HomeMy WebLinkAbout05003-SSS-Disinfectant-DeodorantSAFETY DATA SHEET
SSS® DISINFECTANT DEODORANT (#05003)
Version 1.0 Revision Date 05/30/2015 Print Date 05/30/2015
1 / 11
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Material name
: SSS® Disinfectant Deodorant
EPA ID Number:
10807-177-12120
Material number : A00221
Manufacturer or supplier's details
Company : Triple S
Address : 2 Executive Park Drive
Billerica, MA 01862
Telephone : 978-667-7900
Emergency telephone numbers
For SDS Information : 978-667-7900
For a Medical Emergency : 1-888-779-1339
For a Transportation
Emergency
: 1-888-779-1339
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview
Appearance Aerosol containing a liquefied gas
Colour white, light yellow
Odour characteristic
GHS Classification
Flammable aerosols : Category 2
Gases under pressure : Liquefied gas
Eye irritation : Category 2A
GHS Label element
Hazard pictograms :
Signal word : Warning
Hazard statements : H223 Flammable aerosol.
H280 Contains gas under pressure; may explode if heated.
H319 Causes serious eye irritation.
Precautionary statements : Prevention:
P210 Keep away from heat, hot surfaces, sparks, open flames
and other ignition sources. No smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Pressurized container: Do not pierce or burn, even after
use.
P264 Wash skin thoroughly after handling.
SAFETY DATA SHEET
SSS® DISINFECTANT DEODORANT (#05003)
Version 1.0 Revision Date 05/30/2015 Print Date 05/30/2015
2 / 11
P280 Wear eye protection/ face protection.
Response:
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P337 + P313 If eye irritation persists: Get medical advice/
attention.
Storage:
P410 + P412 Protect from sunlight. Do not expose to
temperatures exceeding 50 °C/ 122 °F.
Disposal:
P501 Dispose of contents/container in accordance with local
regulation.
Potential Health Effects
Carcinogenicity:
IARC No component of this product present at levels greater than or
equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.
ACGIH No component of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential
carcinogen by ACGIH.
OSHA No component of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential
carcinogen by OSHA.
NTP No component of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture : Mixture
Hazardous components
Chemical Name CAS-No. Concentration [%]
ethanol 64-17-5 >= 50 - < 70
butane 106-97-8 >= 10 - < 20
propane 74-98-6 >= 1 - < 5
propan-2-ol 67-63-0 >= 1 - < 5
SECTION 4. FIRST AID MEASURES
General advice : Move out of dangerous area.
Show this safety data sheet to the doctor in attendance.
Do not leave the victim unattended.
If inhaled : If unconscious place in recovery position and seek medical
advice.
If symptoms persist, call a physician.
In case of skin contact : If skin irritation persists, call a physician.
SAFETY DATA SHEET
SSS® DISINFECTANT DEODORANT (#05003)
Version 1.0 Revision Date 05/30/2015 Print Date 05/30/2015
3 / 11
Wash off immediately with plenty of water for at least 15
minutes.
If on clothes, remove clothes.
Wash contaminated clothing before re-use.
In case of eye contact : Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.
In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes.
If swallowed : Keep respiratory tract clear.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
DO NOT induce vomiting unless directed to do so by a
physician or poison control center.
SECTION 5. FIREFIGHTING MEASURES
Suitable extinguishing media : Alcohol-resistant foam
Carbon dioxide (CO2)
Dry chemical
Water spray jet
Unsuitable extinguishing
media
: High volume water jet
Specific hazards during
firefighting
: Do not allow run-off from fire fighting to enter drains or water
courses.
Hazardous combustion
products
: Carbon dioxide (CO2)
Carbon monoxide
Smoke
Specific extinguishing
methods
:
Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Further information : For safety reasons in case of fire, cans should be stored
separately in closed containments.
Use a water spray to cool fully closed containers.
Collect contaminated fire extinguishing water separately. This
must not be discharged into drains.
Special protective equipment
for firefighters
: Wear self-contained breathing apparatus for firefighting if
necessary.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions,
protective equipment and
emergency procedures
: Use personal protective equipment.
Ensure adequate ventilation.
Remove all sources of ignition.
Evacuate personnel to safe areas.
SAFETY DATA SHEET
SSS® DISINFECTANT DEODORANT (#05003)
Version 1.0 Revision Date 05/30/2015 Print Date 05/30/2015
4 / 11
Beware of vapours accumulating to form explosive
concentrations. Vapours can accumulate in low areas.
Environmental precautions : Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.
Methods and materials for
containment and cleaning up
: Sweep up or vacuum up spillage and collect in suitable
container for disposal.
Soak up with inert absorbent material (e.g. sand, silica gel,
acid binder, universal binder, sawdust).
SECTION 7. HANDLING AND STORAGE
Advice on safe handling : Do not breathe vapours/dust.
Avoid contact with skin and eyes.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the
application area.
Take precautionary measures against static discharges.
Provide sufficient air exchange and/or exhaust in work rooms.
Open drum carefully as content may be under pressure.
Dispose of rinse water in accordance with local and national
regulations.
Always replace cap after use.
Do not breathe vapours or spray mist.
Conditions for safe storage : BEWARE: Aerosol is pressurized. Keep away from direct sun
exposure and temperatures over 50 °C. Do not open by force
or throw into fire even after use. Do not spray on flames or
red-hot objects.
No smoking.
Observe label precautions.
Keep in a dry, cool and well-ventilated place.
Electrical installations / working materials must comply with
the technological safety standards.
Materials to avoid : Oxidizing agents
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
Components CAS-No. Value type
(Form of
exposure)
Control
parameters /
Permissible
concentration
Basis
ethanol 64-17-5 TWA 1,000 ppm ACGIH
TWA 1,000 ppm
1,900 mg/m3
NIOSH REL
TWA 1,000 ppm
1,900 mg/m3
OSHA Z-1
TWA 1,000 ppm
1,900 mg/m3
OSHA P0
SAFETY DATA SHEET
SSS® DISINFECTANT DEODORANT (#05003)
Version 1.0 Revision Date 05/30/2015 Print Date 05/30/2015
5 / 11
butane 106-97-8 TWA 800 ppm
1,900 mg/m3
NIOSH REL
TWA 800 ppm
1,900 mg/m3
OSHA P0
propane 74-98-6 TWA 1,000 ppm ACGIH
TWA 1,000 ppm
1,800 mg/m3
NIOSH REL
TWA 1,000 ppm
1,800 mg/m3
OSHA Z-1
TWA 1,000 ppm
1,800 mg/m3
OSHA P0
propan-2-ol 67-63-0 TWA 200 ppm ACGIH
STEL 400 ppm ACGIH
TWA 400 ppm
980 mg/m3
NIOSH REL
ST 500 ppm
1,225 mg/m3
NIOSH REL
TWA 400 ppm
980 mg/m3
OSHA Z-1
TWA 400 ppm
980 mg/m3
OSHA P0
STEL 500 ppm
1,225 mg/m3
OSHA P0
Biological occupational exposure limits
Component CAS-No. Control
parameters
Biological
specimen
Sampling
time
Permissible
concentration
Basis
PROPAN-2-OL 67-63-0 Acetone Urine End of
shift at
end of
workwee
k
40 mg/l ACGIH BEI
Personal protective equipment
Respiratory protection : Use respiratory protection unless adequate local exhaust
ventilation is provided or exposure assessment demonstrates
that exposures are within recommended exposure guidelines.
Hand protection
Remarks : The suitability for a specific workplace should be discussed
with the producers of the protective gloves.
Eye protection : Ensure that eyewash stations and safety showers are close to
the workstation location.
Tightly fitting safety goggles
Skin and body protection : impervious clothing
Choose body protection according to the amount and
concentration of the dangerous substance at the work place.
Hygiene measures : When using do not eat or drink.
When using do not smoke.
Wash hands before breaks and at the end of workday.
SAFETY DATA SHEET
SSS® DISINFECTANT DEODORANT (#05003)
Version 1.0 Revision Date 05/30/2015 Print Date 05/30/2015
6 / 11
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : Aerosol containing a liquefied gas
Colour : white, light yellow
Odour : characteristic
Odour Threshold : no data available
pH : 10.3 - 10.8
Melting point/freezing point : no data available
Boiling point : no data available
Flash point :
no data available
Evaporation rate : no data available
Flammability (solid, gas) : Flammable aerosol.
Upper explosion limit : no data available
Lower explosion limit : no data available
Vapour pressure : no data available
Relative vapour density : no data available
Density : 0.840 g/cm3
Solubility(ies)
Water solubility : completely soluble
Solubility in other solvents : not determined
Partition coefficient: n-
octanol/water
: no data available
Auto-ignition temperature : not determined
Thermal decomposition : no data available
Viscosity
Viscosity, kinematic : no data available
Heat of combustion : 29.16 kJ/g
SECTION 10. STABILITY AND REACTIVITY
Reactivity : Stable
Chemical stability : Stable under normal conditions.
Possibility of hazardous
reactions
: No decomposition if stored and applied as directed.
Vapours may form explosive mixture with air.
Conditions to avoid : Heat, flames and sparks.
SAFETY DATA SHEET
SSS® DISINFECTANT DEODORANT (#05003)
Version 1.0 Revision Date 05/30/2015 Print Date 05/30/2015
7 / 11
Extremes of temperature and direct sunlight.
Heat, flames and sparks.
Incompatible materials : Oxidizing agents
Reducing agents
Ammonium salts
Hazardous decomposition
products
: Carbon oxides
SECTION 11. TOXICOLOGICAL INFORMATION
Acute toxicity
Product:
Acute oral toxicity : Acute toxicity estimate : > 5,000 mg/kg
Method: Calculation method
Components:
ethanol:
Acute oral toxicity : LD50 Oral rat: 7,060 mg/kg
Acute inhalation toxicity : LC50 rat: 124.7 mg/l
Exposure time: 4 h
butane:
Acute inhalation toxicity : LC50 mouse: 1,237 mg/l
Exposure time: 2 h
LC50 rat: 1,355 mg/l
propane:
Acute inhalation toxicity : LC50 mouse: 1,237 mg/l
Exposure time: 2 h
LC50 rat: 658 mg/l
Exposure time: 4 h
LC50 rat: 1,355 mg/l
propan-2-ol:
Acute oral toxicity : LD50 Oral rat: 4,396 mg/kg
Method: Calculation method
Skin corrosion/irritation
Product:
Remarks: May cause skin irritation in susceptible persons.
Serious eye damage/eye irritation
SAFETY DATA SHEET
SSS® DISINFECTANT DEODORANT (#05003)
Version 1.0 Revision Date 05/30/2015 Print Date 05/30/2015
8 / 11
Product:
Remarks: Severe eye irritation
Remarks: May cause irreversible eye damage.
Respiratory or skin sensitisation
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
no data available
Reproductive toxicity
no data available
ethanol:
butane:
propane:
propan-2-ol:
STOT - single exposure
no data available
STOT - repeated exposure
no data available
Aspiration toxicity
no data available
Further information
Product:
Remarks: no data available
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
no data available
Persistence and degradability
no data available
Bioaccumulative potential
Product:
Partition coefficient: n-
octanol/water
: Remarks: no data available
Components:
butane :
Partition coefficient: n-
octanol/water
: Pow: 2.89
SAFETY DATA SHEET
SSS® DISINFECTANT DEODORANT (#05003)
Version 1.0 Revision Date 05/30/2015 Print Date 05/30/2015
9 / 11
Mobility in soil
no data available
Other adverse effects
no data available
Product:
Regulation 40 CFR Protection of Environment; Part 82 Protection of
Stratospheric Ozone - CAA Section 602 Class I
Substances
Remarks This product neither contains, nor was manufactured
with a Class I or Class II ODS as defined by the U.S.
Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A
+ B).
Additional ecological
information
: no data available
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Waste from residues : Do not dispose of waste into sewer.
Do not contaminate ponds, waterways or ditches with
chemical or used container.
Dispose of in accordance with local regulations.
Contaminated packaging : Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
Do not burn, or use a cutting torch on, the empty drum.
SECTION 14. TRANSPORT INFORMATION
Transportation Regulation: 49 CFR (USA):
ORM-D, CONSUMER COMMODITY
Transportation Regulation: IMDG (Vessel):
UN1950, AEROSOLS, 2.1, - Limited quantity
Transportation Regulation: IATA (Cargo Air):
UN1950, Aerosols, flammable, 2.1, - Limited quantity
Transportation Regulation: IATA (Passenger Air):
UN1950, Aerosols, flammable, 2.1, - Limited quantity
Transportation Regulation: TDG (Canada):
UN1950, AEROSOLS, 2.1, - Limited quantity
SAFETY DATA SHEET
SSS® DISINFECTANT DEODORANT (#05003)
Version 1.0 Revision Date 05/30/2015 Print Date 05/30/2015
10 / 11
SECTION 15. REGULATORY INFORMATION
This product is regulated under the United States Federal Insecticide, Fungicide and Rodenticide Act
(FIFRA).
Pesticide Labeling Information Required Under U.S. FIFRA Regulations
This chemical is a pesticide product registered by the Environmental Protection Agency and is subject
to certain labeling requirements under federal pesticide law. These requirements differ from the
classification criteria and hazard information required for safety data sheets, and for workplace labels
of non-pesticide chemicals. Following is the hazard information as required on the pesticide label:
EPCRA - Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity
Components CAS-No. Component RQ
(lbs)
Calculated product RQ
(lbs)
sodium nitrite 7632-00-0 100 *
*: Calculated RQ exceeds reasonably attainable upper limit.
SARA 304 Extremely Hazardous Substances Reportable Quantity
Components CAS-No. Component RQ
(lbs)
Calculated product RQ
(lbs)
ammonia, anhydrous 7664-41-7 100 *
*: Calculated RQ exceeds reasonably attainable upper limit.
SARA 311/312 Hazards : Sudden Release of Pressure Hazard
Acute Health Hazard
Fire Hazard
SARA 302 : SARA 302: No chemicals in this material are subject to the
reporting requirements of SARA Title III, Section 302.
SARA 313 : SARA 313: This material does not contain any chemical
components with known CAS numbers that exceed the
threshold (De Minimis) reporting levels established by SARA
Title III, Section 313.
California Prop 65 WARNING! This product contains a chemical known to the
State of California to cause cancer.
biphenyl-2-ol 90-43-7
The components of this product are reported in the following inventories:
TSCA On TSCA Inventory
DSL This product contains one or several components that are not on the
Canadian DSL nor NDSL.
AICS Not in compliance with the inventory
NZIoC Not in compliance with the inventory
PICCS Not in compliance with the inventory
IECSC Not in compliance with the inventory
Inventory Acronym and Validity Area Legend:
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan),
ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA)
SAFETY DATA SHEET
SSS® DISINFECTANT DEODORANT (#05003)
Version 1.0 Revision Date 05/30/2015 Print Date 05/30/2015
11 / 11
SECTION 16. OTHER INFORMATION
Further information
NFPA: HMIS III:
OSHA GHS Label Information:
Hazard pictograms :
Signal word : Warning:
Hazard statements : Flammable aerosol. Contains gas under pressure; may explode if heated. Causes
serious eye irritation.
Precautionary statements : Prevention: Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking. Do not spray on an open flame or other ignition source.
Pressurized container: Do not pierce or burn, even after use. Wash skin thoroughly after
handling. Wear eye protection/ face protection.
Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get
medical advice/ attention.
Storage: Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122
°F.
Disposal: Dispose of contents/container in accordance with local regulation.
Version: 1.0
Revision Date: 05/30/2015
Print Date: 05/30/2015
We believe the statements, technical information and recommendations contained herein are
reliable, but they are given without warranty or guarantee of any kind. The information in this
document applies to this specific material as supplied. It may not be valid for this material if it
is used in combination with any other materials. Users should make their own investigations
to determine the suitability and applicability of the information for their particular purposes.
This SDS has been prepared by the Compliance Services organization supporting this
manufacturer, supplier or distributor.
Flammability
Health Instability
3
3
0
Special hazard.
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
3
2
3
0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic