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Home My WebLink AboutBrother Ink Cartridge LC61BK* \ r brother at your side SAFETY DATA SHEET Paints &Inks Product name:LC37BK,LC51BK,LC57BK, LC960BK, LC970BK, LC1000BK,LC51HYBK,LC57HYBK,LC960HYBK,LC1000HYBK Ink Issuing Date:20-December-2005 Revision Date:1-April -2015 Version:13 SDSNo:BHK014-01-EUUSOTHER [SECTION 1:Identification of the substance/mixture and of the company/undertaking" 1.1 Product identifier Product name (code)LC37BK(LK3104001, LK4790001), LC51BK(LK2083001,LK4155001), LC57BK(LK2361001.LK4758001), LC960BK (LK2459001),LC970BK (LK2645001), LC1000BK (LK2552001),LC51HYBK (LK2198001),LC57HYBK(LK2367001), LC960HYBK(LK2466001), LC1000HYBK(LK2329001) 1.2 Relevant identified uses of the substance or mixture and uses advised against Relevant Identified Use(s)These products are black ink in a cartridge for Brother Industries,Ltd. inkjet multifunction devices and fax receivers.The cartridge should be used as supplied by Brother and for use in the products stated.Information provided on this SDS is only consistent with the use specified by Brother. 1.3 Details ofthe supplier ofthe safety data sheet Manufacturer Importer (USA) Importer (Canada) Importer (Europe) Importer (Australia) E-mail Address 1.4 Emergencytelephone number EmergencyTelephone (24 hours) M Brother Industries,Ltd. 15-1 Naeshiro-cho,Mizuho-ku,Nagoya 467-8561,Japan Telephone (for information):+81-52-824-2735 Brother International Corporation 200 Crossing Boulevard,Bridgewater,NJ 08807,USA Telephone (for information):+1-877-276-8437 Brother International Corporation (Canada)Ltd. 1 Hotel de Ville,Dollard des Ormeaux,Quebec,H9B 3H6,Canada Telephone (for information):+1-514-685-0600 Brother International Europe Ltd. Brother House,1 Tame Street,Guide Bridge,Audenshaw,Manchester M34 5JE,UK Telephone (for information):+44-161-330-6531 Brother International (Aust.)Pty.Ltd.ACN 001 393 835 Level 3, Building A,11 Talavera Road,Macquarie Park,NSW 2113,Australia Telephone (for information):+61-2-9887-4344 sds.info@brother.co.jp CHEMTREC +1-703-527-3887 (International) +1-800-424-9300 (North America) For France only: Antipoison Centertelephone number:ORFILA +33-1-45-425-959 Page 1 /8 brother at yourside SAFETY DATA SHEET Product name:LC37BK,LC51BK,LC57BK,LC960BK, LC970BK, LC1000BK,LC51HYBK, LC57HYBK, LC960HYBK, LC1000HYBK Ink [SECTION 2: Hazards identification Issuing Date:20-December-2005 Revision Date:1-April -2015 Version:13 SDSNo:BHK014-01-EUUSOTHER 2.1 Classification ofthe substance or mixture Classification according to Regulation (EC) No 1272/2008 Not classified as hazardous Classification according to Directive 1999/45/EC Not classified as hazardous Australia Classification Notclassified as hazardous according to the criteria of NOHSC 2.2 Label elements Labelling according to Regulation (EC) No. 1272/2008 Hazard pictograms None Signal Word None Hazard Statements EUH208 -Contains 1,2-benzisothiazol-3(2H)-one.May produce an allergic reaction. Precautionary statements None 2.3 Other hazards Thisproduct containsnosubstanceconsidered tobepersistent,bioaccumulating nortoxic (PBT).This product containsnosubstanceconsidered to be verypersistent norvery bioaccumulating (vPvB). SECTION 3:Composition/information on ingredients 3.2 Mixtures Description of the mixture:Water based inkjet ink(Mixture). Chemical Name CAS-No EC-No w/w%Classification (67/548/EEC) Classification (EU Reg.1272/2008) Glycerol 56-81-5 200-289-5 20-30 Notclassified Not classified Carbon Black 1333-86-4 215-609-9 1-5 Not classified Not classified Water 7732-18-5 231-791-2 65-75 Not classified Not classified 1,2-benzisothiazol-3(2H)-one 2634-33-5 220-120-9 <0.05 Xn;R22 Xi;R41 Xi;R38 R43 N;R50 Acute Tox. 4 (Oral),H302 Skin Irrit.2,H315 Eye Dam. 1,H318 Skin Sens.1.H317 Aquatic Acute 1,H400 For the full text of R-phrases and H-Statements see Section 16 Page 2/8 r brother at yourside SAFETY DATA SHEET Product name:LC37BK,LC51BK,LC57BK,LC960BK, LC970BK, LC1000BK,LC51HYBK,LC57HYBK,LC960HYBK,LC1000HYBK Ink Issuing Date:20-December-2005 Revision Date: 1-April -2015 Version:13 SDSNo:BHK014-01-EUUSOTHER [SECTION 4: First aid measures 4.1 Description of first aid measures General advice Inhalation Skin contact Eye contact Ingestion 4.2 Most important symptoms and effects,both acute and delayed 4.3 Indication of any immediate medical attention and special treatment needed Ifsymptoms persist,obtain medical attention. Obtain medical attention. In case of accident by inhalation remove casualty to fresh air and keep at rest. Remove contaminated clothing immediately and wash affected skin with plenty ofwateror soap and water. Obtain medical attention. Ifsubstance has got into the eyes,immediately wash out with plenty of water for at least 15 minutes. Obtain immediate medical attention.Wash out mouth with water and give 100-200 ml of water to drink. Skin contact:Repeated and/or prolonged skin contact may cause irritation. Eye contact:Maycause eye irritation. Ingestion: Ingestion may cause irritation ofthe gastrointestinal tract.Unlikely route of exposure. Inhalation: Unlikelyroute of exposure. Treat symptomatically. (SECTION 5:Firefighting measures 5.1 Extinguishing media Suitable Extinguishing Media Unsuitable Extinguishing Media 5.2 Special hazards arising from the substance ormixture 5.3 Advice for firefighters Extinguishpreferablywithdrychemical, carbon dioxide,water spray, foam. None. Thermal decomposition of organic components may result in occurrence of oxides of carbon.Toxic gases may be formed upon combustion and represents a hazard to firefighters.Combustion products:See Section:10. Use appropriate respirator for carbon monoxide and carbon dioxide.Wear positive pressure self-contained breathing apparatus (SCBA)during the attack phase of firefighting operationsand during cleanup inenclosed or pooriyventilated areas immediately after a fire.Personnel not having suitable respiratory protection must leave the area to preventsignificant exposure to toxic combustion gases from any source. Page 3/8 brother at your side SAFETY DATA SHEET Product name:LC37BK,LC51BK,LC57BK,LC960BK, LC970BK, LC1000BK,LC51HYBK,LC57HYBK,LC960HYBK,LC1000HYBK Ink [SECTION 6:Accidental release measures Issuing Date:20-December-2005 Revision Date:1-April -2015 Version:13 SDS No:BHK014-01-EUUSOTHER 6.1 Personal precautions,protective Ensure adequate ventilation. Avoidcontactwith eyes. equipment and emergency procedures 6.2 Environmental precautions Prevent substance entering sewers. Washings must be prevented fromentering surface water drains. 6.3 Methods and materials for containment and cleaning up Wipe up with absorbent towelWash with water to remove remaining traces of ink 6.4 Referenceto other sections For personal protection:See section 8. For disposal considerations:See section 13. [SECTION 7:Handling and storage^ Keep out of the reach of children. Avoid contact with skin and eyes. Keep awayfrom oxidizing agents. 7.1 Precautions for safe handling 7.2 Conditions for safe storage, including any incompatibilities 7.3 Specific end use(s)These products are black ink in a cartridge for Brother Industries,Ltd. inkjet multifunction devices and fax receivers.This cartridgeshould be used as supplied by Brother and for use in the products stated. SECTION 8:Exposure controls/personal protection 8.1 Control Parameters Occupational Exposure Limits Chemical Name Glycerol 56-81-5 ACGIH TLV TWA: 10 mg/mJ mist OSHAPEL TWA:15 mg/mJ mist,totalparticulate TWA:5 mg/m3 mist,respirablefraction European Union - The United Kingdom STEL:30 mg/mJ TWA:10 mg/m3 France TWA:10mg/mJ Spain TWA:10mq/mJ Germany TWA:50 mg/mJ Ceiling / Peak:100 mg/m3 Portugal TWA:10mq/mJ Finland TWA:20 mq/mJ Switzerland STEL:100 mg/mJ TWA:50 mg/m3 Poland TWA:10mg/mJ Ireland TWA:10 mg/mJ Chemical Name Carbon Black 1333-86-4 ACGIH TLV TWA:3 mg/mJ inhalable fraction OSHAPEL TWA:3.5 mg/mJ European Union - The United Kingdom STEL:7 mg/mJ TWA:3.5 mg/m3 France TWA:3.5 mg/mJ Spain TWA:3.5mg/rrf Page 4/8 brother at yourside SAFETY DATA SHEET Product name:LC37BK, LC51BK, LC57BK,LC960BK, LC970BK, LC1000BK,LC51HYBK,LC57HYBK,LC960HYBK,LC1000HYBK Ink Issuing Date:20-December-2005 Revision Date:1-April -2015 Version:13 SDS No:BHK014-01-EUUSOTHER Germany Care Portugal TWA:3.5 mg/mJ Finland TWA:3.5 mg/mJ STEL:7 mg/m3 Denmark TWA: 3.5 mq/mJ Poland TWA: 4.0 mg/mJ Norway TWA:3.5 mg/mJ STEL:7mg/m3 Ireland TWA:3.5 mg/mJ STEL:7mq/m3 8.2 Exposure controls Appropriate engineering controls Good general ventilation should be sufficient under normal use. Personal protective equipment Eye Protection Hand Protection Skinand body protection Respiratory protection Not normally required. For use otherthan in normal operating procedures (such as in the event of large spill),the following should be applied: Safety goggles. Protective gloves. Long sleeved clothing and long pants. Large spillages:Wear suitable respiratory protective equipment. Environmental Exposure Controls Avoid release to the environment. SECTION 9:Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance Physical state Liquid Color Black Odor Slight Odor Threshold No information available pH 7 - 9 Melting point/freezing point -/<-5 °C Initial boiling point and boiling range >100 °C Flash Point Not less than 93.3°C ( Tag closed cup;Cleveland open Evaporation rate No information available Flammability (solid,gas)Not applicable Upper/lower flammability or explosive No information available limits Vapor pressure No information available Vapor density No information available Relative density 1.0-1.1 (H20=1) Solubility(ies)Soluble (water) Partition coefficient:n-octanol/water No information available Auto-ignition temperature >400 "C Decomposition temperature No information available Viscosity 1 -5mPas Explosive properties Not explosive Oxidizing properties No information available 9.2 Other information No information available. Page 5/8 brother at yourside SAFETY DATA SHEET Product name:LC37BK,LC51BK,LC57BK,LC960BK,LC970BK, LC1000BK,LC51HYBK,LC57HYBK,LC960HYBK,LC1000HYBKInk Issuing Date:20-December-2005 Revision Date:1-April-2015 Version:13 SDS No:BHK014-01-EUUSOTHER [SECTION 10:Stability and reactivity 10.1 Reactivity 10.2 Chemical stability 10.3 Possibility of hazardous reactions 10.4 Conditions toavoid 10.5 Incompatible materials 10.6 Hazardous decomposition products No information available. Stable. No information available. No information available. Strong oxidizing agents. Contains:Carbon monoxide (CO). Carbon dioxide (C02). SECTION 11:Toxicologicai information 11.1 Information on toxicologicai effects Acutetoxicity Inhalation Eye contact Skincontact Ingestion Skin corrosion/irritation Serious eye damage/irritation No information available. No information available. No information available. LD50 > 2000 mg/kg (Method OECD#420) Non-irritant. (Method:OECD#404) Minimal irritantto the eye. (Method:OECD#405) Respiratoryorskin sensitisation It isnota skinsensitizer.(Method:OECD#429) Mutagenicity Carcinogenicity Negative. (Method:OECD#471) Carbon Black:In 1996,the IARC re-evaluated carbon black as a Group 2Bcarcinogen (possible human carcinogen).This classification is given to chemicals,for which there is inadequate human evidence, but sufficientanimalevidence on whichto base an opinionofcarcinogenicity.The classificationis based upon the development of lungtumors inrats receivingchronicinhalation exposures to free carbon blackat levels that induce particleoverload ofthe lung.Studies performed in animal models other than rats did not show any association between carbon black and lung tumors. Other ingredients of this product have not been classified as carcinogens according to IARC monographs,NTP and OSHA. Page 6/8 r brother at yourside SAFETY DATA SHEET Product name:LC37BK.LC51BK,LC57BK,LC960BK, LC970BK, LC1000BK,LC51HYBK,LC57HYBK,LC960HYBK,LC1000HYBK Ink Issuing Date:20-December-2005 Revision Date:1-April -2015 Version:13 SDSNo:BHK014-01-EUUSOTHER SECTION 12:Ecological information 12.1 Toxicity Chemical Name Toxicity to algae Toxicityto fish Toxicityto daphnia and other aquatic invertebrates Glycerol 56-81-5 LC50:51 -57mUL96h static (Oncorhynchus mykiss) EC60:>500 mg/L 24 h (Daphnia magna) Carbon Black 1333-86-4 ECso:>5600 mg/L 24 h (Daphnia magna) 12.2 Persistence and degradability No information available. 12.3 Bioaccumulative potential Chemical Name log Pow Glycerol -1.76 12.4 Mobility in soil 12.5 Results of PBT and vPvB assessment 12.6 Otheradverse effects No information available. This product contains no substance considered to be persistent,bioaccumulating nor toxic (PBT). This product contains no substance considered to be very persistent nor very bioaccumulating (vPvB). No information available. SECTION 13:Disposal considerations 13.1 Waste treatment methods Dispose of in accordance with Federal,State,and local regulations. SECTION 14:Transport information Not classified according to the United Nations "Recommendationson the Transport of Dangerous Goods" 14.1 UN Number None 14.2 UN propershipping name None 14.3 Transport hazard class(es)None 14.4 Packing Group None 14.5 Environmental hazards None 14.6 Special precautions for user None 14.7 Transport in bulk according to Not applicable Annex IIof Marpol 73/78 and the IBC Code Not regulated under DOT,IMDG,IATA. Page 7/8 brother at yourside SAFETY DATA SHEET Productname:LC37BK,LC51BK,LC57BK,LC960BK,LC970BK, LC1000BK,LC51HYBK,LC57HYBK, LC960HYBK, LC1000HYBK Ink Issuing Date:20-December-2005 Revision Date:1-April -2015 Version:13 SDS No:BHK014-01-EUUSOTHER [SECTION 15:Regulatory information" 15.1 Safety,health and environmental regulations/legislation specific for the substance or mixture EU:Notclassified as dangerous forsupply/use.(1999/45/EC) USA:Allchemical substancescontained in this product are and had been listed on the TSCA Chemical Substances Inventory, and none is subjectto any of the followingTSCA requirements: section 4 test rules;proposed or finalsection 5(a)(2) significant new use rules;section 5(e)consent orders; section 8(a)preliminary assessment informationrules; and section 8(d) health and safety data reporting rules. Canada:WHMIS:Not applicable.(Manufactured article) No.15.2Chemical Safety Assessment [SECTION 16:Other information Full text ofR-phrases referred to undersections 2 and 3 Full text ofH-Statements referred to under sections 2 and 3 Additional information Revision Note References: Abbreviations: R22 -Harmful if swallowed R41 - Risk of seriousdamage to eyes R38 - Irritating to skin R43 - Maycause sensitization by skin contact R50 - Very toxic to aquatic organisms H302 -Harmful if swallowed H315 -Causes skin irritation H318 -Causes serious eye damage H317 - Maycause an allergic skin reaction H400 - Very toxic to aquatic life The information relates only to this product. Itmay not be valid, ifused in combination withany other materials or inany other process,and it is based on our bestknowledge as of the date of preparation (revision). SECTION 2, 3. U.S.29CFR Part 1910 ACGIH Threshold Limit Values for ChemicalSubstances and Physical Agents and Biological Exposure Indices IARCMonographs on the Evaluation Carcinogenic Risks to Humans World Health Organization EU Directive 91/322/EEC and 2000/39/EC NTP 11th Report on Carcinogens ACGIH:American Conference of Governmental Industrial Hygienists DOT:Department Of Transportation (US) IARC:International Agencyfor Research on Cancer IATA:International Air Transport Association IMDG:International Maritime Dangerous Goods NOHSC: National Occupational Health and SafetyCommission (Australia) NTP:National Toxicology Program (US) OSHA:Occupational Safety and Health Administration (US) PEL:Permissible Exposure Limit STEL:Short Term Exposure Limit TLV:Threshold LimitValue (ACGIH) TSCA:Toxic Substances Control Act (US) TWA:Time WeightedAverage WHMIS:Workplace Hazardous Material Information System (Canada) Page 8/8