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HomeMy WebLinkAboutExpo Cleaners in BottlesExpo Cleaner - Bottle CHEMTREC (U.S. and Canada) 1-800-424-9300 SAFETY DATA SHEET Product name Emergency telephone number (with hours of operation) Section 1. Identification : : Manufacturer :Newell Rubbermaid 3500 Lacey Road, 10th Floor Downers Grove, IL 60515 USA 800-323-0749 or 630-829-2500 Material uses :Cleaning solutions. Section 2. Hazards identification Not classified.Classification of the substance or mixture : Signal word :Not applicable Hazard statements :No known significant effects or critical hazards. Precautionary statements Prevention :Not applicable. Response :Not applicable. Storage :Not applicable. Disposal :Not applicable. GHS label elements General :Read label before use. If medical advice is needed, have product container or label at hand. OSHA/HCS status :While this material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200), this SDS contains valuable information critical to the safe handling and proper use of the product. This SDS should be retained and available for employees and other users of this product. Hazards not otherwise classified :None known. Section 3. Composition/information on ingredients 3-butoxypropan-2-ol 0.1 - 2 5131-66-8 Ingredient name CAS number% There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Any concentration shown as a range is to protect confidentiality or is due to batch variation. Substance/mixture :Mixture Date of issue/Date of revision :3/26/2015.Date of previous issue :No previous validation.Version :1 1/8 Expo Cleaner - Bottle Section 3. Composition/information on ingredients Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if symptoms occur. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if symptoms occur. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Description of necessary first aid measures Specific treatments :No specific treatment. Most important symptoms/effects, acute and delayed Inhalation :No known significant effects or critical hazards. No known significant effects or critical hazards.:Ingestion Skin contact :No known significant effects or critical hazards. No known significant effects or critical hazards.:Eye contact Over-exposure signs/symptoms Skin contact Ingestion Inhalation No specific data. No specific data. No specific data. : : : Eye contact :No specific data. Potential acute health effects See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide In a fire or if heated, a pressure increase will occur and the container may burst. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : : None known. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Date of issue/Date of revision :3/26/2015.Date of previous issue :No previous validation.Version :1 2/8 Expo Cleaner - Bottle Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : :No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders :If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. : : Protective measures Put on appropriate personal protective equipment (see Section 8).: Precautions for safe handling None. Section 8. Exposure controls/personal protection Environmental exposure controls :Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls :Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Control parameters Individual protection measures Occupational exposure limits Date of issue/Date of revision :3/26/2015.Date of previous issue :No previous validation.Version :1 3/8 Expo Cleaner - Bottle Section 8. Exposure controls/personal protection Hand protection Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side- shields. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Skin protection Other skin protection :Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Section 9. Physical and chemical properties Physical state Melting point Vapor pressure Relative density Vapor density Solubility Liquid. Not available. Not available. Not available. Not available. Easily soluble in the following materials: cold water and hot water. Characteristic.Odor pH Clear.Color Evaporation rate Not available. Auto-ignition temperature Flash point Not available. Open cup: 100°C (212°F) [Estimated.] Not available. Not available. Viscosity Not available. Not available.Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance Boiling point :Not available. Flammability (solid, gas):Not available. Lower and upper explosive (flammable) limits :Not available. Burning rate Not applicable.: Burning time :Not applicable. SADT Not available.: Decomposition temperature :Not available. Solubility in water :Not available. Date of issue/Date of revision :3/26/2015.Date of previous issue :No previous validation.Version :1 4/8 Expo Cleaner - Bottle Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid No specific data. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability No specific data. : : : Incompatible materials : Possibility of hazardous reactions :Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity :No specific test data related to reactivity available for this product or its ingredients. Section 11. Toxicological information Acute toxicity 3-butoxypropan-2-ol LD50 Dermal Rabbit 3100 mg/kg - Product/ingredient name Result Species Dose Exposure Carcinogenicity No known significant effects or critical hazards. Mutagenicity No known significant effects or critical hazards. Teratogenicity No known significant effects or critical hazards. Reproductive toxicity No known significant effects or critical hazards. Irritation/Corrosion No known significant effects or critical hazards. Sensitization No known significant effects or critical hazards. Information on the likely routes of exposure Delayed and immediate effects and also chronic effects from short and long term exposure Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) No known significant effects or critical hazards. No known significant effects or critical hazards. Aspiration hazard No known significant effects or critical hazards. Information on toxicological effects :Not available. Potential immediate effects :Not available. Short term exposure Potential delayed effects :Not available. Date of issue/Date of revision :3/26/2015.Date of previous issue :No previous validation.Version :1 5/8 Expo Cleaner - Bottle Section 11. Toxicological information No known significant effects or critical hazards.General : No known significant effects or critical hazards.Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : No known significant effects or critical hazards.Teratogenicity : Developmental effects :No known significant effects or critical hazards. Fertility effects :No known significant effects or critical hazards. Potential chronic health effects Numerical measures of toxicity Dermal 161551.5 mg/kg Route ATE value Acute toxicity estimates Potential immediate effects :Not available. Long term exposure Potential delayed effects :Not available. Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Other adverse effects :No known significant effects or critical hazards. Product/ingredient name 3-butoxypropan-2-ol 1.2 -low Toxicity No known significant effects or critical hazards. Persistence and degradability No known significant effects or critical hazards. Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. :Disposal methods Date of issue/Date of revision :3/26/2015.Date of previous issue :No previous validation.Version :1 6/8 Expo Cleaner - Bottle Section 14. Transport information - - - - - - - Not regulated. - - Not regulated.Not regulated. --- DOT Classification IMDG IATA UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards Special precautions for user No.No.No. Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. : TDG Classification Not regulated. - - - No. - Mexico Classification Not regulated. - - - No. - Section 15. Regulatory information U.S. Federal regulations :United States inventory (TSCA 8b): All components are listed or exempted. SARA 311/312 Classification :Not applicable. 3-butoxypropan-2-ol 0.1 - 2 Yes.No.No.Yes.No. Name %Fire hazard Sudden release of pressure Reactive Immediate (acute) health hazard Delayed (chronic) health hazard Composition/information on ingredients The following components are listed: Propylene glycol butyl ether Not controlled under WHMIS (Canada). None of the components are listed. Canada WHMIS (Canada) Canadian lists Canadian NPRI CEPA Toxic substances : : : Canada inventory :All components are listed or exempted. This product does not contain Chemicals known to State of California to cause cancer, birth defects, or reproductive harm. California Prop. 65 Section 16. Other information History Date of issue/Date of revision Version Prepared by Date of previous issue : : : : 3/26/2015. No previous validation. 1 Product Safety. Date of issue/Date of revision :3/26/2015.Date of previous issue :No previous validation.Version :1 7/8 Expo Cleaner - Bottle Section 16. Other information Since the user's working conditions are not known by us, the information supplied on this safety data sheet is based on our current level of knowledge and on national and community regulations. The mixture must not be used for other uses than those specified in section 1 without having first obtained written handling instructions. It is at all times the responsibility of the user to take all necessary measures to comply with legal requirements and local regulations. The information in this safety data sheet must be regarded as a description of the safety requirements relating to the mixture and not as a guarantee of the properties thereof. Indicates information that has changed from previously issued version. Key to abbreviations :ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient UN = United Nations Date of issue/Date of revision :3/26/2015.Date of previous issue :No previous validation.Version :1 8/8