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HomeMy WebLinkAboutAmine-400-24-D-Weed-Killer-SDS-EPA-2217-2-9.10.2018SAFETY DATA SHEET AMINE 4 2,4-D WEED KILLER SDS REVISIONS: Section 14 DATE OF ISSUE: 09/10/2018 SUPERSEDES: 01/22/2018 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Acute toxicity - Oral Category 4 - (H302) Skin corrosion/irritation Category 1 Sub-category B - (H314) Serious eye damage/eye irritation Category 1 - (H318) Skin sensitization Category 1 - (H317) Carcinogenicity Category 2 - (H351) Specific target organ toxicity (single exposure)Category 3 - (H335) Label elements 1. PRODUCT AND COMPANY IDENTIFICATION Product identifier Product Name AMINE 4 2,4-D WEED KILLER Other means of identification Product Code PST-0019 UN/ID no 3082 Synonyms None Registration Number(s)34704-120 Recommended use of the chemical and restrictions on use Recommended Use Herbicide. Uses advised against No information available Details of the supplier of the safety data sheet Emergency telephone number Company Phone Number 1-888-LPI-CUST (574-2878) Emergency Telephone Chemtrec 1-800-424-9300 Medical Emergencies: 1-866-944-8565 US regulations require reporting spills of this material that could reach any surface waters. The toll-free phone number for the US Coast Guard National Response Center is 1-800-424-8802 Manufacturer Address LOVELAND PRODUCTS, INC. P.O. Box 1286 Greeley, CO 80632-1286 Signal word DANGER Hazard statements H302 - Harmful if swallowed H314 - Causes severe skin burns and eye damage H317 - May cause an allergic skin reaction Page 1 / 12 SAFETY DATA SHEET AMINE 4 2,4-D WEED KILLER SDS REVISIONS: Section 14 DATE OF ISSUE: 09/10/2018 SUPERSEDES: 01/22/2018 Precautionary Statements - Prevention P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P281 - Use personal protective equipment as required P264 - Wash face, hands and any exposed skin thoroughly after handling P270 - Do not eat, drink or smoke when using this product P260 - Do not breathe dust/fume/gas/mist/vapors/spray P272 - Contaminated work clothing should not be allowed out of the workplace P280 - Wear protective gloves P271 - Use only outdoors or in a well-ventilated area Precautionary Statements - Response P301 + P312 - IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell P303 + P361 + P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor/physician P312 - Call a POISON CENTER or doctor/physician if you feel unwell P330 - Rinse mouth P331 - Do NOT induce vomiting P333 + P313 - If skin irritation or rash occurs: Get medical advice/attention P363 - Wash contaminated clothing before reuse Precautionary Statements - Storage P405 - Store locked up P403 + P233 - Store in a well-ventilated place. Keep container tightly closed Precautionary Statements - Disposal P501 - Dispose of contents/ container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable H335 - May cause respiratory irritation H351 - Suspected of causing cancer Page 2 / 12 SAFETY DATA SHEET AMINE 4 2,4-D WEED KILLER SDS REVISIONS: Section 14 DATE OF ISSUE: 09/10/2018 SUPERSEDES: 01/22/2018 3. COMPOSITION/INFORMATION ON INGREDIENTS Mixture Chemical Name CAS No Weight-%GHS Classification Trade Secret 2,4-D 94-75-7 30 - 60 Acute Tox. 4 (H302) Eye Dam. 1 (H318) Skin Sens. 1 (H317) STOT SE 3 (H335) Aquatic Chronic 3 (H412) * DIMETHYLAMINE, ANHYDROUS 124-40-3 7 - 13 Acute Tox. 4 (H332) Skin Irrit. 2 (H315) Eye Dam. 1 (H318) STOT SE 3 (H335) Flam. Gas 1 (H220) Press. Gas * If CAS number is "proprietary", the specific chemical identity and percentage of composition has been withheld as a trade secret. OSHA Hazard Communication 29 CFR 1910.1200 4. FIRST AID MEASURES Description of first aid measures General advice Get medical attention if symptoms occur. Eye contact Hold eyelids apart and flush eyes with plenty of water for at least 15 minutes. Get medical attention. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. Skin contact Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice. Inhalation Remove to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferable by mouth-to-mouth, if possible. Call a poison control center or doctor for treatment advice. Ingestion Call a poison control center or doctor for treatment advice. Have person sip a glass of water if able to swallow. Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Self-protection of the first aider Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Most important symptoms and effects, both acute and delayed Symptoms No information available. Indication of any immediate medical attention and special treatment needed Treatment:Treat symptomatically. Symptoms may be delayed. Have the product container or label with you when calling a poison control center or doctor or going for treatment. You may also call 1-866-944-8565 for emergency medical treatment information. Note to physicians No specific antidote. Treat symptomatically. Antidotes No data available Page 3 / 12 SAFETY DATA SHEET AMINE 4 2,4-D WEED KILLER SDS REVISIONS: Section 14 DATE OF ISSUE: 09/10/2018 SUPERSEDES: 01/22/2018 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Use extinguishing agent suitable for type of surrounding fire, Use CO2, dry chemical, or foam Specific hazards arising from the chemical The product causes burns of eyes, skin and mucous membranes. Thermal decomposition can lead to release of irritating and toxic gases and vapors. In the event of fire and/or explosion do not breathe fumes. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters Self-contained breathing apparatus and full protective gear should be worn in fighting large fires involving chemicals. Use water spray to keep fire exposed containers cool. Keep people away. Isolate fire and deny unnecessary entry. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Environmental precautions Environmental precautions Do not allow into any sewer, on the ground or into any body of water. Should not be released into the environment. Do not flush into surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so. Prevent product from entering drains. Ver la Sección 12 para información ecológica adicional. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Take up mechanically, placing in appropriate containers for disposal. Dike far ahead of liquid spill for later disposal. Soak up with inert absorbent material. Clean contaminated surface thoroughly. Prevent product from entering drains. Dam up. After cleaning, flush away traces with water. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Ensure adequate ventilation, especially in confined areas. In case of insufficient ventilation, wear suitable respiratory equipment. Use only with adequate ventilation and in closed systems. Conditions for safe storage, including any incompatibilities Storage Conditions Keep container tightly closed in a dry and well-ventilated place. Keep out of the reach of children. Keep containers tightly closed in a cool, well-ventilated place. Keep containers tightly closed in a dry, cool and well-ventilated place. Keep in properly labeled containers. Incompatible materials Incompatible with strong acids and bases. Incompatible with oxidizing agents. Page 4 / 12 SAFETY DATA SHEET AMINE 4 2,4-D WEED KILLER SDS REVISIONS: Section 14 DATE OF ISSUE: 09/10/2018 SUPERSEDES: 01/22/2018 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems. Individual protection measures, such as personal protective equipment Eye/face protection Tight sealing safety goggles. Face protection shield. Skin and body protection Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Respiratory protection Dependent on job function. If vapors or dusts exceed acceptable levels, wear a MSHA/NIOSH approved air-purifying respirator with any cartridges/filters approved for pesticides. If respirators are used, a program should be in place to assure compliance with 29 CFR 1910.134, the OSHA Respiratory Protection Standard. Wear a supplied air respirator if exposure concentrations are unknown. General Hygiene Considerations When using do not eat, drink or smoke. Wash contaminated clothing before reuse. Keep away from food, drink and animal feeding stuffs. Contaminated work clothing should not be allowed out of the workplace. Regular cleaning of equipment, work area and clothing is recommended. Avoid contact with skin, eyes or clothing. Take off all contaminated clothing and wash it before reuse. Wear suitable gloves and eye/face protection. Page 5 / 12 SAFETY DATA SHEET AMINE 4 2,4-D WEED KILLER SDS REVISIONS: Section 14 DATE OF ISSUE: 09/10/2018 SUPERSEDES: 01/22/2018 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid Appearance Clear liquid Color Amber or Black Odor Fishy Amine Odor threshold No data available Other Information VOC Content (%)No data available Note: These physical data are typical values based on material tested but may vary from sample to sample. Typical values should not be construed as a guaranteed analysis of any specific lot or as specification items. Property Values (Remarks - Method) pH 6.6 (NEAT) Melting point / freezing point No data available No data available Boiling point No data available No data available Flash point Does not flash Evaporation rate No data available Flammability (solid, gas)No data available Not applicable Flammability Limit in Air Upper flammability limit:No data available Lower flammability limit:No data available Vapor pressure 0.0041 mmHg Vapor density No data available Specific Gravity 1.158 g/ml Water solubility Miscible in water Miscible Solubility in other solvents No data available Partition coefficient No data available No data available Autoignition temperature No data available No data available Decomposition temperature No data available No data available Kinematic viscosity No data available Dynamic viscosity No data available Explosive properties No data available Oxidizing properties No data available Density 9.66 Page 6 / 12 lbs/gal SAFETY DATA SHEET AMINE 4 2,4-D WEED KILLER SDS REVISIONS: Section 14 DATE OF ISSUE: 09/10/2018 SUPERSEDES: 01/22/2018 10. STABILITY AND REACTIVITY Reactivity Chemical stabilityStable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Exposure to air or moisture over prolonged periods. Incompatible materials Incompatible with strong acids and bases. Incompatible with oxidizing agents. Hazardous Decomposition Products Thermal decomposition can lead to release of irritating and toxic gases and vapors. Page 7 / 12 No data available SAFETY DATA SHEET AMINE 4 2,4-D WEED KILLER SDS REVISIONS: Section 14 DATE OF ISSUE: 09/10/2018 SUPERSEDES: 01/22/2018 11. TOXICOLOGICAL INFORMATION Acute toxicity of the formulated product: Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 2,4-D = 420 mg/kg ( Rat ) = 375 mg/kg (Rat )= 1500 mg/kg ( Rat ) DIMETHYLAMINE, ANHYDROUS = 698 mg/kg ( Rat )= 3900 mg/kg ( Rat )= 4540 ppm ( Rat ) 6 h Chemical Name Skin corrosion/irritation Eye damage/irritation Respiratory sensitization Skin sensitization 2,4-D 94-75-7 Category 1 Category 1 DIMETHYLAMINE, ANHYDROUS 124-40-3 Category 2 Category 1 Category 1 Delayed and immediate effects as well as chronic effects from short and long-term exposure Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA 2,4-D 94-75-7 -Group 2B -X IARC (International Agency for Research on Cancer) Group 2B - Possibly Carcinogenic to Humans OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Reproductive toxicity No information available. STOT - single exposure No information available. STOT - repeated exposure No information available. Chronic toxicity Chronic exposure to corrosive fumes/gases may cause erosion of the teeth followed by jaw necrosis. Bronchial irritation with chronic cough and frequent attacks of pneumonia are common. Gastrointestinal disturbances may also be seen. Avoid repeated exposure. Possible risk of irreversible effects. May cause adverse liver effects. Target Organ Effects Central nervous system, Eye damage/irritation, kidney, liver, Respiratory system, Skin. Aspiration hazard No information available. Information on likely routes of exposure Product Information No data available Inhalation No data available. Eye contact No data available. Skin contact No data available. Ingestion No data available. Page 8 / 12 SAFETY DATA SHEET AMINE 4 2,4-D WEED KILLER SDS REVISIONS: Section 14 DATE OF ISSUE: 09/10/2018 SUPERSEDES: 01/22/2018 12. ECOLOGICAL INFORMATION Ecotoxicity Chemical Name Algae/aquatic plants Fish Crustacea 2,4-D 94-75-7 EC50 23.7 - 24.7 mg/L 96 h Pseudokirchneriella subcapitata EC50 20 - 52 mg/L 120 h Pseudokirchneriella subcapitata LC50 20 mg/L 96 h Cyprinus carpio LC50 127.9 - 141.7 mg/L 96 h Cyprinus carpio LC50 180 mg/L 96 h Lepomis macrochirus LC50 77 -157 mg/L 96 h Oncorhynchus mykiss LC50 2450 - 3160 mg/L 96 h Oryzias latipes LC50 103 - 171 mg/L 96 h Pimephales promelas LC50 165 mg/L 96 h Pimephalespromelas LC50 70.7 mg/L 96 h Poecilia reticulata LC50 6.3 - 11.0 mg/L 96 h Poecilia reticulata EC50 17.6 - 32.6 mg/L 48 h Daphnia magna EC50 417.8 mg/L 72 h Daphnia magna DIMETHYLAMINE, ANHYDROUS 124-40-3 EC50 9 mg/L 96 h Pseudokirchneriella subcapitata LC50 111 - 125 mg/L 96 h Oncorhynchus mykiss LC50 120 mg/L 96 h Oncorhynchus mykiss LC50 210 mg/L 96 h Poecilia reticulata LC50 127 - 349 mg/L 96 h Poecilia reticulata LC50 396 mg/L 96 h Brachydanio rerio EC50 88.7 mg/L 48 h Daphnia magna Straus Persistence and degradability No information available. Bioaccumulation No information available. Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes Wastes may be disposed of on site or at an approved waste disposal facility. Triple rinse (or equivalent), adding rinse water to spray tank. Offer container for recycling or dispose of in a sanitary landfill or by other procedures approved by appropriate authorities. Recycling decontaminated containers is the best option of container disposal. The Agricultural Container Recycling Council (ACRC) operates the national recycling program. To contact your state and local ACRC recycler visit the ACRC web page at http://www.acrecycle.org/. Do not contaminate water, food or feed by storage or disposal. Contaminated packaging Do not reuse container. Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes 2,4-D 94-75-7 U240 Included in waste stream: F039 10.0 mg/L regulatory level U240 DIMETHYLAMINE, ANHYDROUS 124-40-3 ---U092 Chemical Name RCRA - Halogenated Organic Compounds RCRA - P Series Wastes RCRA - F Series Wastes RCRA - K Series Wastes 2,4-D 94-75-7 Category IV - Phenoxyacetic Acid Herbicides --- Page 9 / 12 SAFETY DATA SHEET AMINE 4 2,4-D WEED KILLER SDS REVISIONS: Section 14 DATE OF ISSUE: 09/10/2018 SUPERSEDES: 01/22/2018 14. TRANSPORT INFORMATION Note:LESS THAN 27 GALLONS: NOT REGULATED DOT UN/ID no 3082 Proper shipping name GREATER THAN 27 GALLONS: RQ UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE LIQUID, N.O.S., 9, III (2,4-D) ERG GUIDE 171 U.S. Surface Freight Classification:COMPOUND, TREE OR WEED KILLING, NOI (NMFC 50320, SUB 2: CLASS: 60) Hazard Class 9 Packing Group III Reportable Quantity (RQ)100 Page 10 / 12 SAFETY DATA SHEET AMINE 4 2,4-D WEED KILLER SDS REVISIONS: Section 14 DATE OF ISSUE: 09/10/2018 SUPERSEDES: 01/22/2018 15. REGULATORY INFORMATION US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name SARA 313 - Threshold Values % 2,4-D - 94-75-7 0.1 DIMETHYLAMINE, ANHYDROUS - 124-40-3 1.0 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard Yes Fire hazard No Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) Chemical Name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances 2,4-D 94-75-7 100 lb --X DIMETHYLAMINE, ANHYDROUS 124-40-3 1000 lb --X CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) 2,4-D 94-75-7 100 lb -RQ 100 lb final RQ RQ 45.4 kg final RQ DIMETHYLAMINE, ANHYDROUS 124-40-3 1000 lb -RQ 1000 lb final RQ RQ 454 kg final RQ US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals US EPA Waste Number U092 U240 U.S. EPA Label Information EPA Registration Number 34704-120 EPA Statement This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: DANGER NFPA Health hazards 3 Flammability 0 Instability 0 Physical and Chemical Properties - HMIS Health hazards 3 Flammability 0 Physical hazards 0 Personal protection X 0 - Least 1 - Slight 2 - Moderate 3 - High 4 - Severe Page 11 / 12 SAFETY DATA SHEET AMINE 4 2,4-D WEED KILLER SDS REVISIONS: Section 14 DATE OF ISSUE: 09/10/2018 SUPERSEDES: 01/22/2018 Difference between SDS and EPA Pesticide label Corrosive. Causes irreversible eye damage. Harmful if swallowed. Do not get in eyes or on clothing. 16. OTHER INFORMATION Issue Date 09/10/2018 Revision Date 09/10/2018 Revision Note 1 SDS sections updated AMINE 4 2,4-D WEED KILLER is a trademark of Loveland Products, Inc. Disclaimer This safety data sheet was developed from information on the constituent materials identified herein and does not relate to the use of such materials in combination with any other material or process. No warranty is expressed or implied with respect to the completeness or ongoing accuracy of the information contained in this data sheet, and LOVELAND PRODUCTS, INC. disclaims all liability for reliance on such information. This data sheet is not a guarantee of safety. Users are responsible for ensuring that they have all current information necessary to safely use the product described by this data sheet for their specific purpose. End of Safety Data Sheet Prepared By Product Stewardship and Regulatory Affairs Reviewed By Safety, Health and Environment Page 12 / 12