Loading...
HomeMy WebLinkAboutMinwax-Wood-Finish-Dark-WalnutMINWAX® WOOD FINISH® Dark Walnut Not available. Liquid. US/Canada: (800) 424-9300 Mexico: CHEMTREC México 800-681-9531. Available 24 hours and 365 days per year SAFETY DATA SHEET Product name Other means of identification Product type Emergency telephone number of the company Section 1. Identification : : : : Manufacturer :MINWAX Company 10 Mountainview Road Upper Saddle River, NJ 07458 Relevant identified uses of the substance or mixture and uses advised against Paint or paint related material. 2716 2716Product code : Product Information Telephone Number :US/Canada: (800) 523-9299 Mexico: 800-717-3123 / 55-5333-1501 Regulatory Information Telephone Number :US / Canada: (216) 566-2902 Mexico: 800-717-3123 / 55-5333-1501 Transportation Emergency Telephone Number :US / Canada: (800) 424-9300 Mexico: SETIQ 800-00-214-00 / 55-5559-1588 Available 24 hours and 365 days a year Section 2. Hazards identification FLAMMABLE LIQUIDS - Category 3 CARCINOGENICITY - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1 ASPIRATION HAZARD - Category 1 Classification of the substance or mixture : Signal word :Danger Hazard pictograms : GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 58.4% (oral), 58.4% (dermal), 58.4% (inhalation) OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Date of issue/Date of revision :4/13/2021 Date of previous issue :10/14/2020 Version :25 1/16 2716 MINWAX® WOOD FINISH® Dark Walnut SHW-85-NA-GHS-US Section 2. Hazards identification Precautionary statements Prevention :Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves, protective clothing and eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating or lighting equipment. Use non-sparking tools. Take action to prevent static discharges. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Response :IF exposed or concerned: Get medical advice or attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or doctor. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. Storage :Store locked up. Store in a well-ventilated place. Keep container tightly closed. Keep cool. Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations. General :Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. This product contains a Significant New Use Rule (SNUR) Chemical. Do not allow this product to enter drains, sewers, wastewater treatment systems, groundwater, streams, lakes or ponds. See Environmental Data Sheet (EDS) for additional details. Hazards not otherwise classified :DANGER: Rags, steel wool, other waste soaked with this product, and sanding residue may spontaneously catch fire if improperly discarded. Immediately place rags, steel wool, other waste soaked with this product, and sanding residue in a sealed, water-filled, metal container. Dispose of in accordance with local fire regulations. Flammable liquid and vapor. May be fatal if swallowed and enters airways. May cause respiratory irritation. May cause drowsiness or dizziness. Suspected of causing cancer. Causes damage to organs through prolonged or repeated exposure. :Hazard statements Please refer to the SDS for additional information. Keep out of reach of children. Do not transfer contents to other containers for storage. Supplemental label elements DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. : Section 3. Composition/information on ingredients Other means of identification :Not available. Substance/mixture CAS number/other identifiers :Mixture Date of issue/Date of revision :4/13/2021 Date of previous issue :10/14/2020 Version :25 2/16 2716 MINWAX® WOOD FINISH® Dark Walnut SHW-85-NA-GHS-US Section 3. Composition/information on ingredients Light Aliphatic Hydrocarbon ≥25 - ≤50 64742-47-8 Heavy Naphthenic Petroleum Oil ≥10 - ≤25 64742-52-5 Aliphatic Solvent ≥10 - ≤25 64742-47-8 Med. Aliphatic Hydrocarbon Solvent ≤5 64742-88-7 Light Aromatic Hydrocarbons <1 64742-95-6 trimethylbenzene <1 25551-13-7 Mineral Spirits (Odorless)<1 64742-47-8 1,3,5-Trimethylbenzene ≤0.3 108-67-8 1,2,4-Trimethylbenzene ≤0.3 95-63-6 Carbon Black ≤0.3 1333-86-4 Ingredient name CAS number% by weight There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Any concentration shown as a range is to protect confidentiality or is due to batch variation. Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important symptoms/effects, acute and delayed Inhalation :Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. :Ingestion Skin contact :No known significant effects or critical hazards. No known significant effects or critical hazards.:Eye contact Over-exposure signs/symptoms Potential acute health effects Date of issue/Date of revision :4/13/2021 Date of previous issue :10/14/2020 Version :25 3/16 2716 MINWAX® WOOD FINISH® Dark Walnut SHW-85-NA-GHS-US Section 4. First aid measures Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments :No specific treatment. Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness Adverse symptoms may include the following: nausea or vomiting No specific data. : : : Eye contact :No specific data. See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use dry chemical, CO₂, water spray (fog) or foam. Extinguishing media : : : Do not use water jet. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Date of issue/Date of revision :4/13/2021 Date of previous issue :10/14/2020 Version :25 4/16 2716 MINWAX® WOOD FINISH® Dark Walnut SHW-85-NA-GHS-US Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : :No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". This product contains a Significant New Use Rule (SNUR) Chemical. Do not allow this product to enter drains, sewers, wastewater treatment systems, groundwater, streams, lakes or ponds. See Environmental Data Sheet (EDS) for additional details. Section 7. Handling and storage Advice on general occupational hygiene Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. : Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. : Precautions for safe handling Date of issue/Date of revision :4/13/2021 Date of previous issue :10/14/2020 Version :25 5/16 2716 MINWAX® WOOD FINISH® Dark Walnut SHW-85-NA-GHS-US Section 7. Handling and storage Conditions for safe storage, including any incompatibilities Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. : Light Aliphatic Hydrocarbon 64742-47-8 ACGIH TLV (United States, 3/2020). Absorbed through skin. TWA: 200 mg/m³, (as total hydrocarbon vapor) 8 hours. Heavy Naphthenic Petroleum Oil 64742-52-5 OSHA PEL (United States, 5/2018). TWA: 5 mg/m³ 8 hours. ACGIH TLV (United States, 3/2020). TWA: 5 mg/m³ 8 hours. Form: Inhalable fraction NIOSH REL (United States, 10/2016). TWA: 5 mg/m³ 10 hours. Form: Mist STEL: 10 mg/m³ 15 minutes. Form: Mist Aliphatic Solvent 64742-47-8 ACGIH TLV (United States, 3/2020). Absorbed through skin. TWA: 200 mg/m³, (as total hydrocarbon vapor) 8 hours. Med. Aliphatic Hydrocarbon Solvent 64742-88-7 OSHA PEL (United States, 5/2018). TWA: 100 ppm 8 hours. TWA: 400 mg/m³ 8 hours. Light Aromatic Hydrocarbons 64742-95-6 None. trimethylbenzene 25551-13-7 ACGIH TLV (United States, 3/2020). TWA: 25 ppm 8 hours. TWA: 123 mg/m³ 8 hours. Mineral Spirits (Odorless)64742-47-8 ACGIH TLV (United States, 3/2020). Absorbed through skin. TWA: 200 mg/m³, (as total hydrocarbon vapor) 8 hours. 1,3,5-Trimethylbenzene 108-67-8 ACGIH TLV (United States, 3/2020). TWA: 25 ppm 8 hours. TWA: 123 mg/m³ 8 hours. NIOSH REL (United States, 10/2016). TWA: 25 ppm 10 hours. TWA: 125 mg/m³ 10 hours. 1,2,4-Trimethylbenzene 95-63-6 ACGIH TLV (United States, 3/2020). TWA: 25 ppm 8 hours. TWA: 123 mg/m³ 8 hours. NIOSH REL (United States, 10/2016). TWA: 25 ppm 10 hours. TWA: 125 mg/m³ 10 hours. Carbon Black 1333-86-4 ACGIH TLV (United States, 3/2020). TWA: 3 mg/m³ 8 hours. Form: Inhalable fraction Section 8. Exposure controls/personal protection Ingredient name Exposure limits Control parameters Occupational exposure limits (OSHA United States) CAS # Date of issue/Date of revision :4/13/2021 Date of previous issue :10/14/2020 Version :25 6/16 2716 MINWAX® WOOD FINISH® Dark Walnut SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection NIOSH REL (United States, 10/2016). TWA: 3.5 mg/m³ 10 hours. TWA: 0.1 mg of PAHs/cm³ 10 hours. OSHA PEL (United States, 5/2018). TWA: 3.5 mg/m³ 8 hours. Petroleum refining, hydrotreated light distillate 64742-47-8 CA British Columbia Provincial (Canada, 1/2020). Absorbed through skin. TWA: 200 mg/m³, (as total hydrocarbon vapour) 8 hours. CA Alberta Provincial (Canada, 6/2018). Absorbed through skin. 8 hrs OEL: 200 mg/m³, (as total hydrocarbon vapour) 8 hours. CA Ontario Provincial (Canada, 6/2019). Absorbed through skin. TWA: 200 mg/m³, (as total hydrocarbon vapour) 8 hours. Petroleum refining, hydrotreated light distillate 64742-47-8 CA British Columbia Provincial (Canada, 1/2020). Absorbed through skin. TWA: 200 mg/m³, (as total hydrocarbon vapour) 8 hours. CA Alberta Provincial (Canada, 6/2018). Absorbed through skin. 8 hrs OEL: 200 mg/m³, (as total hydrocarbon vapour) 8 hours. CA Ontario Provincial (Canada, 6/2019). Absorbed through skin. TWA: 200 mg/m³, (as total hydrocarbon vapour) 8 hours. Medium aliphatic solvent naphtha (petroleum) C9-C12 64742-88-7 CA Ontario Provincial (Canada, 6/2019). TWA: 525 mg/m³ 8 hours. Carbon black 1333-86-4 CA British Columbia Provincial (Canada, 1/2020). TWA: 3 mg/m³ 8 hours. Form: Inhalable CA Ontario Provincial (Canada, 6/2019). TWA: 3 mg/m³ 8 hours. Form: Inhalable particulate matter. CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 3.5 mg/m³ 8 hours. CA Quebec Provincial (Canada, 7/2019). TWAEV: 3.5 mg/m³ 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 7 mg/m³ 15 minutes. TWA: 3.5 mg/m³ 8 hours. Ingredient name Exposure limits Occupational exposure limits (Canada) Occupational exposure limits (Mexico) CAS # Date of issue/Date of revision :4/13/2021 Date of previous issue :10/14/2020 Version :25 7/16 2716 MINWAX® WOOD FINISH® Dark Walnut SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Hand protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side- shields. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls :Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Other skin protection :Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. This product contains a Significant New Use Rule (SNUR) Chemical. Do not allow this product to enter drains, sewers, wastewater treatment systems, groundwater, streams, lakes or ponds. See Environmental Data Sheet (EDS) for additional details. Environmental exposure controls : Light Aliphatic Hydrocarbon 64742-47-8 ACGIH TLV (United States, 3/2020). Absorbed through skin. TWA: 200 mg/m³, (as total hydrocarbon vapor) 8 hours. Aliphatic Solvent 64742-47-8 ACGIH TLV (United States, 3/2020). Absorbed through skin. TWA: 200 mg/m³, (as total hydrocarbon vapor) 8 hours. Exposure limitsCAS # Date of issue/Date of revision :4/13/2021 Date of previous issue :10/14/2020 Version :25 8/16 2716 MINWAX® WOOD FINISH® Dark Walnut SHW-85-NA-GHS-US Section 9. Physical and chemical properties Physical state Melting point/freezing point Vapor pressure Relative density Vapor density Solubility Liquid. Not available. 0.85 5 [Air = 1] 0.17 kPa (1.27 mm Hg) [at 20°C] Not available. Not available.Odor pH Not available.Color Evaporation rate 0.13 (butyl acetate = 1) Auto-ignition temperature Flash point Not available. Closed cup: 41°C (105.8°F) [Pensky-Martens Closed Cup] Not available. Not applicable. Viscosity Kinematic (40°C (104°F)): <0.205 cm2/s (<20.5 cSt) Not available.Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance Boiling point/boiling range :148°C (298.4°F) Flammability (solid, gas):Not available. Lower and upper explosive (flammable) limits :Lower: 1% Upper: 8.8% Decomposition temperature :Not available. Heat of combustion :30.734 kJ/g Aerosol product Molecular weight :Not applicable. Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability Reactive or incompatible with the following materials: oxidizing materials : : : Incompatible materials : Possibility of hazardous reactions :Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity :No specific test data related to reactivity available for this product or its ingredients. Date of issue/Date of revision :4/13/2021 Date of previous issue :10/14/2020 Version :25 9/16 2716 MINWAX® WOOD FINISH® Dark Walnut SHW-85-NA-GHS-US Section 11. Toxicological information Acute toxicity Heavy Naphthenic Petroleum Oil LD50 Oral Rat >5000 mg/kg - Light Aromatic Hydrocarbons LD50 Oral Rat 8400 mg/kg - trimethylbenzene LD50 Oral Rat 8970 mg/kg - 1,3,5-Trimethylbenzene LC50 Inhalation Vapor Rat 24000 mg/m³4 hours LD50 Oral Rat 5000 mg/kg - 1,2,4-Trimethylbenzene LC50 Inhalation Vapor Rat 18000 mg/m³4 hours LD50 Oral Rat 5 g/kg - Carbon Black LD50 Oral Rat >15400 mg/kg - Product/ingredient name Result Species Dose Exposure Carcinogenicity Not available. Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. Irritation/Corrosion Heavy Naphthenic Petroleum Oil Skin - Severe irritant Rabbit -500 mg - Light Aromatic Hydrocarbons Eyes - Mild irritant Rabbit -24 hours 100 uL - trimethylbenzene Eyes - Mild irritant Rabbit -24 hours 500 mg - Skin - Moderate irritant Rabbit -24 hours 500 mg - 1,3,5-Trimethylbenzene Eyes - Mild irritant Rabbit -24 hours 500 mg - Skin - Moderate irritant Rabbit -24 hours 20 mg - Product/ingredient name Result Score Exposure Observation Sensitization Not available. Species Specific target organ toxicity (single exposure) Information on toxicological effects Classification Carbon Black -2B - Product/ingredient name NTPIARCOSHA Date of issue/Date of revision :4/13/2021 Date of previous issue :10/14/2020 Version :25 10/16 2716 MINWAX® WOOD FINISH® Dark Walnut SHW-85-NA-GHS-US Section 11. Toxicological information Specific target organ toxicity (repeated exposure) Light Aliphatic Hydrocarbon Category 3 -Respiratory tract irritation Category 3 Narcotic effects Aliphatic Solvent Category 3 -Respiratory tract irritation Category 3 Narcotic effects Med. Aliphatic Hydrocarbon Solvent Category 3 -Respiratory tract irritation Category 3 Narcotic effects Light Aromatic Hydrocarbons Category 3 -Respiratory tract irritation Category 3 Narcotic effects Mineral Spirits (Odorless)Category 3 -Respiratory tract irritation Category 3 Narcotic effects 1,3,5-Trimethylbenzene Category 3 -Respiratory tract irritation 1,2,4-Trimethylbenzene Category 3 -Respiratory tract irritation Name Category Name Category Light Aliphatic Hydrocarbon Category 2 -- Aliphatic Solvent Category 2 -- Med. Aliphatic Hydrocarbon Solvent Category 1 -- Light Aromatic Hydrocarbons Category 2 -- Mineral Spirits (Odorless)Category 2 -- Aspiration hazard Name Result Light Aliphatic Hydrocarbon ASPIRATION HAZARD - Category 1 Aliphatic Solvent ASPIRATION HAZARD - Category 1 Med. Aliphatic Hydrocarbon Solvent ASPIRATION HAZARD - Category 1 Light Aromatic Hydrocarbons ASPIRATION HAZARD - Category 1 trimethylbenzene ASPIRATION HAZARD - Category 1 Mineral Spirits (Odorless)ASPIRATION HAZARD - Category 1 1,3,5-Trimethylbenzene ASPIRATION HAZARD - Category 1 1,2,4-Trimethylbenzene ASPIRATION HAZARD - Category 1 Route of exposure Target organs Route of exposure Target organs Information on the likely routes of exposure Inhalation :Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. :Ingestion Skin contact :No known significant effects or critical hazards. No known significant effects or critical hazards.:Eye contact Symptoms related to the physical, chemical and toxicological characteristics Eye contact :No specific data. :Not available. Potential acute health effects Date of issue/Date of revision :4/13/2021 Date of previous issue :10/14/2020 Version :25 11/16 2716 MINWAX® WOOD FINISH® Dark Walnut SHW-85-NA-GHS-US Section 11. Toxicological information Not available. Causes damage to organs through prolonged or repeated exposure.General : Suspected of causing cancer. Risk of cancer depends on duration and level of exposure. Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : No known significant effects or critical hazards.Teratogenicity : Developmental effects :No known significant effects or critical hazards. Fertility effects :No known significant effects or critical hazards. Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness Adverse symptoms may include the following: nausea or vomiting No specific data. : : : Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Numerical measures of toxicity Not available. Acute toxicity estimates Potential immediate effects :Not available. Short term exposure Potential delayed effects :Not available. Potential immediate effects :Not available. Long term exposure Potential delayed effects :Not available. Section 12. Ecological information Toxicity Light Aliphatic Hydrocarbon Acute LC50 2200 µg/l Fresh water Fish - Lepomis macrochirus 4 days Aliphatic Solvent Acute LC50 2200 µg/l Fresh water Fish - Lepomis macrochirus 4 days trimethylbenzene Acute LC50 5600 µg/l Marine water Crustaceans - Palaemonetes pugio 48 hours Mineral Spirits (Odorless)Acute LC50 2200 µg/l Fresh water Fish - Lepomis macrochirus 4 days 1,3,5-Trimethylbenzene Acute LC50 13000 µg/l Marine water Crustaceans - Cancer magister - Zoea 48 hours Acute LC50 12520 µg/l Fresh water Fish - Carassius auratus 96 hours Chronic NOEC 400 µg/l Fresh water Daphnia - Daphnia magna 21 days 1,2,4-Trimethylbenzene Acute LC50 4910 µg/l Marine water Crustaceans - Elasmopus 48 hours Product/ingredient name SpeciesResult Exposure Date of issue/Date of revision :4/13/2021 Date of previous issue :10/14/2020 Version :25 12/16 2716 MINWAX® WOOD FINISH® Dark Walnut SHW-85-NA-GHS-US Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Other adverse effects :No known significant effects or critical hazards. Product/ingredient name Light Aromatic Hydrocarbons -10 to 2500 high 1,3,5-Trimethylbenzene -161 low 1,2,4-Trimethylbenzene -243 low Product/ingredient name Aquatic half-life Photolysis Biodegradability Light Aromatic Hydrocarbons --Readily pectenicrus - Adult Acute LC50 7720 µg/l Fresh water Fish - Pimephales promelas 96 hours Persistence and degradability Soil/water partition coefficient (KOC) :Not available. Mobility in soil Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. :Disposal methods This product contains a Significant New Use Rule (SNUR) Chemical. Do not allow this product to enter drains, sewers, wastewater treatment systems, groundwater, streams, lakes or ponds. See Environmental Data Sheet (EDS) for additional details. Section 14. Transport information UN1263 UN1263 DOT Classification IMDG UN number TDG Classification UN1263 Mexico Classification UN1263 IATA UN1263 Date of issue/Date of revision :4/13/2021 Date of previous issue :10/14/2020 Version :25 13/16 2716 MINWAX® WOOD FINISH® Dark Walnut SHW-85-NA-GHS-US Section 14. Transport information PAINT 3 III PAINT. Marine pollutant (Light Aliphatic Hydrocarbon, Med. Aliphatic Hydrocarbon Solvent) 3 III This product may be re-classified as "Combustible Liquid," unless transported by vessel or aircraft. Non-bulk packages (less than or equal to 119 gal) of combustible liquids are not regulated as hazardous materials. The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg. Emergency schedules F-E, S- E UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards Special precautions for user Transport in bulk according to IMO instruments No.Yes. Not available. : Proper shipping name : Not available. : PAINT 3 III No. Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.18-2.19 (Class 3). PAINT 3 III No. - Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations. PAINT 3 III Yes. The environmentally hazardous substance mark is not required. The environmentally hazardous substance mark may appear if required by other transportation regulations. 128 ERG No. 128 128 ERG No.ERG No. Date of issue/Date of revision :4/13/2021 Date of previous issue :10/14/2020 Version :25 14/16 2716 MINWAX® WOOD FINISH® Dark Walnut SHW-85-NA-GHS-US Section 15. Regulatory information U.S. Federal regulations : SARA 313 TSCA 5(a)2 final significant new use rules: Chlorodiazocarboxylate This product contains a Significant New Use Rule (SNUR) Chemical. Do not allow this product to enter drains, sewers, wastewater treatment systems, groundwater, streams, lakes or ponds. See Environmental Data Sheet (EDS) for additional details. SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. California Prop. 65 Australia inventory (AIIC): Not determined. China inventory (IECSC): Not determined. Japan inventory (CSCL): Not determined. Japan inventory (ISHL): Not determined. Korea inventory (KECI): Not determined. New Zealand Inventory of Chemicals (NZIoC): Not determined. Philippines inventory (PICCS): Not determined. Taiwan Chemical Substances Inventory (TCSI): Not determined. Thailand inventory: Not determined. Turkey inventory: Not determined. Vietnam inventory: Not determined. International regulations International lists : Section 16. Other information 4/13/2021 History Date of printing Date of issue/Date of revision : :4/13/2021 Hazardous Material Information System (U.S.A.) 3 2 0 *Health Flammability Physical hazards Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service mark of the American Coatings Association, Inc. The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual. FLAMMABLE LIQUIDS - Category 3 On basis of test data CARCINOGENICITY - Category 2 Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 Calculation method SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1 Calculation method ASPIRATION HAZARD - Category 1 Calculation method Procedure used to derive the classification Classification Justification Date of issue/Date of revision :4/13/2021 Date of previous issue :10/14/2020 Version :25 15/16 2716 MINWAX® WOOD FINISH® Dark Walnut SHW-85-NA-GHS-US Section 16. Other information Version It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer, or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source. Date of previous issue : : Indicates information that has changed from previously issued version. Key to abbreviations : 10/14/2020 25 Notice to reader ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) N/A = Not available SGG = Segregation Group UN = United Nations Date of issue/Date of revision :4/13/2021 Date of previous issue :10/14/2020 Version :25 16/16 2716 MINWAX® WOOD FINISH® Dark Walnut SHW-85-NA-GHS-US