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Home My WebLink AboutBayer Telar XP Herbicide - 9-2-15Bayer Environmental Science SAFETY DATA SHEET TELAR®XP HERBICIDE Version 2.0/USA 102000030327 Herbicides &Pesticides 1/10 Revision Date:09/02/2015 Print Date:09/02/2015 3.SECTION 1:IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF 1 -t COMPANY/UNDERTAKING Product identifier Trade name TELAR®XP HERBICIDE Product code (UVP)84067172 SDS Number 102000030327 EPA Registration No.432-1561 Relevant identified uses ofthe substance or mixture and uses advised against Use Herbicide Restrictions on use See product label for restrictions. Information on supplier Supplier Bayer Environmental Science 2 T.W.Alexander Drive Research Triangle PK, NC 27709 United States Email:SDSINFO.BCS-NA@bayer.com < Responsible Department Emergency telephone no. Emergency Telephone Number (24hr/7 days) Product Information Telephone Number 1-800-334-7577 1-800-331-2867 SECTION 2:HAZARDS IDENTIFICATION Classification in accordance with regulation HCS 29CFR §1910.1200 This material is not hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29CFR 1910.1200. Other hazards No particular hazards known. SECTION 3:COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Component Name chlorsulfuron Lignosulfonic acid,sodium salt,sulfomethylated CAS-No. 64902-72-3 68512-34-5 Concentration %by weight 75.0 6.0 o C u Bayer Environmental Science SAFETY DATA SHEET TELAR®XP HERBICIDE Version 2.0/USA 102000030327 2/10 Revision Date:09/02/2015 Print Date:09/02/2015 SECTION 4:FIRST AID MEASURES Description offirst aid measures General advice Inhalation Skin contact Eye contact Ingestion Treatment When possible,have the product containeror label with you when calling a poison control centeror doctor or going for treatment. Move to fresh air. If person is not breathing,call 911 or an ambulance, then give artificial respiration,preferably mouth-to-mouth if possible.Call a physician or poison control centerimmediately. Take offcontaminated clothing and shoes immediately.Wash off immediatelywith plenty of waterfor at least 15 minutes.Call a physician or poison control center immediately. Hold eye open and rinse slowly and gently with waterfor 15-20 minutes. Remove contact lenses,if present,afterthe first 5 minutes,then continue rinsing eye.Call a physician or poison control center immediately. Call a physician or poison control center immediately.Rinse out mouth and give water in small sips to drink. DO NOT induce vomiting unless directed to do so by a physician or poison control center.Nevergive anything by mouth to an unconscious person.Do not leave victim unattended. Most important symptoms and effects,both acute and delayed Symptoms To date no symptoms are known. Indication ofany immediate medical attention and special treatment needed Appropriate supportive and symptomatic treatment as indicated by the patient's condition is recommended.There is no specific antidote. SECTION 5:FIREFIGHTING MEASURES Extinguishing media Suitable Unsuitable Special hazards arising from the substance or mixture Advice for firefighters Special protective equipment for fire-fighters Further information Use water spray,alcohol-resistant foam,dry chemical or carbon dioxide. High volume waterjet Dangerous gases are evolved in the event of a fire. Firefighters should wear NIOSH approved self-contained breathing apparatus and full protective clothing. Keep out of smoke.Fight fire from upwind position.Cool closed containers exposed to fire with waterspray.Do not allow run-off from fire fighting to enter drains or water courses.Wheneverpossible, contain fire-fighting water by diking area with sand or earth. /*% (C C Bayer Environmental Science SAFETY DATA SHEET TELAR®XP HERBICIDE Version 2.0/USA 102000030327 3/10 Revision Date:09/02/2015 Print Date:09/02/2015 Flash point Autoignition temperature Lowerexplosion limit Upper explosion limit Explosivity not applicable no data available not applicable not applicable no data available SECTION 6:ACCIDENTAL RELEASE MEASURES Personal precautions,protective equipment and emergency procedures Precautions Keep unauthorized people away. Isolate hazard area.Avoid contact withspilled product or contaminated surfaces. Methods and materials for containment and cleaning up Methods for cleaning up Additional advice Reference to other sections Sweep uporvacuumupspillageand collectinsuitablecontainerfor disposal.Cleancontaminated floors and objects thoroughly,observing environmental regulations.Contaminatedsoilmay have to be removed and disposed. Usepersonal protective equipment.Donotallowtoenter soil, waterways or waste water canal. Donot allowproduct to contact non- target plants. Information regarding safe handling,see section 7. Information regardingpersonal protectiveequipment,see section8. Information regarding waste disposal,see section 13. SECTION 7:HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Ensure adequate ventilation.Handleand open container ina manner as to prevent spillage. Wash hands thoroughlywith soap and water after handlingand before eating,drinking,chewinggum, usingtobacco, using the toiletor applying cosmetics. Remove Personal Protective Equipment (PPE)immediately after handlingthis product. Remove soiledclothingimmediatelyand clean thoroughly before using again.Wash thoroughly and put on clean clothing. Conditions for safe storage,including any incompatibilities Hygiene measures ' U Bayer Environmental Science SAFETY DATA SHEET TELAR®XP HERBICIDE Version 2.0 /USA 102000030327 4/10 Revision Date:09/02/2015 Print Date:09/02/2015 Requirements for storage areas and containers Store in a cool,dry place and in such a manner as to prevent cross contamination with other crop protection products,fertilizers,food,and feed.Store in original container and out of the reach of children, preferably in a locked storage area. SECTION 8:EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Components CAS-No.Control parameters Update Basis Sucrose 57-50-1 10mg/m3 (TWA) 02 2012 ACGIH Sucrose (Total) 57-50-1 10 mg/m3 (REL) 2010 NIOSH Sucrose (Respirable.) 57-50-1 5 mg/m3 (REL) 2010 NIOSH Sucrose (Respirable fraction.) 57-50-1 5 mg/m3 (PEL) 02 2006 OSHA Z1 Sucrose (Total dust.) 57-50-1 15mg/m3 (PEL) 02 2006 OSHA Z1 Sucrose (Respirable fraction.) 57-50-1 5 mg/m3 (TWA) 1989 OSHAZ1A Sucrose (Total dust.) 57-50-1 15 mg/m3 (TWA) 1989 OSHAZ1A Sucrose (Total dust.) 57-50-1 15 mg/m3 (TWA) 06 2008 TNOEL Sucrose (Respirable fraction.) 57-50-1 5 mg/m3 (TWA) 06 2008 TNOEL Sucrose 57-50-1 5ug/m3 (AN ESL) 03 2014 TXESL Sucrose 57-50-1 50ug/m3 (ST ESL) 03 2014 TXESL Exposure controls Personal protective equipment In normal use and handling conditions please refer to the label and/or leaflet.In all other cases the following recommendations would apply. Respiratory protection When respirators are required,select NIOSH approved equipment based on actual or potential airborne concentrations and in accordance with the appropriate regulatory standards and/or industry recommendations. Hand protection Eye protection Skin and body protection General protective measures Chemical resistant nitrile rubber gloves Safety glasses with side-shields Wear long-sleeved shirt and long pants and shoes plus socks. Follow manufacturer's instructions for cleaning/maintaining PPE.If no such instructions for washables,use detergent and warm/tepid 1 e. Bayer Environmental Science SAFETY DATA SHEET TELAR®XP HERBICIDE Version 2.0/USA 102000030327 5/10 Revision Date:09/02/2015 Print Date:09/02/2015 water. Keep and wash PPE separately from other laundry. SECTION 9.PHYSICAL AND CHEMICAL PROPERTIES Appearance Physical State Odor OdourThreshold PH Vapor Pressure Vapor Density (Air =1) Bulk density Evapouration rate Boiling Point Melting /Freezing Point Water solubility Minimum Ignition Energy Decomposition temperature Partition coefficient:n- octanol/water Viscosity Flash point Autoignition temperature Lower explosion limit Upper explosion limit Exploslvity light tan to brown granular mild no data available 5-7at1 % (as aqueous solution) no data available no data available 580-700kg/m3 not applicable not applicable not applicable dispersible not applicable no data available not applicable not applicable not applicable no data available not applicable not applicable no data available SECTION 10:STABILITY AND REACTIVITY Reactivity Thermal decomposition Chemical stability no data available Stable under normal conditions. o ('.) U Bayer Environmental Science SAFETY DATA SHEET TELAR®XP HERBICIDE Version 2.0/USA 102000030327 6/10 Revision Date:09/02/2015 Print Date:09/02/2015 Possibility of hazardous reactions Conditions to avoid Incompatible materials No hazardous reactions when stored and handled according to prescribed instructions. no data available no data available Hazardous decomposition No decomposition products expected under normal conditions of use. products SECTION 11:TOXICOLOGICAL INFORMATION Exposure routes Immediate Effects Eye Skin Ingestion Information on toxicological Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity Skin irritation Eye irritation Sensitisation ACGIH None. NTP None. IARC None. OSHA None. Ingestion,Eye contact,Skin contact,Inhalation May cause slight irritation. May cause slight irritation. Harmful if swallowed. effects LD50(rat)4,286 mg/kg no data available LD50(rat)>5,000 mg/kg Slight irritation (rabbit) Slight irritation (rabbit) Non-sensitizing,(guinea pig) OECD Test Guideline 406,Buehler test Further information Only acute toxicity studies have been performed on the formulated product.^% (f C Bayer Environmental Science SAFETY DATA SHEET TELAR®XP HERBICIDE Version 2.0/USA 102000030327 7/10 Revision Date:09/02/2015 Print Date:09/02/2015 SECTION 12:ECOLOGICAL INFORMATION Toxicity to fish Toxicity to aquatic invertebrates Toxicity to aquatic plants Environmental precautions LC50 (Oncorhynchus mykiss (rainbow trout)) > 122 mg/l Exposure time:96 h The value mentioned relates to the active ingredient chlorsulfuron. EC50 (Daphnia magna (Waterflea))>112 mg/l Exposure time:48 h The value mentioned relates to the active ingredient chlorsulfuron. LC50(Mysidopsis bahia (mysid shrimp)) 89 mg/l Exposure time:96 h The value mentioned relates to the active ingredient chlorsulfuron. ErC50 (Raphidocelis subcapitata (freshwater green alga))> 0.24 mg/l Exposure time:72 h EbC50 (Raphidocelis subcapitata (freshwater green alga)) 0.088 mg/l Exposure time: 72 h Do not apply directlyto water, to areas where surface water is present or to intertidal areas below the mean high water mark. Do not contaminate surface or ground water by cleaning equipment or disposal of wastes,including equipment wash water. SECTION 13:DISPOSAL CONSIDERATIONS Waste treatment methods Product Contaminated packaging RCRA Information Do not contaminate water,food, or feed by disposal. Dispose of unused product by incineration at a licensed incineration plant, in accordance withall applicable national and local regulations. Consult state and local regulations regarding the proper disposal of container. Follow advice on product label and/orleaflet. Characterization and proper disposal of this material as a special or hazardous waste is dependent upon Federal,State and local laws and are the user's responsibility. RCRA classification may apply. SECTION 14:TRANSPORT INFORMATION 49CFR Not dangerous goods / not hazardous material IMDG UN number Class Packaging group 3077 9 o U Bayer Environmental Science SAFETY DATA SHEET TELAR®XP HERBICIDE 8/10 Version 2.0 /USA Revision Date:09/02/2015 102000030327 PrintDate:09/02/2015 Marine pollutant YES Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE,SOLID, N.O.S. (CHLORSULFURON MIXTURE) IATA UN number 3077 Class 9 Packaging group III Environm.Hazardous Mark YES Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE,SOLID, N.O.S. (CHLORSULFURON MIXTURE) This transportation information is not intended to convey all specific regulatory information relating to this product.It does notaddress regulatory variations due to package size or special transportation requirements. ()SECTION 15:REGULATORY INFORMATION ^ EPA Registration No.432-1561 US Federal Regulations TSCA list Lignosulfonic acid,sodium salt,68512-34-5 sulfomethylated US.Toxic Substances Control Act(TSCA)Section 12(b)Export Notification (40 CFR 707,Subpt D) None. SARA Title III -Section 302 -Notification and Information None. SARA Title III -Section 313 -Toxic Chemical Release Reporting chlorsulfuron 64902-72-3 US States Regulatory Reporting CA Prop65 This product does not contain any substances known to the State of California to cause cancer. This product does not contain any substances known to the State of Califomia to cause reproductive harm. US State Right-To-Know Ingredients chlorsulfuron 64902-72-3 NJ,Rl Canadian Regulations Canadian Domestic Substance List None. Environmental CERCLA None. Clean Water Section 307 Priority Pollutants C Bayer Environmental Science SAFETY DATA SHEET TELAR®XP HERBICIDE 9/10 Version 2.0/USA Revision Date:09/02/2015 102000030327 Print Date:09/02/2015 None. Safe Drinking Water Act Maximum Contaminant Levels None. EPA/FIFRA Information: Thischemicalis a pesticideproductregisteredbythe Environmental Protection Agencyand issubjectto certain labeling requirements underfederal pesticide law.These requirements differ from theclassification criteria and hazard information required forsafetydata sheets, and forworkplace labelsofnon-pesticide chemicals.Following is the hazard information requiredon the pesticide label: Signal word:Cautionl Hazard statements:Harmful if swallowed. Wash hands thoroughlywithsoap and water after handling and before eating,drinking,chewinggum, using tobacco, using the toilet or applying cosmetics. SECTION 16:OTHER INFORMATION Abbreviations and acronyms 49CFR Code of Federal Regulations,Title 49 ACGIH US.ACGIH Threshold Limit Values CAS-Nr.Chemical Abstracts Service number EINECS European inventory ofexisting commercial substances ELINCS European list of notified chemical substances IARC US.IARC Monographs on Occupational Exposures to Chemical Agents IATA International AirTransport Association IMDG International Maritime Dangerous Goods N.O.S.Not otherwise specified NTP US. National Toxicology Program (NTP)Report on Carcinogens OECD Organization for Economic Co-operation and Development TDG Transportation of Dangerous Goods TWA Time weighted average UN United Nations WHO World health organisation NFPA 704 (National Fire Protection Association): Health-1 Flammability -1 Instability- 0 Others-none HMIS (Hazardous Materials Identification System,based on the Third Edition Ratings Guide) Health-1 Flammability -1 Physical Hazard - 0 PPE- 0 = minimalhazard,1 = slight hazard,2 =moderate hazard, 3 =severe hazard,4 =extreme hazard Reason for Revision:New Safety Data Sheet. o Bayer Environmental Science SAFETY DATA SHEET TELAR®XP HERBICIDE 10/10 Version 2.0 /USA Revision Date:09/02/2015 102000030327 Print Date:09/02/2015 Revision Date:09/02/2015 This informationis provided in good faith but without express or impliedwarranty. The customerassumes all responsibility for safety and use not in accordance withlabel instructions.The product names are registered trademarks of Bayer. ,(^ U