HomeMy WebLinkAbout05177-SSS-Cinna-Mist-Dry-Air-FreshenerSAFETY DATA SHEET
SSS® CINNA-MIST AIR FRESHENER (#05177)
Version 1.0 Revision Date 05/20/2015 Print Date 05/31/2015
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SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Material name
: SSS® Cinna-Mist Dry Air Freshener
Material number : A00238CF
Manufacturer or supplier's details
Company : Triple S
Address : 2 Executive Park Drive
Billerica, MA 01862
Telephone : 978-667-7900
Emergency telephone numbers
For SDS Information : 978-667-7900
For a Medical Emergency : 1-888-779-1339
For a Transportation
Emergency
: 1-888-779-1339
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview
Appearance Aerosol containing a liquefied gas
Colour colourless
Odour odourized
GHS Classification
Flammable aerosols : Category 1
Gases under pressure : Liquefied gas
Eye irritation : Category 2A
Skin sensitisation : Category 1
Specific target organ toxicity -
single exposure
: Category 3 (Central nervous system)
GHS Label element
Hazard pictograms :
Signal word : Danger
Hazard statements : H222 Extremely flammable aerosol.
H280 Contains gas under pressure; may explode if heated.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
Precautionary statements : Prevention:
P210 Keep away from heat, hot surfaces, sparks, open flames
and other ignition sources. No smoking.
P211 Do not spray on an open flame or other ignition source.
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P251 Pressurized container: Do not pierce or burn, even after
use.
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of
the workplace.
P280 Wear eye protection/ face protection.
P280 Wear protective gloves.
Response:
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 + P312 IF INHALED: Remove victim to fresh air
and keep at rest in a position comfortable for breathing. Call a
POISON CENTER or doctor/ physician if you feel unwell.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P333 + P313 If skin irritation or rash occurs: Get medical
advice/ attention.
P337 + P313 If eye irritation persists: Get medical advice/
attention.
P363 Wash contaminated clothing before reuse.
Storage:
P403 + P233 Store in a well-ventilated place. Keep container
tightly closed.
P405 Store locked up.
P410 + P412 Protect from sunlight. Do not expose to
temperatures exceeding 50 °C/ 122 °F.
Disposal:
P501 Dispose of contents/container in accordance with local
regulation.
Potential Health Effects
Carcinogenicity:
IARC No component of this product present at levels greater than or
equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.
ACGIH No component of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential
carcinogen by ACGIH.
OSHA No component of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential
carcinogen by OSHA.
NTP No component of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture : Mixture
Hazardous components
Chemical Name CAS-No. Concentration [%]
acetone 67-64-1 >= 70 - < 90
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propane 74-98-6 >= 10 - < 20
butane 106-97-8 >= 5 - < 10
eugenol 97-53-0 >= 0.1 - < 1
SECTION 4. FIRST AID MEASURES
General advice : Show this safety data sheet to the doctor in attendance.
If inhaled : Remove to fresh air.
Call a physician or poison control centre immediately.
In case of skin contact : If skin irritation persists, call a physician.
Wash off immediately with plenty of water for at least 15
minutes.
In case of eye contact : Flush eyes with water at least 15 minutes. Get medical
attention if eye irritation develops or persists.
If swallowed : Do NOT induce vomiting.
Drink 1 or 2 glasses of water.
Obtain medical attention.
SECTION 5. FIREFIGHTING MEASURES
Suitable extinguishing media : Foam
Carbon dioxide (CO2)
Dry chemical
Water
Unsuitable extinguishing
media
: High volume water jet
Specific hazards during
firefighting
: Do not allow run-off from fire fighting to enter drains or water
courses.
Hazardous combustion
products
: Carbon dioxide (CO2)
Carbon monoxide
Smoke
Specific extinguishing
methods
: Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Further information : For safety reasons in case of fire, cans should be stored
separately in closed containments.
Use a water spray to cool fully closed containers.
Special protective equipment
for firefighters
: Wear self-contained breathing apparatus for firefighting if
necessary.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions,
protective equipment and
emergency procedures
: Use personal protective equipment.
Ensure adequate ventilation.
Remove all sources of ignition.
Evacuate personnel to safe areas.
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Beware of vapours accumulating to form explosive
concentrations. Vapours can accumulate in low areas.
Environmental precautions : Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.
Methods and materials for
containment and cleaning up
: Soak up with inert absorbent material (e.g. sand, silica gel,
acid binder, universal binder, sawdust).
Sweep up and shovel into suitable containers for disposal.
SECTION 7. HANDLING AND STORAGE
Advice on safe handling : Do not breathe vapours/dust.
Do not puncture.
Keep away from fire (No Smoking).
Avoid contact with skin and eyes.
Use only with adequate ventilation.
Conditions for safe storage : BEWARE: Aerosol is pressurized. Keep away from direct sun
exposure and temperatures over 50 °C. Do not open by force
or throw into fire even after use. Do not spray on flames or
red-hot objects.
No smoking.
Observe label precautions.
Electrical installations / working materials must comply with
the technological safety standards.
Materials to avoid : Keep away from oxidising agents, strongly acid or alkaline
materials and amines.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
Components CAS-No. Value type
(Form of
exposure)
Control
parameters /
Permissible
concentration
Basis
acetone 67-64-1 TWA 500 ppm ACGIH
STEL 750 ppm ACGIH
TWA 250 ppm
590 mg/m3
NIOSH REL
TWA 1,000 ppm
2,400 mg/m3
OSHA Z-1
TWA 750 ppm
1,800 mg/m3
OSHA P0
STEL 1,000 ppm
2,400 mg/m3
OSHA P0
propane 74-98-6 TWA 1,000 ppm ACGIH
TWA 1,000 ppm
1,800 mg/m3
NIOSH REL
TWA 1,000 ppm
1,800 mg/m3
OSHA Z-1
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TWA 1,000 ppm
1,800 mg/m3
OSHA P0
butane 106-97-8 TWA 800 ppm
1,900 mg/m3
NIOSH REL
TWA 800 ppm
1,900 mg/m3
OSHA P0
Biological occupational exposure limits
Component CAS-No. Control
parameters
Biological
specimen
Sampling
time
Permissible
concentration
Basis
2-PROPANONE 67-64-1 Acetone Urine End of
shift (As
soon as
possible
after
exposure
ceases)
50 mg/l ACGIH BEI
Personal protective equipment
Respiratory protection : In case of insufficient ventilation, wear suitable respiratory
equipment.
Hand protection
Remarks : The suitability for a specific workplace should be discussed
with the producers of the protective gloves.
Eye protection : Safety glasses
Ensure that eyewash stations and safety showers are close to
the workstation location.
Skin and body protection : impervious clothing
Choose body protection according to the amount and
concentration of the dangerous substance at the work place.
Hygiene measures : When using do not eat or drink.
When using do not smoke.
Wash hands before breaks and at the end of workday.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : Aerosol containing a liquefied gas
Colour : colourless
Odour : odourized
Odour Threshold : no data available
pH : not applicable
Melting point/freezing point : no data available
Boiling point : not applicable
Flash point :
not applicable
Evaporation rate : not determined
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Flammability (solid, gas) : Extremely flammable aerosol.
Upper explosion limit : no data available
Lower explosion limit : no data available
Vapour pressure : no data available
Relative vapour density : no data available
Density : < 1 g/cm3
Solubility(ies)
Water solubility : soluble
Solubility in other solvents : not determined
Partition coefficient: n-
octanol/water
: no data available
Auto-ignition temperature : not determined
Thermal decomposition : no data available
Viscosity
Viscosity, kinematic : no data available
SECTION 10. STABILITY AND REACTIVITY
Reactivity : Stable
Chemical stability : Stable under normal conditions.
Possibility of hazardous
reactions
: Vapours may form explosive mixture with air.
No decomposition if stored and applied as directed.
Conditions to avoid : Heat, flames and sparks.
Extremes of temperature and direct sunlight.
Incompatible materials : Oxidizing agents
Bases
Amines
Hazardous decomposition
products
: Carbon dioxide (CO2)
Carbon monoxide
SECTION 11. TOXICOLOGICAL INFORMATION
Acute toxicity
Components:
acetone:
Acute oral toxicity : LD50 rat: 5,800 mg/kg
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Acute inhalation toxicity : LC50 rat: 132 mg/l
Exposure time: 3 h
LC50 rat: 50.1 mg/l
Acute dermal toxicity : LD50 guinea pig: > 7,426 mg/kg
LD50 rabbit: > 7,426 mg/kg
propane:
Acute inhalation toxicity : LC50 mouse: 1,237 mg/l
Exposure time: 2 h
LC50 rat: 658 mg/l
Exposure time: 4 h
LC50 rat: 1,355 mg/l
butane:
Acute inhalation toxicity : LC50 mouse: 1,237 mg/l
Exposure time: 2 h
LC50 rat: 1,355 mg/l
Skin corrosion/irritation
Product:
Remarks: slight irritation
Serious eye damage/eye irritation
Product:
Remarks: Irritating to eyes.
Respiratory or skin sensitisation
Product:
Remarks: Causes sensitisation.
Germ cell mutagenicity
no data available
Carcinogenicity
no data available
Reproductive toxicity
no data available
acetone:
propane:
butane:
eugenol:
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STOT - single exposure
no data available
STOT - repeated exposure
no data available
Aspiration toxicity
no data available
Further information
Product:
Remarks: Symptoms of overexposure may be headache, dizziness, tiredness, nausea
and vomiting., Concentrations substantially above the TLV value may cause narcotic
effects., Solvents may degrease the skin.
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
no data available
Persistence and degradability
no data available
Bioaccumulative potential
Product:
Partition coefficient: n-
octanol/water
: Remarks: no data available
Components:
butane :
Partition coefficient: n-
octanol/water
: Pow: 2.89
Mobility in soil
no data available
Other adverse effects
no data available
Product:
Regulation 40 CFR Protection of Environment; Part 82 Protection of
Stratospheric Ozone - CAA Section 602 Class I
Substances
Remarks This product neither contains, nor was manufactured
with a Class I or Class II ODS as defined by the U.S.
Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A
+ B).
Additional ecological
information
: no data available
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SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Waste from residues : Dispose of in accordance with local regulations.
Contaminated packaging : Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
Do not burn, or use a cutting torch on, the empty drum.
SECTION 14. TRANSPORT INFORMATION
Transportation Regulation: 49 CFR (USA):
ORM-D, CONSUMER COMMODITY
Transportation Regulation: IMDG (Vessel):
UN1950, AEROSOLS, 2.1, - Limited quantity
Transportation Regulation: IATA (Cargo Air):
UN1950, Aerosols, flammable, 2.1, - Limited quantity
Transportation Regulation: IATA (Passenger Air):
UN1950, Aerosols, flammable, 2.1, - Limited quantity
Transportation Regulation: TDG (Canada):
UN1950, AEROSOLS, 2.1, - Limited quantity
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity
Components CAS-No. Component RQ
(lbs)
Calculated product RQ
(lbs)
acetone 67-64-1 5000 *
*: Calculated RQ exceeds reasonably attainable upper limit.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
SARA 311/312 Hazards : Fire Hazard
Sudden Release of Pressure Hazard
Acute Health Hazard
SARA 302 : SARA 302: No chemicals in this material are subject to the
reporting requirements of SARA Title III, Section 302.
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SARA 313 : SARA 313: This material does not contain any chemical
components with known CAS numbers that exceed the
threshold (De Minimis) reporting levels established by SARA
Title III, Section 313.
California Prop 65 This product does not contain any chemicals known to State of
California to cause cancer, birth defects, or any other
reproductive harm.
The components of this product are reported in the following inventories:
TSCA On TSCA Inventory
DSL This product contains one or several components that are not on the
Canadian DSL nor NDSL.
AICS Not in compliance with the inventory
NZIoC Not in compliance with the inventory
PICCS Not in compliance with the inventory
IECSC Not in compliance with the inventory
Inventory Acronym and Validity Area Legend:
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan),
ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA)
SECTION 16. OTHER INFORMATION
Further information
NFPA: HMIS III:
OSHA GHS Label Information:
Hazard pictograms :
Signal word : Danger:
Hazard statements : Extremely flammable aerosol. Contains gas under pressure; may explode if heated. May
cause an allergic skin reaction. Causes serious eye irritation. May cause drowsiness or
dizziness.
Precautionary statements :
Prevention: Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking. Do not spray on an open flame or other ignition source.
Flammability
Health Instability
2
3
0
Special hazard.
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
3
2
2
0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic
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Pressurized container: Do not pierce or burn, even after use. Avoid breathing dust/
fume/ gas/ mist/ vapours/ spray. Wash skin thoroughly after handling. Use only outdoors
or in a well-ventilated area. Contaminated work clothing should not be allowed out of the
workplace. Wear eye protection/ face protection. Wear protective gloves.
Response: IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a
POISON CENTER or doctor/ physician if you feel unwell. IF IN EYES: Rinse cautiously
with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. If skin irritation or rash occurs: Get medical advice/ attention. If eye
irritation persists: Get medical advice/ attention. Wash contaminated clothing before
reuse.
Storage: Store in a well-ventilated place. Keep container tightly closed. Store locked up.
Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122 °F.
Disposal: Dispose of contents/container in accordance with local regulation.
Version: 1.0
Revision Date: 05/20/2015
Print Date: 05/31/2015
We believe the statements, technical information and recommendations contained herein are
reliable, but they are given without warranty or guarantee of any kind. The information in this
document applies to this specific material as supplied. It may not be valid for this material if it
is used in combination with any other materials. Users should make their own investigations
to determine the suitability and applicability of the information for their particular purposes.
This SDS has been prepared by the Compliance Services organization supporting this
manufacturer, supplier or distributor.