HomeMy WebLinkAboutBuckeye-Uppercut-5225CESafety Data Sheet
Issue Date: 27-Dec-2011
Revision Date: 12-Oct-2018 Version 2
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1. IDENTIFICATION
Product identifier
Product Name Buckeye Uppercut
Other means of identification
SDS # BE-5225-CA
Product Code 5225
Synonyms None
Recommended use of the chemical and restrictions on use
Recommended Use Toilet Bowl Cleaner, Water Based
Uses Advised Against No information available
Details of the supplier of the safety data sheet
United States Supplier Address
Buckeye International, Inc.
2700 Wagner Place
Maryland Heights, MO 63043 USA
1-314-291-1900
Initial Supplier Identifier
24 hr Emergency telephone
numbers TRANSPORTATION - INFOTRAC 1-352-323-3500 (International)
1-800-535-5053 (North America)
MEDICAL - 1-651-632-8956 (International) 1-800-303-0441 (North America)
2. HAZARDS IDENTIFICATION
Appearance White opaque liquid Physical state Liquid Odour Wintergreen
Classification
Acute toxicity - Oral Category 4
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 1
Signal word
Danger
BE-5225-CA - Buckeye Uppercut
Revision Date: 12-Oct-2018
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Hazard statements
Harmful if swallowed
Causes skin irritation
Causes serious eye damage
Precautionary Statements - Prevention
Wash face, hands and any exposed skin thoroughly after handling
Do not eat, drink or smoke when using this product
Wear protective gloves/protective clothing/eye protection/face protection
Keep only in original container
Precautionary Statements - Response
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
Immediately call a poison centre or doctor/physician
IF ON SKIN: Wash with plenty of water and soap
Take off all contaminated clothing and wash it before reuse
If skin irritation occurs: Get medical advice/attention
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
Rinse mouth
Absorb spillage to prevent material damage
Precautionary Statements - Disposal
Dispose of contents/container to an approved waste disposal plant
3. COMPOSITION/INFORMATION ON INGREDIENTS
Mixture
Chemical name CAS No Weight-% Hazardous Material
Information Review Act
registry number
(HMIRA registry #)
Date HMIRA filed and
date exemption
granted (if applicable)
Urea Hydrochloride 506-89-8 30-60 - -
*The exact percentage (concentration) of composition has been withheld as a trade secret.
4. FIRST AID MEASURES
Description of first aid measures
Eye contact Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. Immediately call a poison centre or doctor/physician.
Skin contact Wash skin with soap and water. Take off contaminated clothing and wash it before reuse.
Get medical attention if irritation occurs.
Inhalation Remove to fresh air.
Ingestion Rinse mouth. Do NOT induce vomiting. Give two glasses of water. Never give anything by
mouth to an unconscious person. Immediately call a poison centre or doctor/physician.
BE-5225-CA - Buckeye Uppercut
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Most important symptoms and effects, both acute and delayed
Symptoms Causes skin irritation. Causes serious eye damage. Ingestion may cause nausea and
headache.
Indication of any immediate medical attention and special treatment needed
Note to doctors Treat symptomatically.
5. FIREFIGHTING MEASURES
Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.
Unsuitable extinguishing media Not determined.
Specific hazards arising from the
chemical
Combustion products may be toxic.
Hazardous combustion products Carbon oxides. Nitrogen oxides (NOx).
Explosion Data
Sensitivity to Mechanical Impact None.
Sensitivity to Static Discharge None.
Special protective equipment for
fire-fighters
Firefighters should wear self-contained breathing apparatus and full firefighting turnout
gear. Use personal protection equipment.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions Use personal protection recommended in Section 8.
Environmental precautions
Environmental precautions Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See
Section 12, Ecological Information. See Section 13: DISPOSAL CONSIDERATIONS.
Methods and material for containment and cleaning up
Methods for containment Prevent further leakage or spillage if safe to do so.
Methods for cleaning up Pick up with mop, wet/dry vac, or absorbent material. Rinse area with clear water and allow
floor to dry before allowing traffic.
Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.
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7. HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Use personal
protection recommended in Section 8. Avoid contact with skin, eyes or clothing. Wash face,
hands and any exposed skin thoroughly after handling. Do not eat, drink or smoke when
using this product. Keep containers closed when not in use.
Conditions for safe storage, including any incompatibilities
Storage Conditions Keep container tightly closed and store in a cool, dry and well-ventilated place. Store at
room temperature.
Incompatible materials Chlorine bleach Caustics Alkalis
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Limits No exposure limits noted for ingredient(s). The following information is given as general
guidance.
Appropriate engineering controls
Engineering controls Ensure adequate ventilation, especially in confined areas. Eyewash stations. Showers.
Individual protection measures, such as personal protective equipment
Eye/face protection Use safety glasses or chemical splash goggles.
Skin and body protection Wear rubber gloves or other impervious gloves.
Respiratory protection No protection is ordinarily required under normal conditions of use and with adequate
ventilation.
General hygiene considerations Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical state Liquid
Appearance White opaque liquid
Colour White opaque
Odour Wintergreen
Odour Threshold Not determined
Property Values Remarks • Method pH <1.0 (conc.)
1.1 (1:4 dilution)
Melting point / freezing point Not determined Boiling point / boiling range 100 °C / 212 °F
Flash point None Tag Closed Cup Evaporation Rate 1.0 (n-BuAc =1) Flammability (Solid, Gas) Liquid-Not applicable
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Flammability Limit in Air
Upper flammability or explosive
limits
Not applicable
Lower flammability or explosive
limits
Not applicable
Vapour Pressure Not determined
Vapour Density Not determined
Relative Density 1.15 Water Solubility Mostly soluble
Solubility in other solvents Not determined Partition Coefficient Not determined Autoignition temperature Not determined
Decomposition temperature Not determined Kinematic Viscosity Not determined Dynamic Viscosity Not determined
Explosive properties Not determined.
Oxidising properties Not determined.
Other information
Softening Point Not determined
Molecular weight Not determined
VOC Content (%) Not determined
Liquid Density Not determined
Bulk density Not determined
10. STABILITY AND REACTIVITY
Reactivity Not reactive under normal conditions.
Chemical stability Stable under recommended storage conditions.
Possibility of hazardous reactions None under normal processing.
Hazardous Polymerisation Hazardous polymerisation does not occur.
Conditions to Avoid Keep separated from incompatible substances. Keep out of reach of children.
Incompatible materials Chlorine bleach. Caustics. Alkalis.
Hazardous decomposition products Carbon oxides. Nitrogen oxides (NOx).
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Product Information
Eye contact Causes serious eye damage.
Skin contact Causes skin irritation.
Inhalation Avoid breathing vapours or mists.
Ingestion Harmful if swallowed.
Symptoms related to the physical, chemical and toxicological characteristics
Symptoms Please see section 4 of this SDS for symptoms.
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Acute toxicity
Unknown acute toxicity No information available
Component Information
Chemical name Oral LD50 Dermal LD50 Inhalation LC50
Water
7732-18-5
> 90 mL/kg ( Rat ) - -
Methyl salicylate
119-36-8
= 887 mg/kg ( Rat ) > 5000 mg/kg ( Rabbit ) -
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Carcinogenicity Based on the information provided, this product does not contain any carcinogens or
potential carcinogens as listed by OSHA, IARC or NTP.
12. ECOLOGICAL INFORMATION
Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude
the possibility that large or frequent spills can have a harmful or damaging effect on the
environment.
Chemical name Algae/aquatic plants Fish Toxicity to
microorganisms
Crustacea
Methyl salicylate
119-36-8
- - - 50: 24 h Daphnia magna
mg/L EC50
Persistence/Degradability No information available.
Bioaccumulation No information available.
Other Adverse Effects No information available.
13. DISPOSAL CONSIDERATIONS
Waste Treatment Methods
Waste from residues/unused
products
Dispose of in accordance with local regulations. Dispose of waste in accordance with
environmental legislation.
Contaminated packaging Do not reuse empty containers.
14. TRANSPORT INFORMATION
Note Please see current shipping paper for most up to date shipping information, including
exemptions and special circumstances
DOT Not regulated if shipped in non-aluminum containers (49 CFR 173.154 (d))
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TDG
UN/ID No UN1760
Proper Shipping Name Corrosive liquid, n.o.s. (contains Urea monohydrochloride)
Hazard class 8
Packing Group III
IATA
UN number UN1760
Proper Shipping Name Corrosive liquid, n.o.s. (contains Urea monohydrochloride)
Transport hazard class(es) 8
Packing Group III
IMDG
UN number UN1760
Proper Shipping Name Corrosive liquid, n.o.s. (contains Urea monohydrochloride)
Transport hazard class(es) 8
Packing Group III
15. REGULATORY INFORMATION
REGULATORY INFORMATION
International Regulations
Ozone-depleting substances (ODS) Not applicable
The Stockholm Convention on
Persistent Organic Pollutants
Not applicable
The Rotterdam Convention Not applicable
International Inventories
Chemical name TSCA DSL/NDSL EINECS/ELI
NCS
ENCS IECSC KECL PICCS AICS
Urea Hydrochloride X X X X X X X
Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances
BE-5225-CA - Buckeye Uppercut
Revision Date: 12-Oct-2018
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16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION
NFPA Health Hazards 3 Flammability 0 Instability 0 Special Hazards Not
determined
HMIS
Health Hazards Not
determined
Flammability Not
determined
Physical hazards Not
determined
Personal Protection
Not determined
Legend Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
TWA TWA (time-weighted average)
STEL STEL (Short Term Exposure Limit)
Ceiling Maximum limit value
* Skin designation
Issue Date: 27-Dec-2011
Revision Date: 12-Oct-2018
Revision Note: Regulatory update
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
End of Safety Data Sheet