HomeMy WebLinkAboutSSS-Chalkboard-Whiteboard-CleanerSAFETY DATA SHEET
SSS® Chalkboard & Whiteboard Cleaner (#05156)
Version 1.0 Revision Date 04/27/2015 Print Date 05/30/2015
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SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Material name : SSS® Chalkboard & Whiteboard Cleaner
Material number : A00101
Manufacturer or supplier's details
Company : Triple S
Address : 2 Executive Park Drive
Billerica, MA 01862
Telephone : 978-667-7900
Emergency telephone numbers
For SDS Information : 978-667-7900
For a Medical Emergency : 1-888-779-1339
For a Transportation
Emergency
: 1-888-779-1339
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview
Appearance Aerosol containing a liquefied gas
Colour white
Odour characteristic
GHS Classification
Gases under pressure : Liquefied gas
GHS Label element
Hazard pictograms :
Signal word : Warning
Hazard statements : H280 Contains gas under pressure; may explode if heated.
Precautionary statements : Storage:
P410 + P403 Protect from sunlight. Store in a well-ventilated
place.
Potential Health Effects
Carcinogenicity:
IARC No component of this product present at levels greater than or
equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.
ACGIH Confirmed animal carcinogen with unknown relevance to
humans
SAFETY DATA SHEET
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Version 1.0 Revision Date 04/27/2015 Print Date 05/30/2015
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ethanol 64-17-5
2-butoxyethanol 111-76-2
OSHA No component of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential
carcinogen by OSHA.
NTP No component of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture : Mixture
Hazardous components
Chemical Name CAS-No. Concentration [%]
propane 74-98-6 >= 1 - < 5
ethanol 64-17-5 >= 1 - < 5
butane 106-97-8 >= 1 - < 5
2-butoxyethanol 111-76-2 >= 1 - < 5
SECTION 4. FIRST AID MEASURES
General advice : Do not leave the victim unattended.
Move out of dangerous area.
Show this safety data sheet to the doctor in attendance.
If inhaled : If inhaled, remove to fresh air.
If symptoms persist, call a physician.
In case of skin contact : In case of contact, immediately flush skin with plenty of water
for at least 15 minutes while removing contaminated clothing
and shoes.
Get medical attention if irritation develops and persists.
In case of eye contact : Rinse immediately with plenty of water for at least 15 minutes.
Remove contact lenses.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.
If swallowed : DO NOT induce vomiting unless directed to do so by a
physician or poison control center.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
SECTION 5. FIREFIGHTING MEASURES
Suitable extinguishing media : Dry chemical
Carbon dioxide (CO2)
Foam
Unsuitable extinguishing
media
: High volume water jet
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Version 1.0 Revision Date 04/27/2015 Print Date 05/30/2015
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Hazardous combustion
products
: Carbon dioxide (CO2)
Carbon monoxide
Smoke
Specific extinguishing
methods
: Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Further information : Standard procedure for chemical fires.
Special protective equipment
for firefighters
: Wear self-contained breathing apparatus for firefighting if
necessary.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions,
protective equipment and
emergency procedures
: Use personal protective equipment.
Beware of vapours accumulating to form explosive
concentrations. Vapours can accumulate in low areas.
Environmental precautions : Prevent further leakage or spillage if safe to do so.
Methods and materials for
containment and cleaning up
: Sweep up or vacuum up spillage and collect in suitable
container for disposal.
Soak up with inert absorbent material (e.g. sand, silica gel,
acid binder, universal binder, sawdust).
SECTION 7. HANDLING AND STORAGE
Advice on safe handling : Avoid contact with skin and eyes.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the
application area.
Dispose of rinse water in accordance with local and national
regulations.
Conditions for safe storage : BEWARE: Aerosol is pressurized. Keep away from direct sun
exposure and temperatures over 50 °C. Do not open by force
or throw into fire even after use. Do not spray on flames or
red-hot objects.
Observe label precautions.
Keep in a dry, cool and well-ventilated place.
Electrical installations / working materials must comply with
the technological safety standards.
Materials to avoid : Strong oxidizing agents
Do not freeze.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
Components CAS-No. Value type
(Form of
exposure)
Control
parameters /
Permissible
Basis
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concentration
propane 74-98-6 TWA 1,000 ppm ACGIH
TWA 1,000 ppm
1,800 mg/m3
NIOSH REL
TWA 1,000 ppm
1,800 mg/m3
OSHA Z-1
TWA 1,000 ppm
1,800 mg/m3
OSHA P0
ethanol 64-17-5 TWA 1,000 ppm ACGIH
TWA 1,000 ppm
1,900 mg/m3
NIOSH REL
TWA 1,000 ppm
1,900 mg/m3
OSHA Z-1
TWA 1,000 ppm
1,900 mg/m3
OSHA P0
butane 106-97-8 TWA 800 ppm
1,900 mg/m3
NIOSH REL
TWA 800 ppm
1,900 mg/m3
OSHA P0
2-butoxyethanol 111-76-2 TWA 20 ppm ACGIH
TWA 5 ppm
24 mg/m3
NIOSH REL
TWA 50 ppm
240 mg/m3
OSHA Z-1
TWA 25 ppm
120 mg/m3
OSHA P0
Biological occupational exposure limits
Component CAS-No. Control
parameters
Biological
specimen
Sampling
time
Permissible
concentration
Basis
2-BUTOXYETHANOL 111-76-2 Butoxyacetic
acid (BAA)
Urine End of
shift (As
soon as
possible
after
exposure
ceases)
200 mg/g ACGIH BEI
Remarks: Creatinine
Personal protective equipment
Respiratory protection : In case of insufficient ventilation, wear suitable respiratory
equipment.
In the case of dust or aerosol formation use respirator with an
approved filter.
Hand protection
Remarks : The suitability for a specific workplace should be discussed
with the producers of the protective gloves.
Eye protection : Safety glasses
Skin and body protection : impervious clothing
Choose body protection according to the amount and
concentration of the dangerous substance at the work place.
Hygiene measures : When using do not eat or drink.
SAFETY DATA SHEET
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When using do not smoke.
Wash hands before breaks and at the end of workday.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : Aerosol containing a liquefied gas
Colour : white
Odour : characteristic
Odour Threshold : no data available
pH : 10.5 - 11.5
Melting point/freezing point : no data available
Boiling point : no data available
Flash point :
no data available
Evaporation rate : no data available
Flammability (solid, gas) : The product is not flammable.
Upper explosion limit : no data available
Lower explosion limit : no data available
Vapour pressure : 482.6 hPa (21 °C)
Relative vapour density : no data available
Relative density : no data available
Density : 0.985 g/cm3
Solubility(ies)
Water solubility : soluble
Partition coefficient: n-
octanol/water
: no data available
Auto-ignition temperature : not determined
Thermal decomposition : no data available
Viscosity
Viscosity, kinematic : not determined
Heat of combustion : 3.08 kJ/g
SECTION 10. STABILITY AND REACTIVITY
Reactivity : Stable
Chemical stability : Stable under normal conditions.
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Possibility of hazardous
reactions
: No decomposition if stored and applied as directed.
Vapours may form explosive mixture with air.
Conditions to avoid : Heat, flames and sparks.
Incompatible materials : Strong oxidizing agents
Hazardous decomposition
products
: Carbon dioxide (CO2)
Carbon monoxide
SECTION 11. TOXICOLOGICAL INFORMATION
Acute toxicity
Product:
Acute oral toxicity : Acute toxicity estimate : > 5,000 mg/kg
Method: Calculation method
Acute inhalation toxicity : Acute toxicity estimate : > 10 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Method: Calculation method
Acute dermal toxicity : Acute toxicity estimate : > 5,000 mg/kg
Method: Calculation method
Components:
propane:
Acute inhalation toxicity : LC50 mouse: 1,237 mg/l
Exposure time: 2 h
LC50 rat: 658 mg/l
Exposure time: 4 h
LC50 rat: 1,355 mg/l
ethanol:
Acute oral toxicity : LD50 Oral rat: 7,060 mg/kg
Acute inhalation toxicity : LC50 rat: 124.7 mg/l
Exposure time: 4 h
butane:
Acute inhalation toxicity : LC50 mouse: 1,237 mg/l
Exposure time: 2 h
LC50 rat: 1,355 mg/l
Skin corrosion/irritation
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Product:
Remarks: May cause skin irritation and/or dermatitis.
Serious eye damage/eye irritation
Product:
Remarks: Vapours may cause irritation to the eyes, respiratory system and the skin.
Respiratory or skin sensitisation
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
no data available
Reproductive toxicity
no data available
propane:
ethanol:
butane:
2-butoxyethanol:
STOT - single exposure
no data available
STOT - repeated exposure
no data available
Aspiration toxicity
no data available
Further information
Product:
Remarks: no data available
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
no data available
Persistence and degradability
no data available
Bioaccumulative potential
Product:
Partition coefficient: n-
octanol/water
: Remarks: no data available
Components:
butane :
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Version 1.0 Revision Date 04/27/2015 Print Date 05/30/2015
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Partition coefficient: n-
octanol/water
: Pow: 2.89
Mobility in soil
no data available
Other adverse effects
no data available
Product:
Regulation 40 CFR Protection of Environment; Part 82 Protection of
Stratospheric Ozone - CAA Section 602 Class I
Substances
Remarks This product neither contains, nor was manufactured
with a Class I or Class II ODS as defined by the U.S.
Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A
+ B).
Additional ecological
information
: no data available
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Waste from residues : Do not dispose of waste into sewer.
Do not contaminate ponds, waterways or ditches with
chemical or used container.
Dispose of in accordance with local regulations.
Contaminated packaging : Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
Do not burn, or use a cutting torch on, the empty drum.
SECTION 14. TRANSPORT INFORMATION
Transportation Regulation: 49 CFR (USA):
ORM-D, CONSUMER COMMODITY
Transportation Regulation: IMDG (Vessel):
UN1950, AEROSOLS, NON-FLAMMABLE, 2.2, - Limited quantity
Transportation Regulation: IATA (Cargo Air):
UN1950, AEROSOLS, NON-FLAMMABLE, 2.2, - Limited quantity
Transportation Regulation: IATA (Passenger Air):
UN1950, AEROSOLS, NON-FLAMMABLE, 2.2, - Limited quantity
Transportation Regulation: TDG (Canada):
UN1950, AEROSOLS, NON-FLAMMABLE, 2.2, - Limited quantity
SAFETY DATA SHEET
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Version 1.0 Revision Date 04/27/2015 Print Date 05/30/2015
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SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity
Components CAS-No. Component RQ
(lbs)
Calculated product RQ
(lbs)
2,2'-iminodiethanol 111-42-2 100 *
*: Calculated RQ exceeds reasonably attainable upper limit.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
SARA 311/312 Hazards : Sudden Release of Pressure Hazard
SARA 302 : SARA 302: No chemicals in this material are subject to the
reporting requirements of SARA Title III, Section 302.
SARA 313 : SARA 313: This material does not contain any chemical
components with known CAS numbers that exceed the
threshold (De Minimis) reporting levels established by SARA
Title III, Section 313.
California Prop 65 WARNING! This product contains a chemical known to the
State of California to cause cancer.
2,2'-iminodiethanol 111-42-2
The components of this product are reported in the following inventories:
TSCA On TSCA Inventory
DSL This product contains one or several components that are not on the
Canadian DSL nor NDSL.
AICS Not in compliance with the inventory
NZIoC Not in compliance with the inventory
PICCS Not in compliance with the inventory
IECSC Not in compliance with the inventory
Inventory Acronym and Validity Area Legend:
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan),
ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA)
SECTION 16. OTHER INFORMATION
SAFETY DATA SHEET
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Version 1.0 Revision Date 04/27/2015 Print Date 05/30/2015
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Further information
NFPA: HMIS III:
OSHA GHS Label Information:
Hazard pictograms :
Signal word : Warning:
Hazard statements : Contains gas under pressure; may explode if heated. Precautionary statements :
Storage: Protect from sunlight. Store in a well-ventilated place.
We believe the statements, technical information and recommendations contained herein are
reliable, but they are given without warranty or guarantee of any kind. The information in this
document applies to this specific material as supplied. It may not be valid for this material if it
is used in combination with any other materials. Users should make their own investigations
to determine the suitability and applicability of the information for their particular purposes.
This SDS has been prepared by the Compliance Services organization supporting this
manufacturer, supplier or distributor.
Flammability
Health Instability
3
0
0
Special hazard.
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
0
2
3
0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic