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John Deere Cool-Gard™ II Premix
Safety Data Sheet
according to the federal final rule of hazard communication revised on 2012 (HazCom 2012)
Date of issue: 07/30/2014 Version: 1.0
08/02/2014 EN (English) SDS Ref.: 81Q2 Page 1
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product form : Mixture
Trade name : John Deere Cool-Gard™ II Premix
Product code : TY26575, TY26576, TY26577, TY26578
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Engine Coolant and Anti-freeze
1.3. Details of the supplier of the safety data sheet
MANUFACTURER:
Northland Products
1000 Rainbow Drive
Waterloo, IA 50704
Tel: +1-319-234-5585
+1-800-772-1724
SUPPLIER:
Deere & Company
One John Deere Place
Moline, IL 61265
1.4. Emergency telephone number
Emergency number : Chemtrec 1-800-424-9300
Chemtrec (Outside USA) +1 703-527-3887 (24 hours)
Supplier: +1-309-748-5636 (24 hours)
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
GHS-US classification
Acute Tox. 4 (Oral) H302
Skin Irrit. 2 H315
Eye Irrit. 2A H319
STOT RE 2 H373
2.2. Label elements
GHS-US labelling
Hazard pictograms (GHS-US) :
GHS07
GHS08
Signal word (GHS-US) : Warning
Hazard statements (GHS-US) : H302 - Harmful if swallowed
H315 - Causes skin irritation
H319 - Causes serious eye irritation
H373 - May cause damage to organs (kidneys) through prolonged or repeated exposure (oral)
Precautionary statements (GHS-US) : P260 - Do not breathe dust, fume, mist, spray, vapours
P264 - Wash hands thoroughly after handling
P270 - Do not eat, drink or smoke when using this product
P280 - Wear protective gloves, eye protection, protective clothing
P301+P312 - If swallowed: Call a a doctor, a POISON CENTER if you feel unwell
P302+P352 - If on skin: Wash with plenty of water
P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P314 - Get medical advice/attention if you feel unwell
P321 - Specific treatment (see on this label)
P330 - Rinse mouth
P332+P313 - If skin irritation occurs: Get medical advice/attention
P337+P313 - If eye irritation persists: get medical advice/attention
P362 - Take off contaminated clothing and wash before reuse
P501 - Dispose of contents/container to comply with applicable local, national and international
regulation.
John Deere Cool-Gard™ II Premix
Safety Data Sheet
according to the federal final rule of hazard communication revised on 2012 (HazCom 2012)
08/02/2014 EN (English) SDS Ref.: 81Q2 2/10
2.3. Other hazards
other hazards which do not result in
classification
: Spills of this product present a serious slipping hazard.
2.4. Unknown acute toxicity (GHS-US)
No data available
SECTION 3: Composition/information on ingredients
3.1. Substance
Not applicable
Full text of H-phrases: see section 16
3.2. Mixture
Name Product identifier % GHS-US classification
Ethylene glycol (CAS No) 107-21-1 45 - 50 Acute Tox. 4 (Oral), H302
STOT RE 2, H373
Sodium tetraborate decahydrate (CAS No) 1303-96-4 0.5 - 1.5 Repr. 1B, H360
Sodium hydroxide (CAS No) 1310-73-2 0.5 - 1.5 Acute Tox. 4 (Dermal), H312
Skin Corr. 1A, H314
Eye Dam. 1, H318
SECTION 4: First aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice
(show the label where possible).
First-aid measures after inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Assure fresh
air breathing. If breathing is difficult, give oxygen. In all cases of doubt, or when symptoms
persist, seek medical advice.
First-aid measures after skin contact : Rinse and then wash skin thoroughly with water and soap. If skin irritation occurs: Get medical
advice/attention. Wash contaminated clothing before reuse.
First-aid measures after eye contact : In case of contact with eyes, rinse immediately with plenty of flowing water for 10 to 15 minutes
holding eyelids apart. Subsequently consult an ophthalmologist. Remove contact lenses, if
present and easy to do. Continue rinsing. If redness, burning, blurred vision or swelling occur,
transport to nearest medical facility for additional treatment. Get medical advice/attention.
First-aid measures after ingestion : If swallowed, rinse mouth with water (only if the person is conscious). Immediately call a
POISON CENTER or doctor/physician. Do NOT induce vomiting. If vomiting occurs naturally,
have victim lean forward to reduce risk of aspiration. Obtain emergency medical attention.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries : Causes damage to organs (kidneys) (Oral).
Symptoms/injuries after inhalation : Long-term (repeated). Inhalation of mist or aerosol may cause irritation to nose and throat.
Symptoms/injuries after skin contact : Causes skin irritation.
Symptoms/injuries after eye contact : Causes serious eye irritation. Swelling and inflammation.
Symptoms/injuries after ingestion : May be harmful if swallowed. Ingestion may cause nausea and vomiting. Depression of the
central nervous system, headaches, dizziness, drowsiness, loss of coordination. In the case of
extreme exposure there is a risk of severe metabolic acidosis and haemorrhagy. Death in
extreme cases. Symptoms may be delayed.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Symptoms may be
delayed.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water fog. Water spray. Sand.
Unsuitable extinguishing media : Do not use a water jet since it may cause the fire to spread.
5.2. Special hazards arising from the substance or mixture
Fire hazard : When heated above the flash point, releases vapours. Gas/vapours, flammable.
Explosion hazard : Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns
and injuries.
5.3. Advice for firefighters
Precautionary measures fire : Stop and contain spill/release if it can be done safely. If this cannot be done, allow fire to burn
under control. Gases/vapours, toxic.
Firefighting instructions : Exercise caution when fighting any chemical fire. Do not use direct water stream; may spread
fire. Burning liquids may be moved by flushing with water to protect personnel and minimize
property damage. Heat may build pressure, rupturing closed containers, spreading fire and
increasing risk of burns and injuries. Cool closed containers exposed to fire with water spray.
Prevent fire-fighting water from entering environment.
John Deere Cool-Gard™ II Premix
Safety Data Sheet
according to the federal final rule of hazard communication revised on 2012 (HazCom 2012)
08/02/2014 EN (English) SDS Ref.: 81Q2 3/10
Protective equipment for firefighters : Wear approved self-contained breathing apparatus (set on positive pressure mode). Do not enter
fire area without proper protective equipment, including respiratory protection.
Other information : Special danger of slipping by leaking/spilling product. Most vapors are heavier than air. They will
spread along ground and collect in low or confined areas (sewers, basements, tanks).
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Spilled material may present a slipping hazard. Stop leak if safe to do so. Eliminate all ignition
sources if safe to do so.
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Ensure adequate ventilation, especially in confined areas.
6.2. Environmental precautions
Prevent contamination of soil, drains and surface waters. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or
public waters.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : Approach from upwind. For small spills, absorb or cover with dry earth, sand, or other inert non-
combustible absorbent material and place into waste containers for later disposal. Gather the
product and place it in a spare container that has been suitably labelled. Consult the appropriate
authorities about waste disposal. Large spills: Contain large spills to maximize product recovery
or disposal. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as
possible. Collect spillage. Shovel into suitable and closed container for disposal. Minimize
generation of dust. Store away from other materials. Ensure all national/local regulations are
observed.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed : Special danger of slipping by leaking/spilling product.
Precautions for safe handling : Avoid contact with skin, eyes and clothes. Avoid breathing dust/fume/gas/mist/vapours/spray.
Provide good ventilation in process area to prevent formation of vapour. Personal protective
equipment should be selected based upon the conditions under which this product is handled or
used. Empty container retains product residue. Use and store away from all naked flames, heat
sources or working electrical appliances. Do not smoke.
Hygiene measures : Contaminated work clothing should not be allowed out of the workplace. Wash contaminated
clothing before reuse. Separate working clothes from town clothes. Launder separately. Do not
eat, drink or smoke when using this product. Discard contaminated leather articles. Wash hands
and other exposed areas with mild soap and water before eating, drinking or smoking and when
leaving work.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Provide adequate ventilation. A washing facility/water for eye and skin cleaning purposes should
be present.
Storage conditions : Keep out of reach of children. Keep container tightly closed. Keep only in the original container in
a cool, well-ventilated place away from highly flammable substances. Keep away from open
flames, hot surfaces and sources of ignition. Keep out of direct sunlight. Protect from moisture.
Containers that have been opened must be carefully resealed and kept upright to prevent
leakage.
Incompatible materials : Refer to Section 10 on Incompatible Materials.
Heat and ignition sources : Remove all sources of ignition.
Storage area : Store in dry, cool, well-ventilated area. Keep away from heat and direct sunlight.
7.3. Specific end use(s)
No additional information available
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Ethylene glycol (107-21-1)
USA ACGIH ACGIH Ceiling (mg/m³) 100 mg/m³
John Deere Cool-Gard™ II Premix
Safety Data Sheet
according to the federal final rule of hazard communication revised on 2012 (HazCom 2012)
08/02/2014 EN (English) SDS Ref.: 81Q2 4/10
Sodium tetraborate decahydrate (1303-96-4)
USA ACGIH ACGIH TWA (mg/m³) 2 mg/m³
USA ACGIH ACGIH STEL (mg/m³) 6 mg/m³
Sodium hydroxide (1310-73-2)
USA ACGIH ACGIH Ceiling (mg/m³) 2 mg/m³
USA OSHA OSHA PEL (TWA) (mg/m³) 2 mg/m³
8.2. Exposure controls
Appropriate engineering controls : A washing facility/water for eye and skin cleaning purposes should be present. Emergency eye
wash fountains and safety showers should be available in the immediate vicinity of any potential
exposure. Provide exhaust ventilation or other engineering controls to keep the airborne
concentrations of mists and/or vapors below the recommended exposure limits. Ensure
adequate ventilation.
Personal protective equipment : Avoid all unnecessary exposure. Personal protective equipment should be selected based upon
the conditions under which this product is handled or used. For certain operations, additional
Personal Protection Equipment (PPE) may be required. Gloves. Protective clothing. Protective
goggles.
Hand protection : Wear protective gloves. Nitrile-rubber protective gloves. For special purposes, it is recommended
to check the resistance to chemicals of the protective gloves mentioned above together with the
supplier of these gloves.
Eye protection : Chemical goggles or safety glasses. with side-shields. Eye protection, including both chemical
splash goggles and face shield, must be worn when possibility exists for eye contact due to
spraying liquid or airborne particles.
Skin and body protection : Chemical resistant suit. Wear rubber boots. Wear suitable protective clothing.
Respiratory protection : Where exposure through inhalation may occur from use, respiratory protection equipment is
recommended. Use a properly fitted, air-purifying or air-fed respirator if neceassary.
Other information : Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Appearance : Clear viscous liquid.
Colour : Gold.
odour : Odourless.
Odour threshold : 25 ppm
pH : 7.8 - 8.5
Relative evaporation rate (butyl acetate=1) : 0.01
Melting point : -13 °C (9 ºF)
Freezing point : No data available
Boiling point : 129 °C (264 ºF)
Flash point : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : < 0.008 kPa
Relative vapour density at 20 °C : 2.1
Relative density : 1.07 - 1.08 g/cm³
Solubility : Water: completely soluble
Log Pow : -1.07
Log Kow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : 21 mPa.s
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
John Deere Cool-Gard™ II Premix
Safety Data Sheet
according to the federal final rule of hazard communication revised on 2012 (HazCom 2012)
08/02/2014 EN (English) SDS Ref.: 81Q2 5/10
9.2. Other information
VOC content : 49.5
SECTION 10: Stability and reactivity
10.1. Reactivity
No additional information available
10.2. Chemical stability
Stable at normal conditions.
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
No additional information available
10.5. Incompatible materials
Oxidizing agents. Strong acids. strong bases. Contact with Aluminium, Zinc and Tin can cause formation of hydrogen that together with air can be
an combustible mixture.
10.6. Hazardous decomposition products
unburned hydrocarbons. Fume. Carbon monoxide. Carbon dioxide.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity : Harmful if swallowed.
John Deere Cool-Gard™ II Premix
ATE CLP (oral) 500.000 mg/kg bodyweight
Ethylene glycol (107-21-1)
LD50 oral rat 4000 mg/kg
LD50 dermal rabbit 9530 µl/kg
ATE CLP (oral) 500.000 mg/kg
Sodium tetraborate decahydrate (1303-96-4)
LD50 oral rat 2660 mg/kg
Sodium hydroxide (1310-73-2)
LD50 dermal rabbit 1350 mg/kg
ATE CLP (dermal) 1350.000 mg/kg bodyweight
Skin corrosion/irritation : Causes skin irritation.
pH: 7.8 - 8.5
Serious eye damage/irritation : Causes serious eye irritation.
pH: 7.8 - 8.5
Respiratory or skin sensitisation : Not classified (Based on available data, the classification criteria are not met)
Germ cell mutagenicity : Not classified (Based on available data, the classification criteria are not met)
Carcinogenicity : Not classified (Based on available data, the classification criteria are not met)
Reproductive toxicity : Not classified (Conclusive but not sufficient for classification)
Specific target organ toxicity (single exposure) : Not classified (Based on available data, the classification criteria are not met)
Specific target organ toxicity (repeated
exposure)
: May cause damage to organs (kidneys) through prolonged or repeated exposure (oral).
Aspiration hazard : Not classified (Based on available data, the classification criteria are not met)
Potential Adverse human health effects and
symptoms
: Based on available data, the classification criteria are not met.
Symptoms/injuries after inhalation : Long-term (repeated). Inhalation of mist or aerosol may cause irritation to nose and throat.
Symptoms/injuries after skin contact : Causes skin irritation.
Symptoms/injuries after eye contact : Causes serious eye irritation. Swelling and inflammation.
Symptoms/injuries after ingestion : May be harmful if swallowed. Ingestion may cause nausea and vomiting. Depression of the
central nervous system, headaches, dizziness, drowsiness, loss of coordination. In the case of
extreme exposure there is a risk of severe metabolic acidosis and haemorrhagy. Death in
extreme cases. Symptoms may be delayed.
SECTION 12: Ecological information
12.1. Toxicity
John Deere Cool-Gard™ II Premix
Safety Data Sheet
according to the federal final rule of hazard communication revised on 2012 (HazCom 2012)
08/02/2014 EN (English) SDS Ref.: 81Q2 6/10
Ethylene glycol (107-21-1)
LC50 fishes 1 41000 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss)
EC50 Daphnia 1 46300 mg/l (Exposure time: 48 h - Species: Daphnia magna)
LC50 fish 2 14 - 18 ml/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [static])
Sodium hydroxide (1310-73-2)
LC50 fishes 1 45.4 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [static])
12.2. Persistence and degradability
John Deere Cool-Gard™ II Premix
Persistence and degradability Not established.
12.3. Bioaccumulative potential
John Deere Cool-Gard™ II Premix
Log Pow -1.07
Bioaccumulative potential Not established.
Ethylene glycol (107-21-1)
Log Pow -1.93
12.4. Mobility in soil
No additional information available
12.5. Other adverse effects
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Waste disposal recommendations : Dispose of contents/container to comply with applicable local, national and international
regulations. Liquid product may not be disposed of with household waste or landfilled. Do not
allow to enter into drains/waters or in the soil. Do not re-use empty containers. Since emptied
containers retain product residue, follow label warnings even after container is emptied. Dispose
in a safe manner in accordance with local/national regulations. Dispose of at an licensed site.
Additional information : Do not pressurize, cut, weld, braze, solder, drill, grind, or expose containers to flames, sparks,
heat, or other potential ignition sources. Empty container retains product residue.
Ecology - waste materials : Prevent contamination of soil, drains and surface waters. Avoid release to the environment.
SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
Not applicable
14.2. UN proper shipping name
Not applicable
14.3. Additional information
Other information : RQ value – Refer to section 15.
Overland transport
No additional information available
Transport by sea
No additional information available
Air transport
No additional information available
SECTION 15: Regulatory information
15.1. US Federal regulations
John Deere Cool-Gard™ II Premix
RQ (Reportable quantity, section 304 of EPA's
List of Lists) :
10526 lb
Ethylene glycol (107-21-1)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Listed on United States SARA Section 313
John Deere Cool-Gard™ II Premix
Safety Data Sheet
according to the federal final rule of hazard communication revised on 2012 (HazCom 2012)
08/02/2014 EN (English) SDS Ref.: 81Q2 7/10
Ethylene glycol (107-21-1)
EPA TSCA Regulatory Flag Y2 - Y2 - indicates an exempt polymer that is a polyester and is made only from reactants
included in a specified list of low concern reactants that comprises one of the eligibility criteria
for the exemption rule.
RQ (Reportable quantity, section 304 of EPA's
List of Lists) :
5000 lb
SARA Section 313 - Emission Reporting 1.0 %
Sodium tetraborate decahydrate (1303-96-4)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Sodium hydroxide (1310-73-2)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
RQ (Reportable quantity, section 304 of EPA's
List of Lists) :
1000 lb
15.2. International regulations
CANADA
John Deere Cool-Gard™ II Premix
WHMIS Classification Class D Division 1 Subdivision B - Toxic material causing immediate and serious toxic effects
Class D Division 2 Subdivision A - Very toxic material causing other toxic effects
Class D Division 2 Subdivision B - Toxic material causing other toxic effects
Ethylene glycol (107-21-1)
Listed on the Canadian DSL (Domestic Sustances List)
WHMIS Classification Class D Division 1 Subdivision B - Toxic material causing immediate and serious toxic effects
Class D Division 2 Subdivision A - Very toxic material causing other toxic effects
Sodium tetraborate decahydrate (1303-96-4)
Listed on the Canadian DSL (Domestic Sustances List)
WHMIS Classification Class D Division 2 Subdivision B - Toxic material causing other toxic effects
Sodium hydroxide (1310-73-2)
Listed on the Canadian DSL (Domestic Sustances List)
WHMIS Classification Class E - Corrosive Material
EU-Regulations
Ethylene glycol (107-21-1)
Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)
Sodium hydroxide (1310-73-2)
Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)
Classification according to Regulation (EC) No. 1272/2008 [CLP]
No additional information available
Classification according to Directive 67/548/EEC or 1999/45/EC
No additional information available
15.2.2. National regulations
Ethylene glycol (107-21-1)
Listed on the AICS (Australian Inventory of Chemical Substances)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory
Listed on the Korean ECL (Existing Chemicals List)
Listed on NZIoC (New Zealand Inventory of Chemicals)
Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
Listed on the Canadian IDL (Ingredient Disclosure List)
John Deere Cool-Gard™ II Premix
Safety Data Sheet
according to the federal final rule of hazard communication revised on 2012 (HazCom 2012)
08/02/2014 EN (English) SDS Ref.: 81Q2 8/10
Sodium tetraborate decahydrate (1303-96-4)
Listed on the AICS (Australian Inventory of Chemical Substances)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory
Listed on the Korean ECL (Existing Chemicals List)
Listed on NZIoC (New Zealand Inventory of Chemicals)
Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
Japanese Pollutant Release and Transfer Register Law (PRTR Law)
Listed on the Canadian IDL (Ingredient Disclosure List)
Sodium hydroxide (1310-73-2)
Listed on the AICS (Australian Inventory of Chemical Substances)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory
Listed on the Korean ECL (Existing Chemicals List)
Listed on NZIoC (New Zealand Inventory of Chemicals)
Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
Japanese Poisonous and Deleterious Substances Control Law
Listed on the Canadian IDL (Ingredient Disclosure List)
15.3. US State regulations
Ethylene glycol (107-21-1)
U.S. - California - SCAQMD - Toxic Air Contaminants - Non-Cancer Chronic
U.S. - California - Toxic Air Contaminant List (AB 1807, AB 2728)
U.S. - Connecticut - Hazardous Air Pollutants - HLVs (30 min)
U.S. - Connecticut - Hazardous Air Pollutants - HLVs (8 hr)
U.S. - Delaware - Pollutant Discharge Requirements - Reportable Quantities
U.S. - Idaho - Non-Carcinogenic Toxic Air Pollutants - Acceptable Ambient Concentrations
U.S. - Idaho - Non-Carcinogenic Toxic Air Pollutants - Emission Levels (ELs)
U.S. - Illinois - Toxic Air Contaminants
U.S. - Louisiana - Reportable Quantity List for Pollutants
U.S. - Maine - Air Pollutants - Hazardous Air Pollutants
U.S. - Massachusetts - Allowable Ambient Limits (AALs)
U.S. - Massachusetts - Allowable Threshold Concentrations (ATCs)
U.S. - Massachusetts - Drinking Water Guidelines
U.S. - Massachusetts - Right To Know List
U.S. - Massachusetts - Threshold Effects Exposure Limits (TELs)
U.S. - Massachusetts - Toxics Use Reduction Act
U.S. - Michigan - Occupational Exposure Limits - Ceilings
U.S. - Michigan - Polluting Materials List
U.S. - Minnesota - Groundwater Health Risk Limits
U.S. - Minnesota - Hazardous Substance List
U.S. - Minnesota - Permissible Exposure Limits - Ceilings
U.S. - New Hampshire - Regulated Toxic Air Pollutants - Ambient Air Levels (AALs) - 24-Hour
U.S. - New Hampshire - Regulated Toxic Air Pollutants - Ambient Air Levels (AALs) - Annual
U.S. - New Jersey - Discharge Prevention - List of Hazardous Substances
U.S. - New Jersey - Environmental Hazardous Substances List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - New Jersey - Water Quality - Ground Water Quality Criteria
U.S. - New Jersey - Water Quality - Practical Quantitation Levels (PQLs)
U.S. - New York - Reporting of Releases Part 597 - List of Hazardous Substances
U.S. - North Dakota - Air Pollutants - Guideline Concentrations - 1-Hour
U.S. - Oregon - Permissible Exposure Limits - TWAs
U.S. - California - Safer Consumer Products - Initial List of Candidate Chemicals and Chemical Groups
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
U.S. - Pennsylvania - RTK (Right to Know) List
U.S. - Rhode Island - Air Toxics - Acceptable Ambient Levels - 1-Hour
U.S. - Rhode Island - Air Toxics - Acceptable Ambient Levels - Annual
U.S. - South Carolina - Toxic Air Pollutants - Maximum Allowable Concentrations
U.S. - South Carolina - Toxic Air Pollutants - Pollutant Categories
U.S. - Tennessee - Occupational Exposure Limits - Ceilings
U.S. - Texas - Effects Screening Levels - Long Term
U.S. - Texas - Effects Screening Levels - Short Term
U.S. - Vermont - Permissible Exposure Limits - Ceilings
U.S. - Washington - Permissible Exposure Limits - Ceilings
U.S. - Wisconsin - Hazardous Air Contaminants - All Sources - Emissions From Stack Heights 25 Feet to Less Than 40 Feet
U.S. - Wisconsin - Hazardous Air Contaminants - All Sources - Emissions From Stack Heights 40 Feet to Less Than 75 Feet
U.S. - Wisconsin - Hazardous Air Contaminants - All Sources - Emissions From Stack Heights 75 Feet or Greater
U.S. - Wisconsin - Hazardous Air Contaminants - All Sources - Emissions From Stack Heights Less Than 25 Feet
John Deere Cool-Gard™ II Premix
Safety Data Sheet
according to the federal final rule of hazard communication revised on 2012 (HazCom 2012)
08/02/2014 EN (English) SDS Ref.: 81Q2 9/10
Sodium tetraborate decahydrate (1303-96-4)
U.S. - Connecticut - Hazardous Air Pollutants - HLVs (30 min)
U.S. - Connecticut - Hazardous Air Pollutants - HLVs (8 hr)
U.S. - Idaho - Non-Carcinogenic Toxic Air Pollutants - Acceptable Ambient Concentrations
U.S. - Idaho - Non-Carcinogenic Toxic Air Pollutants - Emission Levels (ELs)
U.S. - Illinois - Toxic Air Contaminants
U.S. - Massachusetts - Right To Know List
U.S. - Michigan - Occupational Exposure Limits - TWAs
U.S. - Minnesota - Hazardous Substance List
U.S. - Minnesota - Permissible Exposure Limits - TWAs
U.S. - New Hampshire - Regulated Toxic Air Pollutants - Ambient Air Levels (AALs) - 24-Hour
U.S. - New Hampshire - Regulated Toxic Air Pollutants - Ambient Air Levels (AALs) - Annual
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) List
U.S. - Tennessee - Occupational Exposure Limits - TWAs
U.S. - Texas - Effects Screening Levels - Long Term
U.S. - Texas - Effects Screening Levels - Short Term
U.S. - Vermont - Permissible Exposure Limits - TWAs
U.S. - Washington - Permissible Exposure Limits - STELs
U.S. - Washington - Permissible Exposure Limits - TWAs
U.S. - Wisconsin - Hazardous Air Contaminants - All Sources - Emissions From Stack Heights 25 Feet to Less Than 40 Feet
U.S. - Wisconsin - Hazardous Air Contaminants - All Sources - Emissions From Stack Heights 40 Feet to Less Than 75 Feet
U.S. - Wisconsin - Hazardous Air Contaminants - All Sources - Emissions From Stack Heights 75 Feet or Greater
U.S. - Wisconsin - Hazardous Air Contaminants - All Sources - Emissions From Stack Heights Less Than 25 Feet
Sodium hydroxide (1310-73-2)
U.S. - California - SCAQMD - Toxic Air Contaminants - Non-Cancer Acute
U.S. - California - Toxic Air Contaminant List (AB 1807, AB 2728)
U.S. - Connecticut - Hazardous Air Pollutants - HLVs (30 min)
U.S. - Connecticut - Hazardous Air Pollutants - HLVs (8 hr)
U.S. - Delaware - Pollutant Discharge Requirements - Reportable Quantities
U.S. - Idaho - Non-Carcinogenic Toxic Air Pollutants - Acceptable Ambient Concentrations
U.S. - Idaho - Non-Carcinogenic Toxic Air Pollutants - Emission Levels (ELs)
U.S. - Idaho - Occupational Exposure Limits - TWAs
U.S. - Louisiana - Reportable Quantity List for Pollutants
U.S. - Massachusetts - Oil & Hazardous Material List - Groundwater Reportable Concentration - Reporting Category 1
U.S. - Massachusetts - Oil & Hazardous Material List - Groundwater Reportable Concentration - Reporting Category 2
U.S. - Massachusetts - Oil & Hazardous Material List - Reportable Quantity
U.S. - Massachusetts - Oil & Hazardous Material List - Soil Reportable Concentration - Reporting Category 1
U.S. - Massachusetts - Oil & Hazardous Material List - Soil Reportable Concentration - Reporting Category 2
U.S. - Massachusetts - Right To Know List
U.S. - Massachusetts - Toxics Use Reduction Act
U.S. - Michigan - Occupational Exposure Limits - Ceilings
U.S. - Michigan - Polluting Materials List
U.S. - Minnesota - Chemicals of High Concern
U.S. - Minnesota - Hazardous Substance List
U.S. - Minnesota - Permissible Exposure Limits - Ceilings
U.S. - New Jersey - Discharge Prevention - List of Hazardous Substances
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - New Jersey - Special Health Hazards Substances List
U.S. - New York - Occupational Exposure Limits - TWAs
U.S. - New York - Reporting of Releases Part 597 - List of Hazardous Substances
U.S. - North Dakota - Air Pollutants - Guideline Concentrations - 1-Hour
U.S. - Oregon - Permissible Exposure Limits - TWAs
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
U.S. - Pennsylvania - RTK (Right to Know) List
U.S. - Rhode Island - Air Toxics - Acceptable Ambient Levels - 1-Hour
U.S. - Rhode Island - Air Toxics - Acceptable Ambient Levels - Annual
U.S. - South Carolina - Toxic Air Pollutants - Maximum Allowable Concentrations
U.S. - South Carolina - Toxic Air Pollutants - Pollutant Categories
U.S. - Tennessee - Occupational Exposure Limits - Ceilings
U.S. - Texas - Effects Screening Levels - Long Term
U.S. - Texas - Effects Screening Levels - Short Term
U.S. - Vermont - Permissible Exposure Limits - Ceilings
U.S. - Washington - Permissible Exposure Limits - Ceilings
U.S. - Wisconsin - Hazardous Air Contaminants - All Sources - Emissions From Stack Heights 25 Feet to Less Than 40 Feet
U.S. - Wisconsin - Hazardous Air Contaminants - All Sources - Emissions From Stack Heights 40 Feet to Less Than 75 Feet
U.S. - Wisconsin - Hazardous Air Contaminants - All Sources - Emissions From Stack Heights 75 Feet or Greater
U.S. - Wisconsin - Hazardous Air Contaminants - All Sources - Emissions From Stack Heights Less Than 25 Feet
John Deere Cool-Gard™ II Premix
Safety Data Sheet
according to the federal final rule of hazard communication revised on 2012 (HazCom 2012)
08/02/2014 EN (English) SDS Ref.: 81Q2 10/10
SECTION 16: Other information
Other information : None.
Full text of H-phrases: see section 16:
------ Acute Tox. 4 (Dermal) Acute toxicity (dermal) Category 4
------ Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4
------ Eye Dam. 1 Serious eye damage/eye irritation, Category 1
------ Eye Irrit. 2A Serious eye damage/eye irritation, Category 2A
------ Repr. 1B Reproductive toxicity Category 1B
------ Skin Corr. 1A Skin corrosion/irritation Category 1A
------ Skin Irrit. 2 Skin corrosion/irritation Category 2
------ STOT RE 2 Specific target organ toxicity (repeated exposure) Category 2
------ H302 Harmful if swallowed
------ H312 Harmful in contact with skin
------ H314 Causes severe skin burns and eye damage
------ H315 Causes skin irritation
------ H318 Causes serious eye damage
------ H319 Causes serious eye irritation
------ H360 May damage fertility or the unborn child
------ H373 May cause damage to organs through prolonged or repeated
exposure
SDS US (GHS HazCom 2012)
The information presented herein has been compiled from sources considered to be dependable and is accurate to the best of Northland Products Company's knowledge; however, Northland
Products Company makes no warranty whatsoever, expressed or implied, of merchantability or fitness for the particular purpose, regarding the accuracy of such data or the results to be obtained
from the use thereof. Northland Products Company assumes no responsibility for the injury to the recipient or to third party persons or for any damage to any property and recipient assumes all such
risks