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Home My WebLink AboutTerminator5099 Safety Data Sheet Issue Date: 01-Apr-2014 Revision Date: 14-Sep-2017 Version 3 _____________________________________________________________________________________________ Page 1 / 9 1. IDENTIFICATION Product Identifier Product Name Buckeye Terminator Other means of identification SDS # BE-5099 Product Code 5099 Registration Number(s) EPA Reg. No. 6836-75-559 UN/ID No UN1760 Recommended use of the chemical and restrictions on use Recommended Use EPA registered disinfectant. Details of the supplier of the safety data sheet Supplier Address Buckeye International, Inc. 2700 Wagner Place Maryland Heights, MO 63043 USA Emergency Telephone Number Company Phone Number 1-314-291-1900 Emergency Telephone (24 hr) Transportation - INFOTRAC 1-352-323-3500 (International) 1-800-535-5053 (North America) Medical - (International) 1-651-632-8956 (North America) 1-800-303-0441 2. HAZARDS IDENTIFICATION Emergency Overview This chemical is a product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-EPA registered chemicals. Please see Section 15 for additional EPA information. Appearance Clear green liquid Physical state Liquid Odor Mild Fragrance added Classification Skin corrosion/irritation Category 1 Sub-category B Serious eye damage/eye irritation Category 1 Signal Word Danger Hazard statements Causes severe skin burns and eye damage BE-5099 - Buckeye Terminator Revision Date: 14-Sep-2017 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 2 / 9 Precautionary Statements - Prevention Wear protective gloves/protective clothing/eye protection/face protection Wash face, hands and any exposed skin thoroughly after handling Do not breathe dust/fume/gas/mist/vapors/spray Precautionary Statements - Response If exposed or concerned: Get medical advice/attention IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTER or doctor IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Immediately call a poison center or doctor/physician IF SWALLOWED: Rinse mouth. Do NOT induce vomiting Precautionary Statements - Storage Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No. Weight-% Nonylphenol Ethoxylate 127087-87-0 1.5-3.5 Di-n-alkyl Dimethyl Ammonium Chloride 68424-95-3 2.0-3.5 Alkyl dimethyl benzyl ammonium chloride (C12-16) 68424-85-1 1.0-2.5 Ethyl Alcohol 64-17-5 0.5-1.0 **If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.** 4. FIRST AID MEASURES First Aid Measures Eye Contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center or doctor/physician. Skin Contact IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Take off contaminated clothing and wash it before reuse. Immediately call a poison center or doctor/physician. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, give artificial respiration. Immediately call a poison center or doctor/physician. Ingestion IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Have person sip a glass of water if able to swallow. Never give anything by mouth to an unconscious person. Immediately call a poison center or doctor/physician. BE-5099 - Buckeye Terminator Revision Date: 14-Sep-2017 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 3 / 9 Most important symptoms and effects Symptoms Causes severe skin burns and eye damage. Mist or vapor inhalation can cause irritation to the nose, throat, and upper respiratory tract. Ingestion may cause nausea and headache. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. If the product is ingested, probable mucosal damage may contraindicate the use of gastric lavage. Dermatitis or other pre-existing skin conditions may be aggravated by overexposure to this product. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Dry chemical. Foam. Water. Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Combustion products may be toxic. Hazardous Combustion Products Carbon oxides. Nitrogen oxides (NOx). Hydrogen chloride. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Use personal protective equipment as required. Environmental precautions Environmental precautions Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information. See Section 13: DISPOSAL CONSIDERATIONS. See Section 12 for additional Ecological Information. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for Clean-Up Pick up with mop, wet/dry vac, or absorbent material. Rinse area with clear water and allow floor to dry before allowing traffic. 7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Use personal protection recommended in Section 8. Wash face, hands and any exposed skin thoroughly after handling. Do not breathe dust/fume/gas/mist/vapors/spray. Conditions for safe storage, including any incompatibilities Storage Conditions Keep container tightly closed and store in a cool, dry and well-ventilated place. Keep container closed when not in use. BE-5099 - Buckeye Terminator Revision Date: 14-Sep-2017 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 4 / 9 Packaging Materials Rinse container before discarding. Incompatible Materials Chlorine bleach. Anionic detergents. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Ethyl Alcohol 64-17-5 STEL: 1000 ppm TWA: 1000 ppm TWA: 1900 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1900 mg/m3 IDLH: 3300 ppm TWA: 1000 ppm TWA: 1900 mg/m3 Appropriate engineering controls Engineering Controls Ensure adequate ventilation, especially in confined areas. Eyewash stations. Showers. Individual protection measures, such as personal protective equipment Eye/Face Protection Splash goggles or safety glasses. Skin and Body Protection Rubber gloves. Normal work clothing (long sleeved shirts and long pants) is recommended. Wear water or chemical resistant footwear when scrubbing floors. Respiratory Protection Refer to 29 CFR 1910.134 for respiratory protection requirements. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid Appearance Clear green liquid Odor Mild Fragrance added Color Clear green Odor Threshold Not determined Property Values Remarks • Method pH 11.8-12.2 (conc.) 9.7-10.7 (1:64 dilution) Melting Point/Freezing Point Not determined Boiling Point/Boiling Range 100 °C / 212 °F Flash Point >93.3 °C / >200 °F Tag Closed Cup Evaporation Rate 1.0 (Water = 1) Flammability (Solid, Gas) Liquid-Not Applicable Flammability Limits in Air Upper Flammability Limits Not Applicable Lower Flammability Limit Not Applicable Vapor Pressure Not determined Vapor Density Not determined Relative Density 1.01 Water Solubility Infinite Solubility in other solvents Not determined Partition Coefficient Not determined Auto-ignition Temperature Not determined Decomposition Temperature Not determined Kinematic Viscosity Not determined Dynamic Viscosity Not determined Explosive Properties Not determined Oxidizing Properties Not determined BE-5099 - Buckeye Terminator Revision Date: 14-Sep-2017 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 5 / 9 10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization Hazardous polymerization does not occur. Conditions to Avoid Keep separated from incompatible substances. Keep out of reach of children. Incompatible Materials Chlorine bleach. Anionic detergents. Hazardous Decomposition Products Thermal decomposition can lead to release of irritating and toxic gases and vapors. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Eye Contact Causes severe eye damage. Skin Contact Causes severe skin burns. Inhalation Avoid breathing vapors or mists. Ingestion Do not ingest. Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Nonylphenol Ethoxylate 127087-87-0 = 1310 mg/kg ( Rat ) - - Alkyl dimethyl benzyl ammonium chloride (C12-16) 68424-85-1 = 426 mg/kg ( Rat ) - - Ethyl Alcohol 64-17-5 = 7060 mg/kg ( Rat ) - = 124.7 mg/L ( Rat ) 4 h Information on physical, chemical and toxicological effects Symptoms Please see section 4 of this SDS for symptoms. Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity The ingredient in this product is only classified as a carcinogen when consumed as an alcoholic beverage in long-term studies. Chemical Name ACGIH IARC NTP OSHA Ethyl Alcohol 64-17-5 A3 Group 1 Known X BE-5099 - Buckeye Terminator Revision Date: 14-Sep-2017 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 6 / 9 Legend ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans NTP (National Toxicology Program) Known - Known Carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Numerical measures of toxicity Not determined. 12. ECOLOGICAL INFORMATION Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Component Information Chemical Name Algae/aquatic plants Fish Crustacea Ethyl Alcohol 64-17-5 12.0 - 16.0: 96 h Oncorhynchus mykiss mL/L LC50 static 13400 - 15100: 96 h Pimephales promelas mg/L LC50 flow-through 100: 96 h Pimephales promelas mg/L LC50 static 10800: 24 h Daphnia magna mg/L EC50 2: 48 h Daphnia magna mg/L EC50 Static 9268 - 14221: 48 h Daphnia magna mg/L LC50 Persistence/Degradability Not determined. Bioaccumulation Not determined. Mobility Chemical Name Partition Coefficient Ethyl Alcohol 64-17-5 -0.32 Other Adverse Effects Not determined 13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. California Hazardous Waste Status Chemical Name California Hazardous Waste Status Ethyl Alcohol 64-17-5 Toxic Ignitable BE-5099 - Buckeye Terminator Revision Date: 14-Sep-2017 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 7 / 9 14. TRANSPORT INFORMATION Note Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances. DOT UN/ID No UN1760 Proper Shipping Name Corrosive liquid, n.o.s. (Dialkyldimethylammonium chloride) Hazard Class 8 Packing Group II IATA UN/ID No UN1760 Proper Shipping Name Corrosive liquid, n.o.s. (Dialkyldimethylammonium chloride) Hazard Class 8 Packing Group II IMDG Not regulated UN/ID No UN1760 Proper Shipping Name Corrosive liquid, n.o.s. (Dialkyldimethylammonium chloride) Hazard Class 8 Packing Group II Marine Pollutant Not a marine pollutant 15. REGULATORY INFORMATION International Inventories Chemical Name TSCA DSL/NDSL EINECS/E LINCS ENCS IECSC KECL PICCS AICS Nonylphenol Ethoxylate X X X Present X Present X X Di-n-alkyl Dimethyl Ammonium Chloride X X X Present X Present X X Alkyl dimethyl benzyl ammonium chloride (C12-16) X X X Present X Present X X Ethyl Alcohol X X X Present X Present X X Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). SARA 313 Not determined BE-5099 - Buckeye Terminator Revision Date: 14-Sep-2017 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 8 / 9 CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals. Chemical Name California Proposition 65 Ethyl Alcohol - 64-17-5 Carcinogen Developmental U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania Water 7732-18-5 X Ethyl Alcohol 64-17-5 X X X EPA Pesticide Registration Number EPA Reg. No 6836-75-559 EPA Statement This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: EPA Pesticide Label Signal Word: Danger Corrosive. Causes irreversible eye damage and skin burns. Do not get in eyes, on skin or on clothing. Wear protective eyewear (goggles, face shield or safety glasses), protective (rubber or chemical resistant) gloves and protective clothing. Harmful if swallowed or absorbed through the skin. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco or using the toilet. Remove contaminated clothing and wash clothing before reuse Difference between SDS and EPA pesticide label EPA OSHA Signal Word Danger Danger Skin corrosion/irritation Causes skin burns Causes severe skin burns Serious eye damage/eye irritation Causes irreversible eye damage Causes serious eye damage BE-5099 - Buckeye Terminator Revision Date: 14-Sep-2017 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 9 / 9 16. OTHER INFORMATION NFPA Health Hazards 3 Flammability 1 Instability 0 Special Hazards Not determined HMIS Health Hazards Not determined Flammability Not determined Physical hazards Not determined Personal Protection Not determined Issue Date: 01-Apr-2014 Revision Date: 14-Sep-2017 Revision Note: Regulatory Update Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet