HomeMy WebLinkAboutCLAIRE-DISINFECTANT-SPRAY-Q
Version: 1.0
Revision Date: 06/11/2019
SDS_US - RE1000038701 1/19
SAFETY DATA SHEET
1. Identification
Product identifier: CLAIRE DISINFECTANT SPRAY Q
Other means of identification
SDS number: RE1000038701
Recommended restrictions
Product Use: Disinfectant
Restrictions on use: Not known.
Manufacturer/Importer/Distributor Information
Manufacturer
Company Name: CLAIRE MANUFACTURING COMPANY
Address: 1000 Integram Dr
Pacific, MO 63069
Telephone: 1-630-543-7600
Fax:
Emergency telephone number: 1-866-836-8855
2. Hazard(s) identification
Hazard Classification
Physical Hazards
Flammable aerosol Category 1
Health Hazards
Serious Eye Damage/Eye Irritation Category 2A
Skin sensitizer Category 1
Specific Target Organ Toxicity -
Repeated Exposure
Category 2
Hazard Symbol:
Signal Word: Danger
Label Elements
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Hazard Statement: Extremely flammable aerosol.
Causes serious eye irritation.
May cause an allergic skin reaction.
May cause damage to organs through prolonged or repeated exposure.
Precautionary
Statements
Prevention: Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking. Do not spray on an open flame or other ignition
source. Do not pierce or burn, even after use. Wash thoroughly after
handling. Wear protective gloves/protective clothing/eye protection/face
protection. Contaminated work clothing should not be allowed out of the
workplace. Do not breathe dust/fume/gas/mist/vapors/spray.
Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If eye irritation
persists: Get medical advice/attention. IF ON SKIN: Wash with plenty of
water/… If skin irritation or rash occurs: Get medical advice/attention. Get
medical advice/attention if you feel unwell. Specific treatment (see on this
label). Wash contaminated clothing before reuse.
Storage: Protect from sunlight. Do not expose to temperatures exceeding
50°C/122°F.
Disposal: Dispose of contents/container to an appropriate treatment and disposal
facility in accordance with applicable laws and regulations, and product
characteristics at time of disposal.
Hazard(s) not otherwise
classified (HNOC):
None.
3. Composition/information on ingredients
Mixtures
Chemical Identity CAS number Content in percent (%)*
Ethanol 64-17-5 10 - <20%
Ethanol, 2-(2-butoxyethoxy)- 112-34-5 10 - <20%
Propane 74-98-6 1 - <5%
Butane 106-97-8 1 - <5%
Glycine, N,N'-1,2-
ethanediylbis[N-
(carboxymethyl)-, sodium salt
(1:4)
64-02-8 1 - <3%
2-Propanol, 2-methyl- 75-65-0 0.1 - <1%
Quaternary ammonium
compounds, C12-14-
alkyl[(ethylphenyl)methyl]dimet
hyl, chlorides
85409-23-0 0.1 - <0.25%
2,6-Octadienal, 3,7-dimethyl- 5392-40-5 0.1 - <1%
Sodium hydroxide (Na(OH)) 1310-73-2 0.1 - <1%
Ethanol, 2-butoxy- 111-76-2 0 - <0.1%
Ammonium hydroxide
((NH4)(OH))
1336-21-6 0 - <0.1%
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.
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4. First-aid measures
Ingestion: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth.
Inhalation: Move to fresh air.
Skin Contact: If skin irritation occurs: Get medical advice/attention. Destroy or thoroughly
clean contaminated shoes. Immediately remove contaminated clothing and
shoes and wash skin with soap and plenty of water. If skin irritation or an
allergic skin reaction develops, get medical attention.
Eye contact: Immediately flush with plenty of water for at least 15 minutes. If easy to do,
remove contact lenses. Get medical attention.
Most important symptoms/effects, acute and delayed
Symptoms: No data available.
Hazards: No data available.
Indication of immediate medical attention and special treatment needed
Treatment: No data available.
5. Fire-fighting measures
General Fire Hazards: Use water spray to keep fire-exposed containers cool. Fight fire from a
protected location. Move containers from fire area if you can do so without
risk.
Suitable (and unsuitable) extinguishing media
Suitable extinguishing
media:
Use fire-extinguishing media appropriate for surrounding materials.
Unsuitable extinguishing
media:
Do not use water jet as an extinguisher, as this will spread the fire.
Specific hazards arising from
the chemical:
Vapors may travel considerable distance to a source of ignition and flash
back.
Special protective equipment and precautions for firefighters
Special fire fighting
procedures:
No data available.
Special protective equipment
for fire-fighters:
Firefighters must use standard protective equipment including flame
retardant coat, helmet with face shield, gloves, rubber boots, and in
enclosed spaces, SCBA.
6. Accidental release measures
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Personal precautions,
protective equipment and
emergency procedures:
Ventilate closed spaces before entering them. ELIMINATE all ignition
sources (no smoking, flares, sparks or flames in immediate area). Keep
upwind. See Section 8 of the SDS for Personal Protective Equipment. Do
not touch damaged containers or spilled material unless wearing
appropriate protective clothing. Keep unauthorized personnel away.
Methods and material for
containment and cleaning
up:
Absorb spill with vermiculite or other inert material, then place in a container
for chemical waste.
Notification Procedures: Prevent entry into waterways, sewer, basements or confined areas. Stop
the flow of material, if this is without risk. ELIMINATE all ignition sources
(no smoking, flares, sparks or flames in immediate area). Stop leak if you
can do so without risk.
Environmental Precautions: Do not contaminate water sources or sewer. Prevent further leakage or
spillage if safe to do so.
7. Handling and storage
Precautions for safe handling: Avoid contact with eyes. Wash hands thoroughly after handling. Keep away
from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking. Do not spray on an open flame or other ignition source. Do not
pierce or burn, even after use. Avoid contact with eyes, skin, and clothing.
Conditions for safe storage,
including any
incompatibilities:
Pressurized container: protect from sunlight and do not expose to
temperatures exceeding 50°C. Do not pierce or burn, even after use.
Aerosol Level 1
8. Exposure controls/personal protection
Control Parameters
Occupational Exposure Limits
Chemical Identity Type Exposure Limit Values Source
Ethanol TWA PEL 1,000 ppm 1,900 mg/m3 US. California Code of Regulations, Title 8,
Section 5155. Airborne Contaminants (09
2006)
REL 1,000 ppm 1,900 mg/m3 US. NIOSH: Pocket Guide to Chemical
Hazards (2005)
PEL 1,000 ppm 1,900 mg/m3 US. OSHA Table Z-1 Limits for Air
Contaminants (29 CFR 1910.1000) (02 2006)
TWA 1,000 ppm 1,900 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
TWA 1,000 ppm 1,900 mg/m3 US. Tennessee. OELs. Occupational Exposure
Limits, Table Z1A (06 2008)
STEL 1,000 ppm US. ACGIH Threshold Limit Values (2009)
AN ESL 1,880 µg/m3 US. Texas. Effects Screening Levels (Texas
Commission on Environmental Quality) (11
2016)
ST ESL 10,000 ppb US. Texas. Effects Screening Levels (Texas
Commission on Environmental Quality) (11
2016)
AN ESL 1,000 ppb US. Texas. Effects Screening Levels (Texas
Commission on Environmental Quality) (11
2016)
ST ESL 18,800
µg/m3
US. Texas. Effects Screening Levels (Texas
Commission on Environmental Quality) (11
2016)
Ethanol, 2-(2-butoxyethoxy)- ST ESL 670 µg/m3 US. Texas. Effects Screening Levels (Texas
Commission on Environmental Quality) (11
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2016)
ST ESL 100 ppb US. Texas. Effects Screening Levels (Texas
Commission on Environmental Quality) (11
2016)
AN ESL 10 ppb US. Texas. Effects Screening Levels (Texas
Commission on Environmental Quality) (11
2016)
AN ESL 67 µg/m3 US. Texas. Effects Screening Levels (Texas
Commission on Environmental Quality) (11
2016)
Ethanol, 2-(2-butoxyethoxy)-
- Inhalable fraction and
vapor.
TWA 10 ppm US. ACGIH Threshold Limit Values (03 2013)
Propane REL 1,000 ppm 1,800 mg/m3 US. NIOSH: Pocket Guide to Chemical
Hazards (2005)
PEL 1,000 ppm 1,800 mg/m3 US. OSHA Table Z-1 Limits for Air
Contaminants (29 CFR 1910.1000) (02 2006)
TWA PEL 1,000 ppm 1,800 mg/m3 US. California Code of Regulations, Title 8,
Section 5155. Airborne Contaminants (09
2006)
TWA 1,000 ppm 1,800 mg/m3 US. Tennessee. OELs. Occupational Exposure
Limits, Table Z1A (06 2008)
TWA 1,000 ppm 1,800 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
Butane REL 800 ppm 1,900 mg/m3 US. NIOSH: Pocket Guide to Chemical
Hazards (2005)
TWA 800 ppm 1,900 mg/m3 US. Tennessee. OELs. Occupational Exposure
Limits, Table Z1A (06 2008)
STEL 1,000 ppm US. ACGIH Threshold Limit Values (03 2018)
TWA 800 ppm 1,900 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
AN ESL 3,000 ppb US. Texas. Effects Screening Levels (Texas Commission on Environmental Quality) (11
2016)
AN ESL 7,100 µg/m3 US. Texas. Effects Screening Levels (Texas
Commission on Environmental Quality) (11
2016)
TWA PEL 800 ppm 1,900 mg/m3 US. California Code of Regulations, Title 8,
Section 5155. Airborne Contaminants (09
2006)
ST ESL 66,000
µg/m3
US. Texas. Effects Screening Levels (Texas
Commission on Environmental Quality) (11
2016)
ST ESL 28,000 ppb US. Texas. Effects Screening Levels (Texas
Commission on Environmental Quality) (11
2016)
2-Propanol, 2-methyl- TWA 100 ppm 300 mg/m3 US. Tennessee. OELs. Occupational Exposure
Limits, Table Z1A (06 2008)
STEL 150 ppm 450 mg/m3 US. Tennessee. OELs. Occupational Exposure
Limits, Table Z1A (06 2008)
ST ESL 200 ppb US. Texas. Effects Screening Levels (Texas
Commission on Environmental Quality) (11
2016)
AN ESL 20 ppb US. Texas. Effects Screening Levels (Texas
Commission on Environmental Quality) (11
2016)
AN ESL 62 µg/m3 US. Texas. Effects Screening Levels (Texas
Commission on Environmental Quality) (11
2016)
ST ESL 620 µg/m3 US. Texas. Effects Screening Levels (Texas
Commission on Environmental Quality) (11
2016)
STEL 150 ppm 450 mg/m3 US. NIOSH: Pocket Guide to Chemical
Hazards (2005)
TWA 100 ppm 300 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
PEL 100 ppm 300 mg/m3 US. OSHA Table Z-1 Limits for Air
Contaminants (29 CFR 1910.1000) (02 2006)
TWA 100 ppm US. ACGIH Threshold Limit Values (2008)
STEL 150 ppm 450 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
STEL 150 ppm 450 mg/m3 US. California Code of Regulations, Title 8,
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Section 5155. Airborne Contaminants (09
2006)
TWA PEL 100 ppm 300 mg/m3 US. California Code of Regulations, Title 8,
Section 5155. Airborne Contaminants (09
2006)
REL 100 ppm 300 mg/m3 US. NIOSH: Pocket Guide to Chemical
Hazards (2005)
2,6-Octadienal, 3,7-dimethyl-
- Inhalable fraction and
vapor.
TWA 5 ppm US. ACGIH Threshold Limit Values (01 2010)
2,6-Octadienal, 3,7-dimethyl- ST ESL 50 ppb US. Texas. Effects Screening Levels (Texas
Commission on Environmental Quality) (11
2016)
ST ESL 310 µg/m3 US. Texas. Effects Screening Levels (Texas
Commission on Environmental Quality) (11
2016)
AN ESL 31 µg/m3 US. Texas. Effects Screening Levels (Texas Commission on Environmental Quality) (11
2016)
AN ESL 5 ppb US. Texas. Effects Screening Levels (Texas
Commission on Environmental Quality) (11
2016)
Sodium hydroxide (Na(OH)) Ceiling 2 mg/m3 US. ACGIH Threshold Limit Values (2008)
Ceiling 2 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989)
Ceil_Time 2 mg/m3 US. NIOSH: Pocket Guide to Chemical
Hazards (2005)
PEL 2 mg/m3 US. OSHA Table Z-1 Limits for Air
Contaminants (29 CFR 1910.1000) (02 2006)
Ceiling 2 mg/m3 US. Tennessee. OELs. Occupational Exposure
Limits, Table Z1A (06 2008)
Ceiling 2 mg/m3 US. California Code of Regulations, Title 8,
Section 5155. Airborne Contaminants (09
2006)
Sodium hydroxide (Na(OH)) -
Particulate.
AN ESL 2 µg/m3 US. Texas. Effects Screening Levels (Texas
Commission on Environmental Quality) (11
2016)
ST ESL 20 µg/m3 US. Texas. Effects Screening Levels (Texas
Commission on Environmental Quality) (11 2016)
Ethanol, 2-butoxy- TWA 20 ppm US. ACGIH Threshold Limit Values (2008)
TWA 25 ppm 120 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
REL 5 ppm 24 mg/m3 US. NIOSH: Pocket Guide to Chemical
Hazards (2005)
PEL 50 ppm 240 mg/m3 US. OSHA Table Z-1 Limits for Air
Contaminants (29 CFR 1910.1000) (02 2006)
TWA PEL 20 ppm 97 mg/m3 US. California Code of Regulations, Title 8,
Section 5155. Airborne Contaminants (09
2006)
TWA 25 ppm 120 mg/m3 US. Tennessee. OELs. Occupational Exposure
Limits, Table Z1A (06 2008)
AN ESL 760 ppb US. Texas. Effects Screening Levels (Texas
Commission on Environmental Quality) (11
2016)
AN ESL 3,700 µg/m3 US. Texas. Effects Screening Levels (Texas
Commission on Environmental Quality) (11
2016)
ST ESL 2,900 µg/m3 US. Texas. Effects Screening Levels (Texas
Commission on Environmental Quality) (11
2016)
ST ESL 600 ppb US. Texas. Effects Screening Levels (Texas
Commission on Environmental Quality) (11
2016)
Ammonium hydroxide
((NH4)(OH))
AN ESL 92 µg/m3 US. Texas. Effects Screening Levels (Texas
Commission on Environmental Quality) (11
2016)
ST ESL 180 µg/m3 US. Texas. Effects Screening Levels (Texas
Commission on Environmental Quality) (11
2016)
STEL 35 ppm US. ACGIH Threshold Limit Values (2008)
TWA 25 ppm US. ACGIH Threshold Limit Values (2008)
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TWA PEL 25 ppm 18 mg/m3 US. California Code of Regulations, Title 8,
Section 5155. Airborne Contaminants (09 2006)
STEL 35 ppm 27 mg/m3 US. California Code of Regulations, Title 8,
Section 5155. Airborne Contaminants (09
2006)
STEL 35 ppm 27 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989)
STEL 35 ppm 27 mg/m3 US. NIOSH: Pocket Guide to Chemical
Hazards (2005)
REL 25 ppm 18 mg/m3 US. NIOSH: Pocket Guide to Chemical
Hazards (2005)
PEL 50 ppm 35 mg/m3 US. OSHA Table Z-1 Limits for Air
Contaminants (29 CFR 1910.1000) (02 2006)
Biological Limit Values
Chemical Identity Exposure Limit Values Source
Ethanol, 2-butoxy-
(Butoxyacetic acid (BAA),
with hydrolysis: Sampling
time: End of shift.)
200 mg/g (Creatinine in urine) ACGIH BEL (03 2013)
Appropriate Engineering
Controls
No data available.
Individual protection measures, such as personal protective equipment
General information: Provide easy access to water supply and eye wash facilities. Good general
ventilation (typically 10 air changes per hour) should be used. Ventilation
rates should be matched to conditions. If applicable, use process
enclosures, local exhaust ventilation, or other engineering controls to
maintain airborne levels below recommended exposure limits. If exposure
limits have not been established, maintain airborne levels to an acceptable
level. If exposure limits have not been established, maintain airborne levels
to an acceptable level.
Eye/face protection: Wear safety glasses with side shields (or goggles).
Skin Protection
Hand Protection: No data available.
Other: Wear chemical-resistant gloves, footwear, and protective clothing
appropriate for the risk of exposure. Contact health and safety professional
or manufacturer for specific information.
Respiratory Protection: In case of inadequate ventilation use suitable respirator. Seek advice from
local supervisor.
Hygiene measures: Avoid contact with eyes. Observe good industrial hygiene practices. When
using do not smoke. Contaminated work clothing should not be allowed out
of the workplace. Avoid contact with skin.
9. Physical and chemical properties
Appearance
Physical state: liquid
Form: Spray Aerosol
Color: No data available.
Odor: No data available.
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Odor threshold: No data available.
pH: No data available.
Melting point/freezing point: No data available.
Initial boiling point and boiling range: No data available.
Flash Point: -104.44 °C
Evaporation rate: No data available.
Flammability (solid, gas): No data available.
Upper/lower limit on flammability or explosive limits
Flammability limit - upper (%): No data available.
Flammability limit - lower (%): No data available.
Explosive limit - upper (%): No data available.
Explosive limit - lower (%): No data available.
Vapor pressure: 5,171.0680 - 6,550.0194 hPa (20 °C)
Vapor density: No data available.
Density: No data available.
Relative density: No data available.
Solubility(ies)
Solubility in water: No data available.
Solubility (other): No data available.
Partition coefficient (n-octanol/water): No data available.
Auto-ignition temperature: No data available.
Decomposition temperature: No data available.
Viscosity: No data available.
10. Stability and reactivity
Reactivity: No data available.
Chemical Stability: Material is stable under normal conditions.
Possibility of hazardous
reactions:
No data available.
Conditions to avoid: Avoid heat or contamination.
Incompatible Materials: No data available.
Hazardous Decomposition
Products:
No data available.
11. Toxicological information
Information on likely routes of exposure
Inhalation: No data available.
Skin Contact: No data available.
Eye contact: No data available.
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Ingestion: No data available.
Symptoms related to the physical, chemical and toxicological characteristics
Inhalation: No data available.
Skin Contact: No data available.
Eye contact: No data available.
Ingestion: No data available.
Information on toxicological effects
Acute toxicity (list all possible routes of exposure)
Oral
Product: ATEmix: 16,286.29 mg/kg
Dermal
Product: Not classified for acute toxicity based on available data.
Specified substance(s):
Ethanol LD 50 (Rabbit): 17,100 mg/kg
Ethanol, 2-(2-
butoxyethoxy)-
LD 50 (Rabbit): 2,764 mg/kg
Glycine, N,N'-1,2-
ethanediylbis[N-
(carboxymethyl)-, sodium
salt (1:4)
LD 50: > 2,000 mg/kg
2-Propanol, 2-methyl- LD 50: > 2,000 mg/kg
2,6-Octadienal, 3,7-
dimethyl-
LD 50 (Rat): > 2,000 mg/kg
Ethanol, 2-butoxy- LD 50 (Rabbit): 667 mg/kg
Inhalation
Product: Not classified for acute toxicity based on available data.
Specified substance(s):
Ethanol LC 50 (Rat): 124.7 mg/l
Ethanol, 2-(2-
butoxyethoxy)-
LC 50 (Various): > 20 mg/l
Propane LC 50 (Mouse): 1,237 mg/l
Butane LC 50 (Mouse): 1,237 mg/l
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Glycine, N,N'-1,2-
ethanediylbis[N-
(carboxymethyl)-, sodium
salt (1:4)
LOAEL (Rat): 30 mg/m3
2-Propanol, 2-methyl- LC 50: < 20 mg/l
Quaternary ammonium
compounds, C12-14-
alkyl[(ethylphenyl)methyl]
dimethyl, chlorides
LC 50: > 5 mg/l
LC 50: > 20 mg/l
Ethanol, 2-butoxy- LC 50: < 5 mg/l
LC 50: < 20 mg/l
Repeated dose toxicity
Product: No data available.
Specified substance(s):
Ethanol NOAEL (Rat(Male), Oral, 7 - 14 Weeks): 10 %(m) Oral Experimental result,
Key study
Ethanol, 2-(2-
butoxyethoxy)-
NOAEL (Rat(Female, Male), Oral, 90 d): 250 mg/kg Oral Experimental
result, Key study
NOAEL (Rat(Female, Male), Dermal, 13 Weeks): > 2,000 mg/kg Dermal
Experimental result, Key study
NOAEL (Rat(Female, Male), Inhalation, 90 - 120 d): 14 ppm(m) Inhalation
Experimental result, Key study
Propane NOAEL (Rat(Female, Male), Inhalation, >= 28 d): 4,000 ppm(m) Inhalation
Experimental result, Key study
LOAEL (Rat(Female, Male), Inhalation, >= 28 d): 12,000 ppm(m) Inhalation
Experimental result, Key study
Butane NOAEL (Rat(Female, Male), Inhalation, >= 28 d): 4,000 ppm(m) Inhalation
Experimental result, Key study
LOAEL (Rat(Female, Male), Inhalation, >= 28 d): 12,000 ppm(m) Inhalation
Experimental result, Key study
Glycine, N,N'-1,2-
ethanediylbis[N-
(carboxymethyl)-, sodium
salt (1:4)
NOAEL (Rat(Female, Male), Oral, 103 Weeks): >= 500 mg/kg Oral Read-
across from supporting substance (structural analogue or surrogate), Key
study
LOAEL (Rat(Male), Inhalation, 1 - 5 d): 30 mg/m3 Inhalation Read-across
from supporting substance (structural analogue or surrogate), Key study
2,6-Octadienal, 3,7-
dimethyl-
LOAEL (Rat(Female, Male), Oral, 104 - 105 Weeks): 210 mg/kg Oral
Experimental result, Key study
LOAEL (Rat(Female), Oral, 14 Weeks): 335 mg/kg Oral Experimental result,
Key study
Ethanol, 2-butoxy- NOAEL (Rabbit(Female, Male), Dermal, 90 d): > 150 mg/kg Dermal
Experimental result, Key study
NOAEL (Rat(Female), Oral, 90 d): < 82 mg/kg Oral Experimental result, Key
study
NOAEL (Rat(Female), Inhalation, 2 yr): < 31 ppm(m) Inhalation
Experimental result, Key study
Skin Corrosion/Irritation
Product: No data available.
Specified substance(s):
Ethanol in vivo (Rabbit): Not irritant Experimental result, Key study
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Ethanol, 2-(2-
butoxyethoxy)-
in vivo (Rabbit): Not irritant Experimental result, Supporting study
Glycine, N,N'-1,2-
ethanediylbis[N-
(carboxymethyl)-,
sodium salt (1:4)
in vivo (Rabbit): Not irritant Experimental result, Key study
Ethanol, 2-butoxy- in vivo (Rabbit): Irritating Experimental result, Key study
Serious Eye Damage/Eye Irritation
Product: No data available.
Specified substance(s):
Ethanol Rabbit, 1 - 24 hrs: Not irritating
Ethanol, 2-(2-
butoxyethoxy)-
Rabbit, 24 - 72 hrs: Highly irritating
Sodium hydroxide
(Na(OH))
Corrosive
Rabbit, 2 d: 10% Sodium Hydroxide- Category 1; 0.5% Sodium Hydroxide-
Slightly irritating to eyes
Ethanol, 2-butoxy- Rabbit, 24 - 72 hrs: Irritating
Respiratory or Skin Sensitization
Product: No data available.
Specified substance(s):
Ethanol Skin sensitization:, in vivo (Guinea pig): Non sensitising
Ethanol, 2-(2-
butoxyethoxy)-
Skin sensitization:, in vivo (Guinea pig): Non sensitising
Glycine, N,N'-1,2-
ethanediylbis[N-
(carboxymethyl)-,
sodium salt (1:4)
Skin sensitization:, in vivo (Guinea pig): Non sensitising
Ethanol, 2-butoxy- Skin sensitization:, in vivo (Guinea pig): Non sensitising
Carcinogenicity
Product: No data available.
IARC Monographs on the Evaluation of Carcinogenic Risks to Humans:
No carcinogenic components identified
US. National Toxicology Program (NTP) Report on Carcinogens:
No carcinogenic components identified
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050):
No carcinogenic components identified
Germ Cell Mutagenicity
In vitro
Product: No data available.
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In vivo
Product: No data available.
Reproductive toxicity
Product: No data available.
Specific Target Organ Toxicity - Single Exposure
Product: No data available.
Specified substance(s):
2-Propanol, 2-methyl- Inhalation - dust and mist: Respiratory tract irritation. - Category 3 with
respiratory tract irritation.
Specific Target Organ Toxicity - Repeated Exposure
Product: No data available.
Aspiration Hazard
Product: No data available.
Other effects: No data available.
12. Ecological information
Ecotoxicity:
Acute hazards to the aquatic environment:
Fish
Product: No data available.
Specified substance(s):
Ethanol LC 50 (Pimephales promelas, 96 h): 15.3 g/l Experimental result, Key study
Ethanol, 2-(2-
butoxyethoxy)-
LC 50 (Lepomis macrochirus, 96 h): 1,300 mg/l Experimental result, Key
study
LC 50 (Pimephales promelas, 96 h): 2,400 mg/l Experimental result,
Supporting study
Propane LC 50 (Various, 96 h): 147.54 mg/l QSAR QSAR, Key study
Butane LC 50 (Various, 96 h): 147.54 mg/l QSAR QSAR, Key study
Glycine, N,N'-1,2-
ethanediylbis[N-
(carboxymethyl)-, sodium
salt (1:4)
LC 50 (Lepomis macrochirus, 96 h): 121 mg/l Experimental result, Key study
NOAEL (Lepomis macrochirus, 96 h): 88 mg/l Experimental result, Key
study
2-Propanol, 2-methyl- LC 50 (Pimephales promelas, 96 h): > 961 mg/l Experimental result, Key
study
NOAEL (Pimephales promelas, 96 h): 961 mg/l Experimental result, Key
study
Quaternary ammonium
compounds, C12-14-
EC 50 (96 h): < 10 mg/l
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alkyl[(ethylphenyl)methyl]
dimethyl, chlorides
2,6-Octadienal, 3,7-
dimethyl-
LC 50 (Leuciscus idus, 96 h): 6.78 mg/l Experimental result, Key study
Sodium hydroxide
(Na(OH))
LC 50 (Western mosquitofish (Gambusia affinis), 96 h): 125 mg/l Mortality
LC 50 (Gambusia affinis, 96 h): < 180 mg/l Experimental result, Supporting
study
Ethanol, 2-butoxy- LC 50 (Oncorhynchus mykiss, 96 h): 1,474 mg/l Experimental result, Key
study
Ammonium hydroxide
((NH4)(OH))
LC 50 (Western mosquitofish (Gambusia affinis), 96 h): 15 mg/l Mortality
LC 50 (Fathead minnow (Pimephales promelas), 48 h): 7 mg/l Mortality
Aquatic Invertebrates
Product: No data available.
Specified substance(s):
Ethanol LC 50 (Ceriodaphnia dubia, 48 h): 5,012 mg/l Experimental result, Key study
Ethanol, 2-(2-
butoxyethoxy)-
LC 50 (Daphnia magna, 48 h): +/- 1,743 mg/l QSAR QSAR, Supporting
study
Butane LC 50 (Daphnia sp., 48 h): 69.43 mg/l QSAR QSAR, Key study
Glycine, N,N'-1,2-
ethanediylbis[N-
(carboxymethyl)-, sodium
salt (1:4)
EC 50 (Daphnia magna, 24 h): 610 mg/l Experimental result, Key study
2-Propanol, 2-methyl- NOAEL (Daphnia magna, 48 h): 180 mg/l Experimental result, Key study
EC 50 (Daphnia magna, 48 h): 933 mg/l Experimental result, Key study
Quaternary ammonium
compounds, C12-14-
alkyl[(ethylphenyl)methyl]
dimethyl, chlorides
EC 50 : 0.015 mg/l
2,6-Octadienal, 3,7-
dimethyl-
EC 50 (Daphnia magna, 48 h): 6.8 mg/l Experimental result, Key study
Sodium hydroxide
(Na(OH))
EC 50 (Water flea (Ceriodaphnia dubia), 48 h): 34.59 - 47.13 mg/l
Intoxication
Ethanol, 2-butoxy- EC 50 (Daphnia magna, 48 h): 1,550 mg/l Experimental result, Key study
Ammonium hydroxide
((NH4)(OH))
LC 50 (Water flea (Ceriodaphnia dubia), 48 h): > 0 - 10 mg/l Mortality
Chronic hazards to the aquatic environment:
Fish
Product: No data available.
Specified substance(s):
Ethanol NOAEL (Oryzias latipes): 7,900 mg/l Read-across from supporting
substance (structural analogue or surrogate), Supporting study
Version: 1.0
Revision Date: 06/11/2019
SDS_US - RE1000038701 14/19
Glycine, N,N'-1,2-
ethanediylbis[N-
(carboxymethyl)-, sodium
salt (1:4)
NOAEL (Danio rerio): >= 25.7 mg/l Read-across from supporting substance
(structural analogue or surrogate), Key study
2-Propanol, 2-methyl- NOAEL (Clarias gariepinus): 332 mg/l Experimental result, Key study
Quaternary ammonium
compounds, C12-14-
alkyl[(ethylphenyl)methyl]
dimethyl, chlorides
NOEC (28 d): 0.032 mg/l
Ethanol, 2-butoxy- NOAEL (Danio rerio): > 100 mg/l Experimental result, Key study
Aquatic Invertebrates
Product: No data available.
Specified substance(s):
Ethanol LC 50 (Daphnia magna): 454 mg/l Experimental result, Key study
NOAEL (Daphnia magna): 9.6 mg/l Experimental result, Key study
Glycine, N,N'-1,2-
ethanediylbis[N-
(carboxymethyl)-, sodium
salt (1:4)
NOAEL (Daphnia magna): 25 mg/l Read-across from supporting substance
(structural analogue or surrogate), Key study
Ethanol, 2-butoxy- EC 50 (Daphnia magna): 297 mg/l Experimental result, Key study
EC 10 (Daphnia magna): 134 mg/l Experimental result, Key study
Toxicity to Aquatic Plants
Product: No data available.
Persistence and Degradability
Biodegradation
Product: No data available.
Specified substance(s):
Ethanol 95 % Detected in water. Experimental result, Key study
Ethanol, 2-(2-
butoxyethoxy)-
85 % (28 d) Detected in water. Experimental result, Key study
Propane 100 % (385.5 h) Detected in water. Experimental result, Key study
50 % (3.19 d) Detected in water. QSAR, Weight of Evidence study
Butane 100 % (385.5 h) Detected in water. Experimental result, Key study
50 % (3.19 d) Detected in water. QSAR, Weight of Evidence study
Glycine, N,N'-1,2-
ethanediylbis[N-
(carboxymethyl)-, sodium
salt (1:4)
90 - 100 % (28 d) Detected in water. Read-across from supporting
substance (structural analogue or surrogate), Weight of Evidence study
2-Propanol, 2-methyl- 2.6 - 5.1 % (29 d) Detected in water. Experimental result, Key study
Version: 1.0
Revision Date: 06/11/2019
SDS_US - RE1000038701 15/19
2,6-Octadienal, 3,7-
dimethyl-
85 - 95 % (28 d) Detected in water. Experimental result, Key study
Ethanol, 2-butoxy- 90.4 % Detected in water. Experimental result, Key study
BOD/COD Ratio
Product: No data available.
Bioaccumulative potential
Bioconcentration Factor (BCF)
Product: No data available.
Specified substance(s):
Ethanol Cyprinus carpio, Bioconcentration Factor (BCF): 4.5 Aquatic sediment Read-
across from supporting substance (structural analogue or surrogate),
Supporting study
Glycine, N,N'-1,2-
ethanediylbis[N-
(carboxymethyl)-, sodium
salt (1:4)
Lepomis macrochirus, Bioconcentration Factor (BCF): 1.8 Aquatic sediment
Experimental result, Key study
2,6-Octadienal, 3,7-
dimethyl-
Bioconcentration Factor (BCF): 89.72 Aquatic sediment Estimated by
calculation, Key study
Partition Coefficient n-octanol / water (log Kow)
Product: No data available.
Mobility in soil: No data available.
Known or predicted distribution to environmental compartments
Ethanol No data available.
Ethanol, 2-(2-
butoxyethoxy)-
No data available.
Propane No data available.
Butane No data available.
Glycine, N,N'-1,2-
ethanediylbis[N-
(carboxymethyl)-, sodium
salt (1:4)
No data available.
2-Propanol, 2-methyl- No data available.
Quaternary ammonium
compounds, C12-14-
alkyl[(ethylphenyl)methyl]di
methyl, chlorides
No data available.
2,6-Octadienal, 3,7-
dimethyl-
No data available.
Sodium hydroxide (Na(OH)) No data available.
Ethanol, 2-butoxy- No data available.
Ammonium hydroxide
((NH4)(OH))
No data available.
Other adverse effects: No data available.
13. Disposal considerations
Version: 1.0
Revision Date: 06/11/2019
SDS_US - RE1000038701 16/19
Disposal instructions: Wash before disposal. Dispose to controlled facilities.
Contaminated Packaging: No data available.
14. Transport information
DOT
UN Number: UN 1950
UN Proper Shipping Name: Aerosols, flammable
Transport Hazard Class(es)
Class: 2.1
Label(s): –
Packing Group: II
Marine Pollutant: No
Environmental Hazards: No
Marine Pollutant No
Special precautions for user: Not regulated.
IMDG
UN Number: UN 1950
UN Proper Shipping Name: Aerosols, flammable
Transport Hazard Class(es)
Class: 2
Label(s): –
EmS No.:
Packing Group: –
Environmental Hazards: No
Marine Pollutant No
Special precautions for user: Not regulated.
IATA
UN Number: UN 1950
Proper Shipping Name: Aerosols, flammable
Transport Hazard Class(es):
Class: 2.1
Label(s): –
Packing Group: –
Environmental Hazards: No
Marine Pollutant No
Special precautions for user: Not regulated.
15. Regulatory information
US Federal Regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
None present or none present in regulated quantities.
CERCLA Hazardous Substance List (40 CFR 302.4):
Version: 1.0
Revision Date: 06/11/2019
SDS_US - RE1000038701 17/19
Chemical Identity Reportable quantity
Ethanol lbs. 100
Propane lbs. 100
Butane lbs. 100
2-Propanol, 2-methyl- lbs. 100
Sodium hydroxide
(Na(OH))
lbs. 1000
Ammonium hydroxide
((NH4)(OH))
lbs. 1000
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories
Fire Hazard
Immediate (Acute) Health Hazards
Delayed (Chronic) Health Hazard
Flammable aerosol
Serious Eye Damage/Eye Irritation
Skin sensitizer
Specific Target Organ Toxicity - Repeated Exposure
SARA 302 Extremely Hazardous Substance
None present or none present in regulated quantities.
SARA 304 Emergency Release Notification
Chemical Identity Reportable quantity
Ethanol lbs. 100
Ethanol, 2-(2-
butoxyethoxy)-
Propane lbs. 100
Butane lbs. 100
2-Propanol, 2-methyl- lbs. 100
Sodium hydroxide
(Na(OH))
lbs. 1000
Ethanol, 2-butoxy-
Ammonium hydroxide
((NH4)(OH))
lbs. 1000
SARA 311/312 Hazardous Chemical
Chemical Identity Threshold Planning Quantity
Ethanol 10000 lbs
Ethanol, 2-(2-butoxyethoxy)- 10000 lbs
Propane 10000 lbs
Butane 10000 lbs
Glycine, N,N'-1,2-ethanediylbis[N-
(carboxymethyl)-, sodium salt
(1:4)
10000 lbs
2-Propanol, 2-methyl- 10000 lbs
Quaternary ammonium
compounds, C12-14-
alkyl[(ethylphenyl)methyl]dimethyl,
chlorides
10000 lbs
2,6-Octadienal, 3,7-dimethyl- 10000 lbs
Sodium hydroxide (Na(OH)) 10000 lbs
Ethanol, 2-butoxy- 10000 lbs
Ammonium hydroxide
((NH4)(OH))
10000 lbs
SARA 313 (TRI Reporting)
Chemical Identity Reporting Reporting threshold for
Version: 1.0
Revision Date: 06/11/2019
SDS_US - RE1000038701 18/19
threshold for
other users
manufacturing and
processing
Ethanol, 2-(2-
butoxyethoxy)-
N230 lbs N230 lbs.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130):
Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3)
US State Regulations
US. California Proposition 65
No ingredient requiring a warning under CA Prop 65.
US. New Jersey Worker and Community Right-to-Know Act
Chemical Identity
Ethanol
Ethanol, 2-(2-butoxyethoxy)-
Propane
Butane
US. Massachusetts RTK - Substance List
Chemical Identity
Glycine, N,N-bis(carboxymethyl)-, sodium salt (1:3)
US. Pennsylvania RTK - Hazardous Substances
Chemical Identity
Ethanol
Ethanol, 2-(2-butoxyethoxy)-
Propane
Butane
US. Rhode Island RTK
No ingredient regulated by RI Right-to-Know Law present.
International regulations
Montreal protocol
Not applicable
Stockholm convention
Not applicable
Rotterdam convention
Not applicable
Kyoto protocol
Not applicable
Version: 1.0
Revision Date: 06/11/2019
SDS_US - RE1000038701 19/19
Inventory Status:Australia AICS: Not in compliance with the inventory.
Canada DSL Inventory List: Not in compliance with the inventory.
EINECS, ELINCS or NLP: Not in compliance with the inventory.
Japan (ENCS) List: Not in compliance with the inventory.
China Inv. Existing Chemical Substances: Not in compliance with the inventory.
Korea Existing Chemicals Inv. (KECI): Not in compliance with the inventory.
Canada NDSL Inventory: Not in compliance with the inventory.
Philippines PICCS: Not in compliance with the inventory.
US TSCA Inventory: Not in compliance with the inventory.
New Zealand Inventory of Chemicals: On or in compliance with the inventory
Japan ISHL Listing: Not in compliance with the inventory.
Japan Pharmacopoeia Listing: Not in compliance with the inventory.
Mexico INSQ: Not in compliance with the inventory.
Ontario Inventory: Not in compliance with the inventory.
Taiwan Chemical Substance Inventory: On or in compliance with the inventory
16.Other information, including date of preparation or last revision
Issue Date: 06/11/2019
Revision Information: No data available.
Version #: 1.0
Further Information: FIFRA: This chemical is a pesticide product registered by the United States
Environmental Protection Agency and is subject to certain labeling
requirements under federal pesticide law. These requirements differ from the
classification criteria and hazard information required for safety data sheets
(SDS), and for workplace labels of non-pesticide chemicals. The pesticide
label also includes other important information, including directions for use.
Disclaimer: This information is provided without warranty. The information is believed to
be correct. This information should be used to make an independent
determination of the methods to safeguard workers and the environment.