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Road Repair &Maintenance
High Performance Pothole Patch/Cold Patch
Safety Data Sheet
according toFederal Register /Vol.77.No 58/Monday.March 26.2012 /Rules and Regulations
Date of issue:07/09/2015 Version: 1.0
1.1.Product Identifier
Product form :Mixture
Tradename T11 :High Performance Pothole Patch/Cold Patch
12.Relevant identified usesofthe substance or mixture and usesadvised against
Use of the substance/mixture Repairing asphalt or concrete pavement,driveways,sidewalks,parking lots &utility cuts
1.3.Details of the supplierof the safetydatasheet
TEAM Laboratory Chemical Corp.
28650 State Highway 34
P0 Box 1467
Detroit Lakes,MN 56502
1-4.Emergency telephone number
Emergencynumber
SECTION 2:Hazards identification
2.1.Classification of the substanceor mixture
Classification (GHS-US)
Care.2 H351
Fulltext of H-phrases:see section 16
2.2.Label elements
GHS-US labeling
Hazard pictograms (GHS-US)
Infotrac:800-535-5053
.
Til
Signal word (GHS-US)Warning
Hazard statemenls (GHS-US).H351 -Suspected of causing cancer
Precautionary statements (GHS-US):P201 -Obtain special instructions before use
P202 - Donol handle until allsafety precautions have been read and understood
P280 -Wear protective equipment
P308 +P313 - Ifexposed or concerned: Gel medical advice/attention
2.3.Other hazards
Vapors and gasesfrom heated asphalt may contain hydrogen sulfide andmay beirritating tothe
eyesandskin.Skin contact with asphalt may causeskin irritation andallergic reactions in some
individuals Hot material may cause burns.
2.4. Unknown acute toxicity (GHS-US)
None ofthe ingredients inthe mixture areofunknown toxicity.
M44,MJHM.InlAUI»MiMI.IMJ„MiM.W
3.1.Substance
Not applicable -product is a mixture
3.2.Mixture
Other hazards nol contributing to Ihe
classification
Name
Asphalt
Fuel oil No.2
mProduct identifier
,(CASNo)8052-42-4
(CAS No)G84763b~2~
'The exact concentrations have been withheld as a trade secret
Full text of H-phrases:see section 16
07/09/2015 EN (EnglishUS)
Classification (GHS-US)
_?-"§!.'•Care.2,H351
Acute Tox. 4 (Inhalation.dust.misl).H3321-3-
Page 1 of 6
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High Performance Pothole Patch/Cold Patch
Safety Data Sheet
according toFederal Register /Vol.77.No.58/Monday.March 26.2012 /Rules andRegulations
SECTION 4:First aid measures
4.1.Description of first aid measures
First-aid measures general
First-aid measures after inhalation
First-aidmeasures after skin contact
First-aid measures after eye contact
Nevergiveanything bymouth toanunconscious person.Ifyoufeel unwell,seek medical
advice (show thelabel where possible).Suspectedofcausing cancer.
: Allow victim to breathe fresh air. Allow the victim to rest.
: Removeaffectedclothing andwashallexposedskinarea with mild soap andwater,followed
by warm water rinse.
:Rinse immediately with plenty ofwater.Obtain medical attention if pain,blinking orredness
persists
First-aid measures after ingestion ;Rinse mouth.Do NOT induce vomiting.Obtain emergency medical attention
4.2.Most important symptomsandeffects,both acute and delayed
No additional information available
4.3.Indication ofanyImmediate medical attentionandspecial treatment needed
Noadditional information available
SECTION 5:Firefighting measures
5.1.Extinguishing media
Suitable extinguishing media :Foam.Dry powder.Carbon dioxide.Water spray Sand.
Unsuitable extinguishing media : Donotusea heavy waler stream.
5.2.Special hazards arising from the substance or mixture
No additional information available
5.3.Advice for firefighters
Firefighting inslructions
Protection during firefighting
Use water spray orfog for cooling exposed containers.Exercise caution when fighting any
chemical fire.Preventfire-fighting waterfrom enteringenvironment.
Do notenterfire areawithout proper protective equipment,including NIOSH approved positive-
pressure breathing apparatuswith full facemaskandfull protective equipment
SECTION 6:Accidental release measures
6.1.
6 1 1.
Emergency procedures
6.1.2 For emergency responders
Protective equipment
Emergency procedures
6.2.Environmental precautions
Prevent entry tosewers andpublic waters.Notify authorities if material enters sewers orpublic waters.
6.3.Methods andmaterial for containment andcleaning up
Methods for cleaning up ; Onland,sweeporshovel into suitable containers for reuse.
6.4.Reference toother sections
See Heading 8. Exposurecontrols and personalprotection.
Personal precautions,protective equipmentandemergency procedures
For non-emergency personnel
SECTION 7:Handling and storage
7.1.Precautions for safe handling
Precautions forsafe handling
Evacuateunnecessary personnel.
Equipcleanup crew withproper protection
Ventilate area.
Wash hands andother exposed areaswith mild soapandwater before eating,drinking or
smoking andwhen leaving work.Provide good ventilation inwork area topreventformation of
vapor.Obtainspecial instructions before use. Donothandle until allsafety precautionshave
been read and understood
7.2.Conditions for safe storage,Including any Incompatibilities
Storage conditions
Incompatible products
Incompatiblematerials
7.3.Specific end use(s)
No additional information available
07/09/2015
Keeponlyin Iheoriginal container ina cool,well ventilated place. Keepcontainerclosedwhen
not in use.
Strong bases.Strong acids.
Sources of ignition.
EN (English US)Page 2 of 6
>:
High Performance Pothole Patch/Cold Patch
Safety Data Sheet
according toFederalRegister/Vol.77.No.58/Monday.March 26.2012/Rules andRegulalions
SECTION 8:Exposure controls/personal protection
8.1.Control parameters
High Performance Pothole Patch/Cold Patch
ACGIH Not applicable
OSHA Not applicable
Asphalt(8052-42-4)
ACGIH IACGIH TWA (mg/m3)0 5 mg/m'Inhalable fraction
OSHA Not applicable
Fuel oil No. 2 (68476-30-2)
ACGIH
OSHA
!ACGIH TWA (mg/m3)
J Not applicable
100 mg/ms (inhalable fraction and vapor)
HydrogenSulfide (7783-06-4)may be released from this product
USA ACGIH
USA ACGIH
USA OSHA
'USA OSHA
USA OSHA
8.2.Exposure controls
Appropriate engineering controls
Personal protective equipment
Hand protection
Eye protection
Respiratory protection
Other information
ACGIH TWA(ppm)
ACGIH STEL (ppm)
OSHA PEL (ppm)"(Vacated limits)
OSHA STEL (ppm)7vacaled limits)
OSHA Ceiling(ppm)
1 ppm
5 ppm
10 ppm
15 ppm
20 ppm
: Ensure that proper ventilation is provided to maintainexposures belowregulated limits
Avoid all unnecessary exposure.
: Wearprotective glovesthatprotectagainstthermal burnswhenhandling hotmaterial.
: Chemical goggles or safety glasses
Nottypically required In cases whereexposuresexceedoccupational control limits,a NIOSH
approved respirator is recommended
: Donot eat.drink or smoke duringuse. Wash hands and other exposed areas afteruse
SECTION 9:Physical and chemical properties
9.1.Informationon basic physical and
Physical state
Appearance
Color
Odor
Odor threshold
PH
Melting point
Freezing point
Boiling point
Flash point
Relativeevaporation rale (butylacetate=1)
Relativeevaporation rate (ether=1)
Flammability(solid,gas)
Explosion limits
Explosive properties
Oxidizing properties
Vaporpressure
Relative density
Relative vapor density at 20 'C
Solubility
Log Pow
07/09/2015
chemical properties
.Coated stone
.Granular Black Material
:Black
Petroleum
:No data available
:No data available
:No data available
:No data available
No data available
.No data available
No data available
Slower than ether
.No data available
.No data available
.No data available
:No data available
:No data available
:No data available
:Heavier than air
:Negligible in water.
.No data available
EN (English US)Page 3 of 6
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High Performance Pothole Patch/Cold Patch
Safety Data Sheet
according to Federal Register /Vol.77.No.53 /Monday,March 26,2012 /Rules and Regulat/ons
L°9Kow :No data available
Auto-.gnition temperature .No data available
Decomposition temperature ;No data available
v,scosity .No data available
Viscosity,kinematic No dalaavailable
Viscosity,dynamic .No data available
9.2.Other information
Percentvolatile 0-4% by volume
SECTION 10:Stability and reactivit
10.1.Reactivity
No additional information available
10.2. Chemical stability
Stable under normal conditions of use.
10.3. Possibility of hazardous reactions
This material isnot known to undergo hazardous polymerization.
1<L4.Conditions to avoid
Extremely highor lowtemperatures.
10.5.Incompatible materials
Avoid contact w.th strong acids,oxidizing agents,and petroleum product to preserve the quality of this material.
10.6.Hazardousdecomposition products
Hydrogen sulfide and other toxic vapors may be given off when heated excessively.Carbon monoxide.Carbon dioxide.
SECTION 11:Toxicological information
11-1.Information ontoxicological effects
Acute toxicity Not classified
Asphalt (8052-42-4)
LD50 oral rat
LD50dermal rabbit
Fuel oilNo.2 (68476-30-2)
LD50 oral rat
LD50 dermalrabbit
J.C50 inhalation rat(mg/l)
ATE US (oral)
ATE US (vapors)"_
ATE US (dust,mist)'""
Skin corrosion/irritation
Serious eye damage/irritation
Respiratory or skin sensitization
Germ cell mutagenicity
Carcinogenicity
Asphalt (8052-42-4)
IARC group
> 5000 mg/kg
>2000 mg/kg"
I 12g/kg
[4>20 pi/kg
.4.6mg/l/4h
12000.000 mg/kg body weight
j4.600 mg/l/4hJ.llOOmg/Wh
Not classified
Not classified
Not classified
Not classified
Suspected ofcausingcancer.
2^_Possiblycarcinogenic tohumans
L1ai!°Aai Toxicology Program (NTP)Status 5-Twelfth Report -Items under consideration
In OSHA Hazard Communication Carcinoqen Yes
, list
Reproductive toxicity
Specific target organ toxicity (single exposure)
Specific largelorgan toxicity (repeated
exposure)
Aspiration hazard
07/09/2015
•Not classified
:Not classified
:Not classified
Nol classified
EN (English US)Page4 or 6
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High Performance Pothole Patch/Cold Patch
Safety Data Sheet
according toFederal Register /Vol.77.No 58/Monday,March 26.2012 /Rules andRegulalions
Potential Adverse human health effects and . Noadditional informationavailable
symptoms
SECTION 12:Ecological information
12.1.Toxicity
jFuel oil No.2(
[k?5^0??Ll_
Fuel oil No. 2 (68476-30-2)
LC50fish 1
12.2.Persistence and degradablllty
35 mg/l(Exposure lime:96h -Species: Pimephales promelas [flow-through])
High Performance Pothole Patch/Cold Patchy
jPersistence and degradability j Not established.
Asphalt (8052-42-4)
[Persistence anddegradability
12.3.Bloaccumulative potential
j Not establishedL
High Performance Pothole Patch/Cold Patch
Bioaccumulative potential I Notestablished.
Asphalt(8052-42-4)
BCFfish 1 (nobioaccumulation expected)
Log Pow >6
Bioaccumulative potenlial Not established.
12.4.Mobility in soil
No additional information available
12.5.Other adverse effects
Other information Avoid release to the environment
SECTION 13:Disposal considerations
13.1.Waste treatmentmethods
Waste disposal recommendations
Ecology -waste materials
SECTION 14:Transoort information
Department of Transportation (DOT)
In accordance with DOT
Not regulated for transport
Additional information
ADR
No additional information available
Transport by sea
No additional information available
Air transport
No additional information available
SECTION 15:Regulatory information
15.1. US Federal regulations
High Performance Pothole Patch/Cold Patch
SARASection 311/312 Hazard Classes
: Dispose in a safe manner inaccordance withlocal,state and federal regulations.
:Avoid release to Ihe environment.
Delayed (chronic)health hazard
fAsphalt (8052-42-4)
Listedon IheUnitedStates TSCA (Toxic Substances ControlAct)inventory
I Fuel oil No,2(68476-30-2)
Listed on the United States TSCA (Toxic Substances Control Act)inventory
07/09/2015 EN(English US)Page 5 of 5
High Performance Pothole Patch/Cold Patch
Safety Data Sheet
according toFederal Register /Vet.77.No 58/Monday.March 26.2012 /Rules andRegulations
15.2.International regulations
CANADA
l^phalt_(8652"-42-4J
'
Listedon the Canadian DSL(DomesticSustances List)
Fuel oil No.2(68476-30-2)
j Listed onjrte Canadian DSL (Domestic Sustances List)
EU-Regulations
Asphalt (8052-42-4)
Listed on theEEC inventory EINECS (European Inventory ofExisting Commercial Chemical Substances)
Fuel oil No. 2 (68476-30-2)
Listed ohIhe EEC Inventory EINECS (European Inventory ofExisting Commercial Chemical Substances)
Classificationaccording to Regulation (EC)No.1272/2008 [CLP]
No additional information available
Classification according to Directive 67/548/EEC (DSD]or 1999/45/EC (DPD)
No additional information available
National regulations
Asphalt (8052-42-4)
Listed ontheAICS (Australian Inventory ofChemical Substances)
Listed on IECSC (Inventory ofExisting Chemical Substances Produced or Imported in China)
Listed onthe Japanese ENCS (Existing &New Chemical Substances)inventory
Listed onthe Korean ECL (Existing Chemicals List)
Listed onNZIoC (New Zealand Inventory ofChemicals)
Listed onPICCS (Philippines Inventory ofChemicals andChemical Substances)
Fuel oil No.2 (68476-30-2)
Listed ontheAICS (Australian Inventory ofChemical Substances)
Listed onIECSC (Inventory ofExisting Chemical Substances Produced orImported in China)
Listed onthe Korean ECL (Existing Chemicals List)
Listedon NZIoC (New ZealandInventory ofChemicals)
Listed onPICCS (Philippines Inventory ofChemicals andChemical Substances)
15.3.US State regulations
Asphalt (8052-42-4)
. J
U.S.-California -
Proposition 65 -
Carcinogens List
U.S.-California -
Proposition 65 -
Developmental Toxicity
U.S.-California -
Proposition65 -
Reproductive Toxicity-
Female
U.S.-California -
Proposition 65 -
Reproductive Toxicity
Male
No significance risk
level (NSRL)
Yes No
SECTION 16:Other information
Other information
Full text of H-phrases:
Acute Tox.4 (Inhalation dust.mist)
Care.2
H332
H351
No
None.
No
Acute toxicity(inhalation:dust.mist) Category 4
Carcinogenicity Caiegory 2
Harmful ifinhaled
Suspected ofcausing cancer
SDS US (GHS HazCom 2012)
The information contained in this SDSisBelievedtobeaccurate asolthe time thatthis documentMSprepared.Altchemicals maypresent unknownhealth hazards and should be used»Ch cautionAlthoughcertainhazardsaredesenbtdherein,.ve cannotguarantee thatthese are the onlyhazards that exist Finaldetermination olswlabJily o'thechemicals)rsthe sole responnbi't/otthe userUsersolanychemicalshouldsatisfythomschasthattheconditionsandmethodsoluseassurethatthechemicalisusedsalcly
riOREPRESENTATIONS OR WARRANTIES.EITHER EXPRESS OR IMPLIED.OF MERCHANTABILITY FITNESS FORAPARTICULAR PURPOSE ORANY OTHER NATURE ARE MADE
HEREUNDER WITHRESPECT TO IHEINFORMATIONCONTAINED T-ERElNORTHE CHEMICAL TO WHICHTHE INFORMATIONREFERS.
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