxyethanol 111-76-2 5-10 1.0 SARA 311/312 Hazard Categories Acute Health Hazard Yes Chronic Health Hazard No Fire Hazard Yes Sudden Release of Pressure Hazard No Reactive Hazard No Clean Water Act This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42): Chemical Name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances n-Amyl acetate 5000 lb X CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302): Chemical Name Hazardous Substances RQs Extremely Hazardous Substances RQs RQ Acetone 5000 lb RQ 5000 lb final RQ RQ 2270 kg final RQ n-Amyl acetate 5000 lb RQ 5000 lb final RQ RQ 2270 kg final RQ U.S. State Regulations 57003 - Triple S Graffiti Remover Wipes Revision Date 24-Sep-2013 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 9 / 9 California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations "X" designates that the ingredients are listed on the state right to know list. Chemical Name New Jersey Massachusetts Pennsylvania Illinois Rhode Island Tripropylene glycol monomethyl ether X X Propylene glycol monomethyl ether X X X X Acetone X X X X 2-Butoxyethanol X X X X X n-Amyl acetate X X X X U.S. EPA Label Information EPA Pesticide Registration Number Not applicable 16. OTHER INFORMATION NFPA Health Hazard 2 Flammability 3 Instability 0 Physical and Chemical Hazards - HMIS Health Hazard 2 Flammability 3 Physical Hazard 0 Personal Protection X Prepared By Product Stewardship 23 British American Blvd. Latham, NY 12110 1-800-572-6501 Issuing Date 24-Sep-2013 Revision Date 24-Sep-2013 Revision Note Initial Release. General Disclaimer The information provided on this SDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. End of Safety Data Sheet