HomeMy WebLinkAboutBuckeye Blue3ockeqe Safety Data Sheet
Issue Date:27-Dec-2011
Product Identifier
Product Name
Other means of identification
SDS#
Product Code
Revision Date:19-Aug-2014
1.IDENTIFICATION
Buckeye Blue
BE-5001
5001
Recommended use of the chemical and restrictions on use
Recommended Use All Purpose Cleaner,Water Based.
Details ofthe supplier of the safety data sheet
Supplier Address
Buckeye International,Inc.
2700 Wagner Place
Maryland Heights,MO 63043 USA
Emergency Telephone Number
Company Phone Number
Emergency Telephone (24 hr)
1-651-632-8956 (International)
1-800-303-0441 (North America)
INFOTRAC 1-352-323-3500 (International)
1-800-535-5053 (North America)
Version 1
2.HAZARDS IDENTIFICATION
Appearance Clear blue liquid
Classification
Physical State Liquid Odor Citrus fragrance
Serious eye damage/eye irritation Category 2
Carcinogenicity Category 1B
Signal Word
Danger
Hazard Statements
Causes serious eye irritation
May cause cancer
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BE-5001 -Buckeye Blue Revision Date:19-Aug-2014
Precautionary Statements -Prevention
Obtain special instructions before use
Do not handle until all safety precautions have been read and understood
Use personal protective equipment as required
Wash face,hands and any exposed skin thoroughly after handling
Precautionary Statements -Response
If exposed or concerned:Get medical advice/attention
IF IN EYES:Rinse cautiously with water for several minutes.Remove contact lenses,if present and easy to do.Continue rinsing
If eye irritation persists:Get medical advice/attention
Precautionary Statements -Storage
Store locked up
Precautionary Statements -Disposal
Dispose of contents/container to an approved waste disposal plant
Other Hazards
Toxic to aquatic life with long lasting effects
3.COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No Weight-%
EDTA 60-00-4 <15
Sodium Nitrite 7632-00-0 <1
"IfChemical Name/CAS No is "proprietary"and/or Weight-%is listedas a range, the specific chemical identityand/or percentage
of composition has been withheld as a trade secret.**
First Aid Measures
General Advice
Eye Contact
Skin Contact
Inhalation
Ingestion
4.FIRST-AID MEASURES
Ifexposed or concerned:Get medical advice/attention.
IF IN EYES:Rinse cautiously with water for several minutes.Remove contact lenses,if
present and easy to do.Continue rinsing. Ifeye irritation persists:Get medical
advice/attention.
Wash off immediately with plenty of water for at least 15 minutes.Get medical attention if
irritation develops or persists.
Remove to fresh air.
Drink2-3 large glasses of water. Do not induce vomiting. Call a physician. Never give
anything by mouth to an unconscious person.
Most important symptoms and effects
Symptoms Causes serious eye irritation.Can cause defatting of skin tissue.
Indication ofany immediate medical attention and special treatment needed
Notes to Physician Treat symptomatically.
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BE-5001 -Buckeye Blue Revision Date:19-Aug-2014
5.FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable Extinguishing Media Not determined.
Specific Hazards Arising from the Chemical
Combustion products may be toxic.
Hazardous Combustion Products Carbon oxides. Nitrogen oxides (NOx).
Protective equipment and precautions for firefighters
As in any fire,wear self-contained breathing apparatus pressure-demand,MSHA/NIOSH (approved or equivalent)and full
protective gear.
6.ACCIDENTAL RELEASE MEASURES
Personal precautions,protective eguipment and emergency procedures
Personal Precautions Use personal protective equipment as required.
Environmental Precautions Prevent from entering into soil,ditches,sewers,waterways and/or groundwater.See
Section 12,Ecological Information.See Section 13:DISPOSAL CONSIDERATIONS.
Methods and material for containment and cleaning up
Methods for Containment Prevent further leakage or spillage ifsafe to do so.
Methods for Clean-Up Pick up with mop,wet/dry vac, or absorbent material.Rinse area with clear water and allow
floor to dry before allowing traffic.
Precautions for safe handling
Advice on Safe Handling
7.HANDLING AND STORAGE
Handle in accordance with good industrial hygiene and safety practice.Avoid contact with
skin,eyes or clothing.Use personal protection recommended in Section 8.Obtain special
instructions before use.Do not handle until all safety precautions have been read and
understood.Wash face,hands,and any exposed skin thoroughly after handling.
Conditions for safe storage,including any incompatibilities
Storage Conditions
Incompatible Materials
Exposure Guidelines
Keep container tightly closed and store in a cool, dry and well-ventilated place.Keep
container closed when not in use.Store at room temperature.Store locked up.
Chlorine bleach.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
Triethanolamine
102-71-6
TWA: 5 mg/m3 --
Phosphoric Acid
7664-38-2
STEL: 3 mg/m3
TWA:1 mg/m3
TWA: 1 mg/m3
(vacated)TWA:1 mg/m3
(vacated)STEL: 3 mg/m3
IDLH:1000 mg/m3
TWA:1 mg/m3
STEL: 3 mq/m3
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BE-5001 -Buckeye Blue Revision Date:19-Aug-2014
Appropriate engineering controls
Engineering Controls Ensure adequate ventilation,especially inconfined areas.Eyewash stations.Showers.
Individual protection measures,such as personal protective eguipment
Eye/Face Protection Splash goggles or safety glasses.
Skin and Body Protection Rubber gloves.Suitable protective clothing.
Respiratory Protection Ensure adequate ventilation,especially in confined areas.
General Hygiene Considerations Handle in accordance withgood industrial hygiene and safety practice.
9.PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical State Liquid
Appearance Clear blue liquid Odor Citrus fragrance
Color Clear blue Odor Threshold Not determined
Property Values Remarks •Method
PH 11.0-11.4 (cone.)
10.3-10.7 (1:16 dilution)
Melting Point/Freezing Point Not determined
Boiling Point/Boiling Range 100°C/212°F
Flash Point None Tag Closed Cup
Evaporation Rate 1.0 (Water = 1)
Flammability (Solid,Gas)Liquid-Not Applicable
Upper Flammability Limits Not Applicable
Lower Flammability Limit Not Applicable
Vapor Pressure Not determined
Vapor Density Not determined
Specific Gravity 1.04
Water Solubility Infinite
Solubility in other solvents Not determined
Partition Coefficient Not determined
Auto-ignition Temperature Not determined
Decomposition Temperature Not determined
Kinematic Viscosity Not determined
Dynamic Viscosity Not determined
Explosive Properties Not determined
Oxidizing Properties Not determined
10.STABILITY AND REACTIVITY
Reactivity
Not reactive under normal conditions.
Chemical Stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None under normal processing.
Hazardous Polymerization Hazardous polymerization does not occur.
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BE-5001 -Buckeye Blue
Conditions to Avoid
Keep separated from incompatible substances.Keep out of reach of children.
Incompatible Materials
Chlorine bleach.
Hazardous Decomposition Products
Carbon oxides.Nitrogen oxides (NOx).
11.TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Product Information
Revision Date:19-Aug-2014
Eye Contact
Skin Contact
Inhalation
Ingestion
Component Information
The information below is for repeated and prolonged contact in an occupational setting.It
does not apply to normal product use
Causes serious eye irritation.
Avoid contact with skin.
Avoid breathing vapors or mists.
Do not ingest.
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
EDTA
60-00-4
=1700mg/kg (Rat)--
Sodium Nitrite
7632-00-0
= 85 mg/kg (Rat)-=5.5mg/L (Rat)4 h
Triethanolamine
102-71-6
=4190mg/kg (Rat)>2000 mg/kg (Rabbit )>16
mL/kg (Rat)
-
Phosphoric Acid
7664-38-2
=1530 mg/kg (Rat)=2730 mg/kg (Rabbit)> 850 mg/m3 (Rat)1 h
Information on physical,chemical and toxicological effects
Symptoms Please see section 4 of this SDS for symptoms.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Carcinogenicity Nitrate or nitrite (ingested)under conditions that result in endogenous nitrosation are
considered IARC group 2A carcinogens.
Chemical Name ACGIH IARC NTP OSHA
Sodium Nitrite
7632-00-0
Group 2A X
Legend
IARC (International Agency for Research on Cancer)
Group2A - Probably Carcinogenic to Humans
OSHA (Occupational Safety and Health Administration ofthe US Department ofLabor)
X -Present
Numerical measures of toxicity
Not determined
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BE-5001 -Buckeye Blue Revision Date:19-Aug-2014
12.ECOLOGICAL INFORMATION
Ecotoxicity
Toxic to aquatic life with long lasting effects.
Component Information
Chemical Name Algae/aquatic plants Fish Toxicity to
microorganisms
Crustacea
EDTA
60-00-4
1.01:72 h Desmodesmus
subspicatus mg/L EC50
34 - 62: 96 h Lepomis
macrochirus mg/L LC50
static44.2 -76.5:96 h
Pimephales promelas mg/L
LC50 static
113:48 h Daphnia magna
mg/L EC50 Static
Sodium Nitrite
7632-00-0
0.19:96 h Oncorhynchus
mykiss mg/L LC50
flow-through 0.092 -0.13:96
h Oncorhynchus mykiss
mg/L LC50 flow-through 0.4 -
0.6: 96 h Oncorhynchus
mykiss mg/L LC50
semi-static 0.65 -1:96 h
Oncorhynchus mykiss mg/L
LC50 static 2.3:96 h
Pimephales promelas mg/L
LC50 flow-through 20:96 h
Pimephales promelas mg/L
LC50 static
Triethanolamine
102-71-6
216:72 h Desmodesmus
subspicatus mg/L EC50 169:
96 h Desmodesmus
subspicatus mg/L EC50
10600-13000:96 h
Pimephales promelas mg/L
LC50 flow-through 1000:96
h Pimephales promelas mg/L
LC50 static 450-1000:96 h
Lepomis macrochirus mg/L
LC50 static
1386:24 h Daphnia magna
mg/L EC50
Persistence/Degradability
Not determined.
Bioaccumulation
Not determined.
Mobility
Chemical Name Partition Coefficient
Sodium Nitrite
7632-00-0
-3.7
Other Adverse Effects
Not determined
Waste Treatment Methods
Disposal of Wastes
Contaminated Packaging
13.DISPOSAL CONSIDERATIONS
Disposal should be in accordance with applicable regional,national and local laws and
regulations.
Disposal should be in accordance with applicable regional,national and local laws and
regulations.
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BE-5001 -Buckeye Blue Revision Date:19-Aug-2014
US EPA Waste Number
Chemical Name RCRA RCRA-Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes
Octylphenozypolyethoxyetha
nol
9036-19-5
Included in waste stream:
K060
California Hazardous Waste Status
Chemical Name California Hazardous Waste Status
Sodium Nitrite
7632-00-0
Toxic
Ignitable
Reactive
Note
DOT
IATA
IMDG
International Inventories
TSCA
14.TRANSPORT INFORMATION
Please see current shipping paper for most up to date shipping information,including
exemptions and special circumstances.
Not regulated
Not regulated
Not regulated
15.REGULATORY INFORMATION
Listed
Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
US Federal Regulations
CERCLA
Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ)
EDTA
60-00-4
5000 lb RQ 5000 lb final RQ
RQ 2270 kq final RQ
Sodium Nitrite
7632-00-0
1001b RQ 100 lb final RQ
RQ 45.4 kg final RQ
SARA 313
Chemical Name CAS No Weight-%SARA 313-Threshold
Values %
Sodium Nitrite -7632-00-0 7632-00-0 <1 1.0
CWA (Clean Water Act)
Component CWA -Reportable
Quantities
CWA -Toxic Pollutants CWA -Priority Pollutants CWA -Hazardous
Substances
EDTA
60-00-4 (<15)
5000 lb X
Sodium Nitrite
7632-00-0 ( <1 )
100 1b X
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BE-5001 -Buckeye Blue
US State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals.
U.S.State Right-to-Know Regulations
Revision Date:19-Aug-2014
Chemical Name New Jersey Massachusetts Pennsylvania
EDTA
60-00-4
X X X
Sodium Nitrite
7632-00-0
X X X
Triethanolamine
102-71-6
X x X
Phosphoric Acid
7664-38-2
x x X
16.OTHER INFORMATION
NFPA
HMIS
Issue Date:
Revision Date:
Revision Note:
Health Hazards
1
Health Hazards
Not determined
Flammability
0
Flammability
Not determined
27-Dec-2011
19-Aug-2014
New format
Instability
0
Physical Hazards
Not determined
Special Hazards
Not determined
Personal Protection
Not determined
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge,information and belief at the
date of its publication.The information given is designed only as a guidance for safe handling,use,processing,storage,
transportation,disposal and release and is not to be considered a warranty or quality specification.The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process,unless specified in the text.
End of Safety Data Sheet
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