Loading...
HomeMy WebLinkAboutSSS-Fresh-Breeze-Foam-Disinfectant-CleanerProduct name: SSS Fresh Breeze Foam Disinfectant Cleaner Product #: 1000026112 Version #: 01 Issue date: 03-24-2015 SDS US 1 / 10 SAFETY DATA SHEET 1. Identification Product number 21006 Product identifier SSS Fresh Breeze Foam Disinfectant Cleaner Company information Triple S 2 Executive Park Dr Billerica, MA 01862 United States Company Phone 1-800-323-2251; Emergency Phone: 1-888-779-1339 Version # 01 Recommended use Cleaner Recommended restrictions None known. 2. Hazard(s) identification Physical hazards Health hazards Environmental hazards OSHA defined hazards Label elements Flammable aerosols Skin corrosion/irritation Serious eye damage/eye irritation Not classified. Not classified. Category 1 Category 1 Category 1 Signal word Danger Hazard statement Extremely flammable aerosol. Causes severe skin burns and eye damage. Causes serious eye damage. Precautionary statement Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Do not breathe mist or vapor. Wash thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. Response If swallowed: Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. Specific treatment (see this label). Wash contaminated clothing before reuse. Storage Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise classified (HNOC) None known. Supplemental information None. 3. Composition/information on ingredients Mixtures Chemical name Common name and synonyms CAS number % 2-Butoxyethanol 111-76-2 2.5 - 10 Product name: SSS Fresh Breeze Foam Disinfectant Cleaner Product #: 1000026112 Version #: 01 Issue date: 03-24-2015 SDS US 2 / 10 Chemical name Common name and synonyms CAS number % Butane EDTA Tertrasodium Salt 106-97-8 64-02-8 1 - 2.5 1 - 2.5 Other components below reportable levels 90 - 100 *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. Composition comments For the full text of the R phrases mentioned in this Section, see Section 16. 4. First-aid measures Inhalation Move to fresh air. Call a physician if symptoms develop or persist. Skin contact Take off immediately all contaminated clothing. Take off immediately all contaminated clothing. Rinse skin with water/shower. Call a physician or poison control center immediately. Chemical burns must be treated by a physician. Wash contaminated clothing before reuse. Wash clothing separately before reuse. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a physician or poison control center immediately. Ingestion Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed Burning pain and severe corrosive skin damage. Causes serious eye damage. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including blindness could result. Provide general supportive measures and treat symptomatically. Chemical burns: Flush with water immediately. While flushing, remove clothes which do not adhere to affected area. Call an ambulance. Continue flushing during transport to hospital. Keep victim under observation. Symptoms may be delayed. General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire-fighting equipment/instructions Do not use water jet as an extinguisher, as this will spread the fire. Contents under pressure. Pressurized container may explode when exposed to heat or flame. During fire, gases hazardous to health may be formed. Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. In the event of fire and/or explosion do not breathe fumes. General fire hazards Extremely flammable aerosol. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate protective equipment and clothing during clean-up. Do not breathe mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid discharge into drains, water courses or onto the ground. Product name: SSS Fresh Breeze Foam Disinfectant Cleaner Product #: 1000026112 Version #: 01 Issue date: 03-24-2015 SDS US 3 / 10 7. Handling and storage Precautions for safe handling Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Avoid contact with skin, eyes and clothing. All equipment used when handling the product must be grounded. Use non-sparking tools and explosion-proof equipment. Do not re-use empty containers. Do not breathe mist or vapor. Do not get in eyes, on skin, or on clothing. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Conditions for safe storage, including any incompatibilities Level 1 Aerosol. Store locked up. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Store in a well-ventilated place. Refrigeration recommended. Store away from incompatible materials (see Section 10 of the SDS). Level 1 Aerosol (NFPA 30B) 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value 2-Butoxyethanol (CAS 111-76-2) US. ACGIH Threshold Limit Values PEL 240 mg/m3 50 ppm Components Type Value 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) TWA 20 ppm STEL 1000 ppm US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) Biological limit values ACGIH Biological Exposure Indices TWA 24 mg/m3 5 ppm TWA 1900 mg/m3 800 ppm Components Value Determinant Specimen Sampling Time 2-Butoxyethanol (CAS 111-76-2) 200 mg/g Butoxyacetic acid (BAA), Creatinine in urine * with hydrolysis * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies 2-Butoxyethanol (CAS 111-76-2) Skin designation applies. US - Tennesse OELs: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US NIOSH Pocket Guide to Chemical Hazards: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. Product name: SSS Fresh Breeze Foam Disinfectant Cleaner Product #: 1000026112 Version #: 01 Issue date: 03-24-2015 SDS US 4 / 10 Appropriate engineering controls Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles) and a face shield. Hand protection Wear appropriate chemical resistant gloves. Skin protection Other Wear appropriate chemical resistant clothing. Respiratory protection If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an air-supplied respirator. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Physical state Liquid. Form Aerosol. Color Yellow. Odor Characteristic. Odor threshold Not available. pH 11.8 - 12.8 estimated Melting point/freezing point Not available. Initial boiling point and boiling range 212 °F (100 °C) estimated Flash point -156.0 °F (-104.4 °C) Propellant estimated Evaporation rate Not available. Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Not available. Not available. Explosive limit - lower (%) Not available. Explosive limit - upper (%) Not available. Vapor pressure 60 - 70 psig @ 70F estimated Vapor density Not available. Relative density Not available. Solubility(ies) Solubility (water) Not available. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. Other information Specific gravity 0.979 estimated estimated Product name: SSS Fresh Breeze Foam Disinfectant Cleaner Product #: 1000026112 Version #: 01 Issue date: 03-24-2015 SDS US 5 / 10 10. Stability and reactivity Reactivity Reacts violently with strong acids. This product may react with oxidizing agents. Chemical stability Material is stable under normal conditions. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. Hazardous polymerization does not occur. Conditions to avoid Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Do not mix with other chemicals. Contact with incompatible materials. Fire or intense heat may cause violent rupture of packages. Incompatible materials Acids. Strong oxidizing agents. Oxidizing agents. Hazardous decomposition products No hazardous decomposition products are known. 11. Toxicological information Information on likely routes of exposure Ingestion Causes digestive tract burns. Ingestion may cause severe irritation of the mouth, the esophagus and the gastrointestinal tract. Inhalation May cause irritation to the respiratory system. Prolonged inhalation may be harmful. Skin contact Causes severe skin burns. 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. Eye contact Causes serious eye damage. Symptoms related to the physical, chemical and toxicological characteristics Burning pain and severe corrosive skin damage. Causes serious eye damage. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including blindness could result. Causes severe eye damage. Information on toxicological effects Acute toxicity Expected to be a low hazard for usual industrial or commercial handling by trained personnel. Product Species 19 OZ FOAMING DSNFCTNT DEOD (CAS Mixture) Acute Dermal LD50 Guinea pig Test Results 4742.2681 ml/kg, 24 Hours estimated 150.5155 ml/kg, 4 Days estimated Inhalation Rabbit 8969.0723 mg/kg, 24 Hours estimated 3095.6687 ml/kg, 24 Hours estimated Rat 40454.3516 mg/kg, 24 Hours estimated 4536 mg/kg LC100 Cat 3000 % estimated LC50 Mouse 41233.332 mg/l, 120 Minutes estimated 1733.3334 %, 120 Minutes estimated 533.3334 mm/l, 2 Hours estimated Rabbit 8247.4229 ppm, 7 Hours estimated Rat 9084.1875 ppm, 4 Hours estimated 861.3093 mg/l, 4 Hours estimated 44 mg/l/4h Oral LD100 Rabbit 14329.8965 mg/kg estimated LD50 Dog 14329.8965 mg/kg estimated Guinea pig 24742.2676 mg/kg estimated Rat Product name: SSS Fresh Breeze Foam Disinfectant Cleaner Product #: 1000026112 Version #: 01 Issue date: 03-24-2015 SDS US 6 / 10 Components Species 2-Butoxyethanol (CAS 111-76-2) Acute Dermal LD50 Guinea pig Test Results 230 ml/kg, 24 Hours 7.3 ml/kg, 4 Days Inhalation Rabbit 450 ml/kg, 24 Hours 435 mg/kg, 24 Hours 0.63 ml/kg Rat > 2000 mg/kg, 24 Hours LC50 Rabbit 400 ppm, 7 Hours Oral Rat 450 ppm, 4 Hours LD100 Rabbit 695 mg/kg LD50 Dog > 695 mg/kg Guinea pig 1200 mg/kg Rat 530 - 2800 mg/kg Butane (CAS 106-97-8) Acute Inhalation LC50 Mouse 1237 mg/l, 120 Minutes 52 %, 120 Minutes Rat 1355 mg/l EDTA Tertrasodium Salt (CAS 64-02-8) Acute Oral LD50 Rat 1658 mg/kg * Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Causes severe skin burns and eye damage. Serious eye damage/eye irritation Respiratory or skin sensitization Causes serious eye damage. Respiratory sensitization Not a respiratory sensitizer. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity 2-Butoxyethanol (CAS 111-76-2) 3 Not classifiable as to carcinogenicity to humans. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Not classified. Not classified. Aspiration hazard Not an aspiration hazard. Product name: SSS Fresh Breeze Foam Disinfectant Cleaner Product #: 1000026112 Version #: 01 Issue date: 03-24-2015 SDS US 7 / 10 Chronic effects Prolonged inhalation may be harmful. May be harmful if absorbed through skin. 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. 12. Ecological information Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Product Species Test Results 19 OZ FOAMING DSNFCTNT DEOD LB(CAS Mixture) Aquatic Algae Crustacea Fish Components IC50 EC50 LC50 Algae Daphnia Fish Species 86.0535 mg/L, 72 Hours 43604 mg/L, 48 Hours 1165 mg/L, 96 Hours Test Results 2-Butoxyethanol (CAS 111-76-2) Aquatic Fish LC50 Inland silverside (Menidia beryllina) 1250 mg/l, 96 hours EDTA Tertrasodium Salt (CAS 64-02-8) Aquatic Algae Fish IC50 LC50 Algae Bluegill (Lepomis macrochirus) 1.01 mg/L, 72 Hours 472 - 500 mg/l, 96 hours * Estimates for product may be based on additional component data not shown. Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential No data available. Partition coefficient n-octanol / water (log Kow) 2-Butoxyethanol 0.83 Butane 2.89 Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused products Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Do not re-use empty containers. 14. Transport information DOT UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Label(s) Packing group UN1950 Aerosols, flammable, corrosive 2.1 8 2.1, 8 Not applicable. Product name: SSS Fresh Breeze Foam Disinfectant Cleaner Product #: 1000026112 Version #: 01 Issue date: 03-24-2015 SDS US 8 / 10 Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Read safety instructions, SDS and emergency procedures before handling. Special provisions Packaging exceptions Packaging non bulk Packaging bulk A34 306 None None This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity. Until 12/31/2020, the "Consumer Commodity - ORM-D" marking may still be used in place of the new limited quantity diamond mark for packages of UN 1950 Aerosols. Limited quantities require the limited quantity diamond mark on cartons after 12/31/20 and may be used now in place of the "Consumer Commodity ORM-D" marking and both may be displayed concurrently. IATA UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Label(s) Packing group Environmental hazards ERG Code UN1950 Aerosols, flammable, containing substances in Class 8, Packing Group III 2.1 8 2.1, 8 Not applicable. No. 10C Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Read safety instructions, SDS and emergency procedures before handling. Other information Passenger and cargo aircraft Cargo aircraft only Packaging Exceptions IMDG UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Label(s) Packing group Environmental hazards Marine pollutant EmS Allowed. Allowed. LTD QTY UN1950 AEROSOLS 2.1 8 2,8 Not applicable. No. F-D,S-U Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Read safety instructions, SDS and emergency procedures before handling. Packaging Exceptions Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code DOT LTD QTY Not applicable. Product name: SSS Fresh Breeze Foam Disinfectant Cleaner Product #: 1000026112 Version #: 01 Issue date: 03-24-2015 SDS US 9 / 10 IATA; IMDG 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Chemical name CAS number Reportable quantity Threshold planning quantity Threshold planning quantity, lower value Threshold planning quantity, upper value Anhydrous Ammonia 7664-41-7 100 500 lbs Hydrogen Peroxide 7722-84-1 1000 1000 lbs SARA 311/312 Hazardous No chemical SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Butane (CAS 106-97-8) Safe Drinking Water Act (SDWA) Not regulated. US state regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. US. Massachusetts RTK - Substance List 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) US. New Jersey Worker and Community Right-to-Know Act 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) US. Pennsylvania Worker and Community Right-to-Know Law 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) Product name: SSS Fresh Breeze Foam Disinfectant Cleaner Product #: 1000026112 Version #: 01 Issue date: 03-24-2015 SDS US 10 / 10 US. Rhode Island RTK Butane (CAS 106-97-8) US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Domestic Substances List (DSL) Canada Non-Domestic Substances List (NDSL) China Inventory of Existing Chemical Substances in China (IECSC) Europe European Inventory of Existing Commercial Chemical Substances (EINECS) Europe European List of Notified Chemical Substances (ELINCS) Japan Inventory of Existing and New Chemical Substances (ENCS) Korea Existing Chemicals List (ECL) New Zealand New Zealand Inventory Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) No Yes No No No No No No No No Yes A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 03-24-2015 Version # 01 Disclaimer The information in the sheet was written based on the best knowledge and experience currently available. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.