HomeMy WebLinkAboutBuckeye-Uppercut-5225CESafety Data Sheet Issue Date: 27-Dec-2011 Revision Date: 12-Oct-2018 Version 2 _____________________________________________________________________________________________ EN / HGHS Page 1 / 8 1. IDENTIFICATION Product identifier Product Name Buckeye Uppercut Other means of identification SDS # BE-5225-CA Product Code 5225 Synonyms None Recommended use of the chemical and restrictions on use Recommended Use Toilet Bowl Cleaner, Water Based Uses Advised Against No information available Details of the supplier of the safety data sheet United States Supplier Address Buckeye International, Inc. 2700 Wagner Place Maryland Heights, MO 63043 USA 1-314-291-1900 Initial Supplier Identifier 24 hr Emergency telephone numbers TRANSPORTATION - INFOTRAC 1-352-323-3500 (International) 1-800-535-5053 (North America) MEDICAL - 1-651-632-8956 (International) 1-800-303-0441 (North America) 2. HAZARDS IDENTIFICATION Appearance White opaque liquid Physical state Liquid Odour Wintergreen Classification Acute toxicity - Oral Category 4 Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 1 Signal word Danger BE-5225-CA - Buckeye Uppercut Revision Date: 12-Oct-2018 _____________________________________________________________________________________________ _____________________________________________________________________________________________ EN / HGHS Page 2 / 8 Hazard statements Harmful if swallowed Causes skin irritation Causes serious eye damage Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Wear protective gloves/protective clothing/eye protection/face protection Keep only in original container Precautionary Statements - Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a poison centre or doctor/physician IF ON SKIN: Wash with plenty of water and soap Take off all contaminated clothing and wash it before reuse If skin irritation occurs: Get medical advice/attention IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell Rinse mouth Absorb spillage to prevent material damage Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant 3. COMPOSITION/INFORMATION ON INGREDIENTS Mixture Chemical name CAS No Weight-% Hazardous Material Information Review Act registry number (HMIRA registry #) Date HMIRA filed and date exemption granted (if applicable) Urea Hydrochloride 506-89-8 30-60 - - *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures Eye contact Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison centre or doctor/physician. Skin contact Wash skin with soap and water. Take off contaminated clothing and wash it before reuse. Get medical attention if irritation occurs. Inhalation Remove to fresh air. Ingestion Rinse mouth. Do NOT induce vomiting. Give two glasses of water. Never give anything by mouth to an unconscious person. Immediately call a poison centre or doctor/physician. BE-5225-CA - Buckeye Uppercut Revision Date: 12-Oct-2018 _____________________________________________________________________________________________ _____________________________________________________________________________________________ EN / HGHS Page 3 / 8 Most important symptoms and effects, both acute and delayed Symptoms Causes skin irritation. Causes serious eye damage. Ingestion may cause nausea and headache. Indication of any immediate medical attention and special treatment needed Note to doctors Treat symptomatically. 5. FIREFIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media Not determined. Specific hazards arising from the chemical Combustion products may be toxic. Hazardous combustion products Carbon oxides. Nitrogen oxides (NOx). Explosion Data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Special protective equipment for fire-fighters Firefighters should wear self-contained breathing apparatus and full firefighting turnout gear. Use personal protection equipment. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Use personal protection recommended in Section 8. Environmental precautions Environmental precautions Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information. See Section 13: DISPOSAL CONSIDERATIONS. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Pick up with mop, wet/dry vac, or absorbent material. Rinse area with clear water and allow floor to dry before allowing traffic. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. BE-5225-CA - Buckeye Uppercut Revision Date: 12-Oct-2018 _____________________________________________________________________________________________ _____________________________________________________________________________________________ EN / HGHS Page 4 / 8 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Use personal protection recommended in Section 8. Avoid contact with skin, eyes or clothing. Wash face, hands and any exposed skin thoroughly after handling. Do not eat, drink or smoke when using this product. Keep containers closed when not in use. Conditions for safe storage, including any incompatibilities Storage Conditions Keep container tightly closed and store in a cool, dry and well-ventilated place. Store at room temperature. Incompatible materials Chlorine bleach Caustics Alkalis 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Limits No exposure limits noted for ingredient(s). The following information is given as general guidance. Appropriate engineering controls Engineering controls Ensure adequate ventilation, especially in confined areas. Eyewash stations. Showers. Individual protection measures, such as personal protective equipment Eye/face protection Use safety glasses or chemical splash goggles. Skin and body protection Wear rubber gloves or other impervious gloves. Respiratory protection No protection is ordinarily required under normal conditions of use and with adequate ventilation. General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid Appearance White opaque liquid Colour White opaque Odour Wintergreen Odour Threshold Not determined Property Values Remarks • Method pH <1.0 (conc.) 1.1 (1:4 dilution) Melting point / freezing point Not determined Boiling point / boiling range 100 °C / 212 °F Flash point None Tag Closed Cup Evaporation Rate 1.0 (n-BuAc =1) Flammability (Solid, Gas) Liquid-Not applicable BE-5225-CA - Buckeye Uppercut Revision Date: 12-Oct-2018 _____________________________________________________________________________________________ _____________________________________________________________________________________________ EN / HGHS Page 5 / 8 Flammability Limit in Air Upper flammability or explosive limits Not applicable Lower flammability or explosive limits Not applicable Vapour Pressure Not determined Vapour Density Not determined Relative Density 1.15 Water Solubility Mostly soluble Solubility in other solvents Not determined Partition Coefficient Not determined Autoignition temperature Not determined Decomposition temperature Not determined Kinematic Viscosity Not determined Dynamic Viscosity Not determined Explosive properties Not determined. Oxidising properties Not determined. Other information Softening Point Not determined Molecular weight Not determined VOC Content (%) Not determined Liquid Density Not determined Bulk density Not determined 10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions None under normal processing. Hazardous Polymerisation Hazardous polymerisation does not occur. Conditions to Avoid Keep separated from incompatible substances. Keep out of reach of children. Incompatible materials Chlorine bleach. Caustics. Alkalis. Hazardous decomposition products Carbon oxides. Nitrogen oxides (NOx). 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Eye contact Causes serious eye damage. Skin contact Causes skin irritation. Inhalation Avoid breathing vapours or mists. Ingestion Harmful if swallowed. Symptoms related to the physical, chemical and toxicological characteristics Symptoms Please see section 4 of this SDS for symptoms. BE-5225-CA - Buckeye Uppercut Revision Date: 12-Oct-2018 _____________________________________________________________________________________________ _____________________________________________________________________________________________ EN / HGHS Page 6 / 8 Acute toxicity Unknown acute toxicity No information available Component Information Chemical name Oral LD50 Dermal LD50 Inhalation LC50 Water 7732-18-5 > 90 mL/kg ( Rat ) - - Methyl salicylate 119-36-8 = 887 mg/kg ( Rat ) > 5000 mg/kg ( Rabbit ) - Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity Based on the information provided, this product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP. 12. ECOLOGICAL INFORMATION Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Chemical name Algae/aquatic plants Fish Toxicity to microorganisms Crustacea Methyl salicylate 119-36-8 - - - 50: 24 h Daphnia magna mg/L EC50 Persistence/Degradability No information available. Bioaccumulation No information available. Other Adverse Effects No information available. 13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Waste from residues/unused products Dispose of in accordance with local regulations. Dispose of waste in accordance with environmental legislation. Contaminated packaging Do not reuse empty containers. 14. TRANSPORT INFORMATION Note Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances DOT Not regulated if shipped in non-aluminum containers (49 CFR 173.154 (d)) BE-5225-CA - Buckeye Uppercut Revision Date: 12-Oct-2018 _____________________________________________________________________________________________ _____________________________________________________________________________________________ EN / HGHS Page 7 / 8 TDG UN/ID No UN1760 Proper Shipping Name Corrosive liquid, n.o.s. (contains Urea monohydrochloride) Hazard class 8 Packing Group III IATA UN number UN1760 Proper Shipping Name Corrosive liquid, n.o.s. (contains Urea monohydrochloride) Transport hazard class(es) 8 Packing Group III IMDG UN number UN1760 Proper Shipping Name Corrosive liquid, n.o.s. (contains Urea monohydrochloride) Transport hazard class(es) 8 Packing Group III 15. REGULATORY INFORMATION REGULATORY INFORMATION International Regulations Ozone-depleting substances (ODS) Not applicable The Stockholm Convention on Persistent Organic Pollutants Not applicable The Rotterdam Convention Not applicable International Inventories Chemical name TSCA DSL/NDSL EINECS/ELI NCS ENCS IECSC KECL PICCS AICS Urea Hydrochloride X X X X X X X Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances BE-5225-CA - Buckeye Uppercut Revision Date: 12-Oct-2018 _____________________________________________________________________________________________ _____________________________________________________________________________________________ EN / HGHS Page 8 / 8 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION NFPA Health Hazards 3 Flammability 0 Instability 0 Special Hazards Not determined HMIS Health Hazards Not determined Flammability Not determined Physical hazards Not determined Personal Protection Not determined Legend Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION TWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit) Ceiling Maximum limit value * Skin designation Issue Date: 27-Dec-2011 Revision Date: 12-Oct-2018 Revision Note: Regulatory update Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet