HomeMy WebLinkAboutWinfield Cornerstone 5 Plus Cornerstone® 5 Plus
Safety Data Sheet (EPA Reg # 1381-241)
Revision Date: 12 – AUG – 13 1 of 6
SECTION 1: IDENTIFICATION
Product Name: Cornerstone® 5 Plus
EPA Registration #: 1381-241
Product ID/Unity #: 10125931, 10125932, 10125971, 10126357, 1421996 (Check product packaging to ensure EPA
registration number on package matches the number on this Safety Data Sheet)
Common Name: Glyphosate herbicide
Chemical Description: Isopropylamine salt of Glyphosate
Recommended Uses: Agricultural Herbicide. See product label for complete list of uses and use sites.
Restrictions for Use: See product label for information regarding restrictions on the use of this product.
Manufactured For: MEDICAL EMERGENCY TELEPHONE NUMBER: 1-877-424-7452 (24hrs)
WINFIELD SOLUTIONS, LLC
P. O. Box 64589 Non-Emergency Business Inquiries: 1-855-494-6343
St. Paul, MN 55164-0589 Mon – Fri 8am – 5pm (Central Standard Time)
FOR EMERGENCY, SPILL, LEAK, FIRE, EXPOSURE, OR ACCIDENT, CALL:
CHEMTREC 1-800-424-9300 (24 hours)
SECTION 2: HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW: Clear pale yellow to amber liquid with no to slight amine odor. Moderate eye irritant. May react with
metals such as galvanized or unlined steel to produce hydrogen gas which could form a highly combustible gas mixture.
POTENTIAL HEALTH EFFECTS:
Eyes: May cause moderate but temporary eye irritation..
Skin: Short-term contact with skin may cause mild irritation. Prolonged contact with skin may lead to swelling, redness and
blistering.
Inhalation: Inhalation of mist may cause mild irritation of the upper respiratory tract.
Ingestion: Ingestion may cause irritation of the digestive tract and lead to colitis.
Preexisting Conditions: Preexisting skin conditions may be aggravated by exposure to mist or spray.
Chronic Health Effects: None known
Carcinogenicity NTP: Not listed IARC: Not listed OSHA: Not listed
OSHA HCS 2012 CLASSIFICATION: Eye Irritation Category 2B; Acute Inhalation Toxicity Category 4
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
Causes eye irritation.
Harmful if inhaled.
Percent of product with unknown toxicity: 0%
PRECAUTIONARY STATEMENTS:
Prevention: Wash hands thoroughly after handling. Avoid breathing mist or spray. Use only outdoors or in a well-ventilated
area.
Continued on next page
NFPA HAZARD RATING U.S. TRANSPORT SUMMARY
0 Least
1 Slight 2 Health
2 Moderate 0 Flammability
3 High 1 Reactivity
4 Severe
Not regulated by the U.S. DOT as a
hazardous material. (See Section 14
for additional information.)
Cornerstone® 5 Plus (EPA Reg # 1381-241)
Revision Date: 12 – AUG – 13 2 of 6
Response: If in eyes: Rinse cautiously with water for 15 minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. If eye irritation persists: Get medical attention. If inhaled: Remove person to fresh air and
keep comfortable for breathing. Call a poison control center (1-877-424-7452) or doctor for treatment advice if
you feel unwell.
Storage: See section 7 for storage information.
Disposal See section 13 for disposal information.
SECTION 4: FIRST AID MEASURES
Inhalation: Remove person from contaminated area to fresh air and assist breathing as needed. Seek medical attention
if irritation occurs.
Ingestion: Seek medical attention or call a poison control center for treatment advice. Do not induce vomiting unless
instructed to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious
person.
Eyes: Flush eyes with clean water for at least 15 minutes. Lift eyelids to facilitate irrigation. If present, remove
contact lenses after 5 minutes and continue rinsing. Seek medical attention if irritation occurs.
Skin: Remove contaminated clothing and wash before re-using. Flush skin with water and then wash with soap
and water. Seek medical attention if irritation persists.
SECTION 5: FIRE FIGHTING MEASURES
Suitable Extinguishing Media: Use water spray, foam or dry chemical. Foam or dry chemical extinguishing systems are
recommended to prevent environmental damage due to water run-off.
Special Fire Fighting Procedures: Wear NIOSH/MSHA approved self-contained breathing apparatus and full bunker gear.
Dike area to prevent runoff and contamination of water sources. Dispose of fire control water later. Avoid breathing vapors; keep
upwind.
Hazardous Combustion Products: Carbon monoxide, nitrogen oxides and phosphorous oxides
Unusual Fire and Explosion Hazards: May decompose in fire due to releasing irritating or toxic gases.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Personal Precautions: Refer to Section 8 for personal protective equipment to be worn during containment and clean-up of a
spill involving this product.
Environmental Precautions: Keep spilled product from entering sewers or waterways.
Methods for Containment: Contain spilled product by diking area with sand or earth.
Methods for Clean-up: Cover contained spill with an inert absorbent material such as sand, vermiculite or other appropriate
material. Vacuum, scoop, or sweep up material and place in a container for disposal. Do not place spilled material back in
original container.
Other Information: None known
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
Ingredient % (wt) CAS Reg. #
Isopropylamine salt of glyphosate 53.8% 38641-94-0
*Ingredients not specifically listed are non-hazardous and are considered to be confidential business information under 29 CFR
1910.1200(i).
See Section 8 for exposure limits.
Cornerstone® 5 Plus (EPA Reg # 1381-241)
Revision Date: 12 – AUG – 13 3 of 6
SECTION 7: HANDLING AND STORAGE
Handling: RECOMMENDATIONS ARE FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING WORKERS.
PESTICIDE APPLICATORS AND WORKERS must refer to the pesticide product label and Directions for Use attached to the
product for Agricultural Use Requirements in accordance with the EPA Worker Protection Standard 40 CFR part 170. Ensure
adequate ventilation. Immediately clean up spills that occur during handling. Keep containers closed when not in use. Practice
good hygiene after using this material, especially before eating, drinking, smoking, using the toilet, or applying cosmetics.
Storage: Store in cool, dry areas away from children, feed and food products and sources of heat. Store in original container
with lid tightly closed. Store above 10°F (-12°C). If crystallized, warm to 80-90°F and re-dissolve by shaking container before
using product. Do not store in galvanized steel or unlined mild steel containers. See pesticide product label for additional
storage information.
Minimum Storage Temperature: 10°F
Other Precautions: Consult Federal, state and local laws and regulations pertaining to storage.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Guidelines
Component: OSHA PEL ACGIH TLV NIOSH REL
No components have exposure guidelines
NOTE TO END USERS: PERSONAL PROTECTIVE EQUIPMENT (PPE) AND CLOTHING LISTED IN THIS SECTION IS FOR
MANUFACTURING, COMMERCIAL BLENDING AND PACKAGING WORKERS. APPLICATORS AND HANDLERS SHOULD
REFER TO THE PESTICIDE PRODUCT LABEL FOR PROPER PERSONAL PROTECTIVE EQUIPMENT (PPE) AND
CLOTHING.
Respiratory Protection: Wear respiratory protection if inadequate ventilation. Wear a NIOSH-certified (or equivalent) TC23C
Chemical/Mechanical type filter system to remove a combination of particles, gas and vapors.
Engineering Controls: Local Exhaust: Provide general or local exhaust ventilation systems to maintain airborne
concentrations below OSHA PELs or other specified exposure limits. Local exhaust ventilation is
preferred.
Protective Gloves: Wear chemical resistant gloves.
Eye Protection: Wear chemical goggles or safety glasses and full-face shield. Contact lenses are not eye protective devices.
An emergency eyewash or water supply should be readily accessible to the work area.
Other Protective Clothing or Equipment: Wear long sleeve shirt, long pants and shoes plus socks to prevent skin exposure.
Work/Hygienic Practices: Never eat, drink, nor use tobacco in work areas. Practice good hygiene after using this material,
especially before eating, drinking, smoking, using the toilet, or applying cosmetics.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid Specific Gravity (H2O=1): 1.18 – 1.25 (typical)
Vapor Pressure (mm Hg): Not determined Density (lbs/gallon): 9.85 – 10.43 lbs/gallon
Vapor Density (Air=1): Not determined Melting Point/Freezing Point: Not determined
Solubility in Water (wt %): Not determined Boiling Point/Range: Not determined
Viscosity: Not determined pH: 4.6 – 5.1
Appearance and odor: Clear pale yellow to amber
liquid with no to slight amine
odor.
Flash Point: Does not flash
SECTION 10: STABILITY AND REACTIVITY
Reactivity: Reacts with galvanized steel or unlined mild steel to produce hydrogen, a highly flammable gas that could explode.
Chemical Stability: Product is stable at ambient temperature and pressure, under normal storage and handling conditions.
Possibility of Hazardous Reactions: Will not occur
Conditions to Avoid: Temperatures above 115°F (46°C) and below 10°F (-12°C).
Incompatible Materials: Strong oxidizers or bases, mild and galvanized steel.
Hazardous Decomposition Products: Carbon monoxide, Nitrogen oxides, phosphorous oxides
Cornerstone® 5 Plus (EPA Reg # 1381-241)
Revision Date: 12 – AUG – 13 4 of 6
SECTION 11: TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
Eye Effects: Causes moderate eye irritation (rabbit) clearing within 48 hours.
Skin Effects: Short-term contact with skin may cause mild irritation. Prolonged contact with skin may lead to
swelling, redness and blistering. LD50 >5,000 mg/kg (male rat). Product is not a sensitizer.
Acute Inhalation Effects: LC50 >2.5 mg/L (rat)
Acute Oral Effects: LD50 >5,000 mg/kg (rat)
Specific Target Organ
Toxicity:
None known
CHRONIC TOXICITY
Chronic Effects: None known
Carcinogenicity: None known
Mutagenicity: None known
Teratogenicity: None known
Reproductive Toxicity: None known
POTENTIAL HEALTH EFFECTS:
Eyes: May cause moderate but temporary eye irritation.
Skin: Short-term contact with skin may cause mild irritation. Prolonged contact with skin may lead to swelling, redness and
blistering.
Inhalation: Inhalation of mist may cause mild irritation of the upper respiratory tract.
Ingestion: Ingestion may cause irritation of the digestive tract and lead to colitis.
SECTION 12: ECOLOGICAL INFORMATION
ENVIRONMENTAL SUMMARY: Do not apply directly to water, to areas where surface water is present or to intertidal areas
below the mean high water mark. Do not contaminate water when cleaning equipment or disposing of equipment washwaters or
rinsate. The information presented below is on the technical active ingredient, glyphosate.
ECOTOXICITY DATA:
Fish Acute and Prolonged Toxicity: Bluegill Sunfish: >24 mg/L (48 hour)
Rainbow Trout: 140 mg/L (48 hour)
Aquatic Invertebrate Acute Toxicity: Daphnia magna: 780 ppm (48 hour)
Aquatic Plant Toxicity: Not determined
Bird Acute and Prolonged Toxicity: Bobwhite quail: Acute LD50 >2,000 mg/kg
Honeybee Toxicity: >100 ug/bee (oral); practically non-toxic
ENVIRONMENTAL EFFECTS:
Soil Absorption/Mobility: Even though technical glyphosate is highly water soluble it appears that parent
glyphosate and its degradation product, aminomethyl phosphonic acid (AMPA), have
a low potential to move to ground-water due to their strong adsorptive characteristics
demonstrated in laboratory and field studies. However, glyphosate does have the
potential to contaminate surface waters due to its aquatic use patterns and erosion via
transport of residues adsorbed to soil particles suspended in runoff water. If
glyphosate were to reach surface water it would be resistant to hydrolysis and
aqueous photolysis.
Persistence and degradability: Glyphosate technical is readily degraded by soil microbes to aminomethyl phosphonic
acid (AMPA), which is degraded to CO2, although at a slower rate than parent
glyphosate.
Bioaccumulative Potential: Not determined
Other adverse effects: Not determined
Cornerstone® 5 Plus (EPA Reg # 1381-241)
Revision Date: 12 – AUG – 13 5 of 6
SECTION 13: DISPOSAL CONSIDERATIONS
Waste: Dispose of in accordance with applicable Federal, state and local laws and regulations.
Container: Triple rinse and recycle the container or dispose of in accordance with Federal, state and local laws and regulations.
See pesticide product label for full instructions on disposal.
RCRA Characteristics: It is the responsibility of the individual disposing of this product to determine the RCRA classification
and hazard status of the waste.
SECTION 14: TRANSPORT INFORMATION
DOT:
(Ground)
This product is not regulated by the U.S. Department of Transportation as a hazardous material for ground
shipment.
IMDG:
(Sea) Not determined
IATA:
(Air) Not determined
TDG:
(Canada) Not determined
SECTION 15: REGULATORY INFORMATION
TSCA Inventory: This product is exempt from TSCA inventory listing requirements as it is solely for FIFRA regulated use.
SARA Title III Information:
Section 302 - Extremely hazardous substances: None listed
Section 311/312 – Hazard Categories: Immediate (Acute)
Section 313 – The following chemicals are subject to the reporting requirements of Section 313 of Title III, Superfund
Amendments and Reauthorization Act of 1986 and 40 CFR 372:
None listed
CERCLA - This product contains the following chemicals which have a reportable quantity (RQ) under the Comprehensive
Environmental Response, Compensation, and Liability Act (CERCLA):
None listed
EPA Registration Information: This chemical is a pesticide product registered by the Environmental Protection Agency and is
subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and
hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard
information as required on the pesticide label:
CAUTION
Causes moderate eye irritation.
Do not get in eyes, on skin, or on clothing.
Wash thoroughly with soap and water after handling. Remove contaminated clothing and wash clothing before re-use.
DOMESTIC ANIMALS: This product is considered to be relatively non-toxic to dogs and other domestic animals; however,
ingestion of this product or large amounts of freshly sprayed vegetation may result in temporary gastrointestinal irritation
(vomiting, diarrhea, colic, etc.). If such symptoms are observed, provide the animal with plenty of fluids to prevent dehydration.
Call a veterinarian if symptoms persist for more than 24 hours.
California Proposition 65: This product does not contain any chemicals known to the state of California to cause cancer and/or
reproductive harm.
U.S. State Worker and Community Right-To-Know (RTK) Information (CT, IL, MA, MN, NH, NJ, PA, RI):
Chemical Name CAS # State(s)
No components listed
Canadian Domestic Substances List: Not determined
WHMIS Classification: This product is not registered for use in Canada. WHMIS classification is not determined.
Cornerstone® 5 Plus (EPA Reg # 1381-241)
Revision Date: 12 – AUG – 13 6 of 6
SECTION 16: OTHER
Disclaimer: The information presented herein is based on available data from reliable sources and is correct to the best of
WinField Solutions’ knowledge. WinField Solutions, LLC makes no warranty, express nor implied, regarding the accuracy of the
data or the results obtained from the use of this product. Nothing herein may be construed as recommending any practice or any
product in violation of any law or regulations. The user is solely responsible for determining the suitability of any material or
product for a specific purpose and for adopting any appropriate safety precautions. We disclaim all liability for injury or damage
stemming from any improper use of the material or product described herein.
Revision Date: August 12, 2013 Supersedes document dated: January 11, 2010
Sections Revised: All