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HomeMy WebLinkAbout64014 SSS ALERO 3000 MICRO METERED DRY AIR FRESHENER, WHITE LINENTRIPLE S 1.Identification Product number Product identifier Revision date Company information Company phone Version # Supersedes date Recommended use Recommended restrictions 2.Hazard(s)identification Physical hazards Health hazards Environmental hazards OSHA defined hazards Label elements Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal Hazard(s)not otherwise classified (HNOC) Supplemental information SAFETY DATA SHEET 64014(1000023615) SSS ALERO 3000 MICRO METERED DRY AIR FRESHENER,WHITE LINEN 03-06-2015 Triple S 2 Executive Park Drive, Billerica,MA 01862 United States General 978-667-7900 /Emergency 888-779-1339 03 03-05-2015 Air Freshener None known. Flammable aerosols Category 1 Serious eye damage/eye irritation Category 2A Specific target organ toxicity,single exposure Category 3 narcotic effects Not classified. Not classified. <M> Danger Extremelyflammableaerosol.Causes serious eye irritation.Maycause drowsiness or dizziness. Keep away from heat/sparks/open flames/hot surfaces.- No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Donot pierce or burn, even after use.Avoid breathinggas. Wash thoroughly after handling.Use onlyoutdoors or ina well-ventilated area. Weareye/face protection. Ifinhaled: Remove person to fresh air and keep comfortable for breathing. Ifin eyes:Rinse cautiously withwater forseveral minutes. Remove contact lenses,ifpresent and easyto do. Continue rinsing.Calla poisoncenter/doctor ifyoufeel unwell.Ifeye irritation persists: Get medical advice/attention. Store in a well-ventilated place. Keep containertightly closed.Store locked up.Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. Dispose ofcontents/container inaccordance withlocal/regional/national/international regulations. None known. None. 3.Composition/information on ingredients Mixtures Chemical name Common name and synonyms CAS number Acetone 67-64-1 40-60 Propane 74-98-6 20-40 Diethylene Glycol Monoethyl Ether 111-90-0 10-20 Othercomponents below reportable levels 10-20 Product name:64014 SSS ALERO MICRO WHITE LINEN Product#:1000023615 Version #:03 Revision date:03-06-2015 Issue date:12-05-2014 SOS us 1/9 'Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4.First-aid measures Inhalation Skin contact Eye contact Ingestion Most important symptoms/effects,acute and delayed Indication of immediate medical attention and special treatment needed General information 5.Fire-fighting measures Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire-fighting equipment/instructions Specific methods General fire hazards Remove victimto fresh air and keep at rest ina position comfortable for breathing. Call a POISON CENTER or doctor/physician ifyou feel unwell. Wash offwith soap and water. Get medical attention ifirritation develops and persists. Rinse with water.Getmedical attention ifirritation develops and persists. Rinse mouth.Get medical attention ifsymptoms occur. May cause drowsiness and dizziness.Headache.Nausea,vomiting. Irritationof nose and throat. Severe eye irritation.Symptoms may include stinging,tearing,redness,swelling,and blurred vision. Provide general supportive measures and treat symptomatically. Keep victim underobservation. Symptoms may be delayed. Ensure that medical personnel are aware of the material(s)involved,and take precautions to protect themselves. Powder.Alcohol resistant foam.Waterspray.Carbon dioxide (C02). Do not use water jet as an extinguisher,as this willspread the fire. Contents under pressure.Pressurized container may explode when exposed to heator flame. Firefighters must use standard protective equipment including flame retardant coat,helmet with face shield,gloves,rubber boots,and in enclosed spaces,SCBA. Move containers from fire area ifyou can do so without risk.Containers should be cooled with water to prevent vapor pressure build up.For massive fire in cargo area,use unmanned hose holder or monitor nozzles,ifpossible.Ifnot,withdraw and let fire burn out. Use standard firefighting procedures and considerthe hazards of other involved materials.Move containers from fire area ifyou can do so without risk.Use waterspray to cool unopened containers.In the event of fire and/or explosion do not breathe fumes. Extremely flammable aerosol. 6.Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Environmental precautions 7.Handling and storage Precautions for safe handling Keep unnecessary personnel away.Keep people away from and upwind of spill/leak.Keep out of low areas.Wear appropriate protective equipment and clothing during clean-up.Avoid breathing gas.Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.Ventilate closed spaces before entering them.Local authorities should be advised if significant spillages cannot be contained.For personal protection,see section 8 of the SDS. Referto attached safety data sheetsand/or instructions for use.Eliminate all ignition sources (no smoking,flares,sparks,or flames in immediate area).Keep combustibles (wood,paper,oil,etc.) awayfrom spilled material.Stop leak ifyou can do so without risk. Move the cylinder to a safe and open area ifthe leak is irreparable.Use water spray to reduce vapors or divert vapor cloud drift. Isolate area until gas hasdispersed.Prevententry into waterways,sewer,basements or confined areas.Following product recovery,flush area with water.Forwaste disposal,see section 13 of the SDS. Avoid release to the environment.Inform appropriate managerial or supervisory personnel of all environmental releases.Prevent further leakage or spillage ifsafe to do so. Avoid discharge into drains,water courses or onto the ground. Pressurized container Do not pierce or burn,even after use.Do not use ifspray button is missing or defective.Do not spray on a naked flame or any other incandescent material.Do notsmoke while using or until sprayed surface is thoroughly dry. Do not cut,weld,solder,drill, grind,or expose containers to heat,flame,sparks,or other sources of ignition. Allequipment used when handling the product mustbe grounded.Do not re-use empty containers.Avoid breathing gas. Avoid contactwith eyes.Avoid prolonged exposure.Use only in well-ventilated areas.Wear appropriate personal protective equipment.Avoid release to the environment.Observe good industrial hygiene practices. Product name:64014 SSS ALERO MICRO WHITE LINEN Products 1000023615 Version #:03 Revision date:03-06-2015 Issue date:12-05-2014 SDS US 2/9 Conditions for safe storage, including any incompatibilities Level 2 Aerosol. Store locked up.Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 °F. Donotpuncture, incinerate or crush. Donot handle or store near an open flame,heator other sources of ignition.This material can accumulate static charge which may cause spark and become an ignitionsource.Refrigeration recommended.Store away from incompatible materials (see Section 10 of the SDS). 8.Exposure controls/personal protection Occupational exposure limits US.OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Acetone (CAS 67-64-1)PEL Propane (CAS 74-98-6)PEL US.ACGIH Threshold Limit Values Components Type Acetone (CAS 67-64-1)STEL TWA US.NIOSH:Pocket Guide to Chemical Hazards Components Type Acetone (CAS 67-64-1) Propane (CAS 74-98-6) TWA TWA US.Workplace Environmental Exposure Level (WEEL)Guides Components Type TWA Value 2400 mg/m3 1000 ppm 1800mg/m3 1000 ppm Value 750 ppm 500 ppm Value 590 mg/m3 250 ppm 1800 mg/m3 1000 ppm Value 140 mg/m3 25 ppm Diethylene Glycol Monoethyl Ether (CAS 111-90-0) Biological limit values ACGIH Biological Exposure Indices Components Value Determinant Specimen Sampling Time Acetone (CAS 67-64-1)50mg/l Acetone Urine * *- For sampling details,please seethe source document. Appropriate engineering Good general ventilation (typically 10 air changes per hour)should be used.Ventilation rates controls should be matched to conditions.Ifapplicable,use process enclosures,local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established,maintain airborne levels to an acceptable level.Provide eyewash station. Individual protection measures,such as personal protective equipment Eye/face protection Wear safety glasses withside shields (or goggles). Hand protection Skin protection Other Respiratory protection Thermal hazards General hygiene considerations Wear appropriate chemical resistant gloves. Wearsuitable protective clothing. Ifpermissible levels are exceeded use NIOSH mechanical filter /organic vapor cartridge or an air-supplied respirator. Wear appropriate thermal protective clothing,when necessary. When using do not smoke.Always observe good personal hygiene measures,such as washing after handling the material and before eating,drinking,and/orsmoking.Routinely wash work clothing and protective equipment to remove contaminants. 9.Physical and chemical properties Appearance Product name:64014 SSS ALERO MICRO WHITE LINEN Product#:1000023615 Version #:03 Revision date:03-06-2015 Issue date:12-05-2014 sosus 3/9 Physical state Odor Odor threshold PH Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid,gas) Gas.Form Aerosol.Color Not available. Not available. Not available. Not available. Not available. 132.89 °F (56.05 °C)estimated -156.0 °F (-104.4 °C)propellant estimated Not available. Not available. Upper/lowerflammability or explosive limits Flammability limit -lower (%) Flammability limit (%) Explosive limit Explosive limit Vapor pressure Vapor density Relative density Solubility(ies) Solubility (water) Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity Other information Specific gravity 10.Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products 1.6%estimated upper 14.5%estimated lower (%) upper (%) Not available. Not available. 258.6 psig @70F estimated Not available. Not available. Not available. Not available. Not available. Not available. Not available. 0.682 estimated The product is stable and non-reactive under normal conditions of use,storage and transport. Material is stable under normal conditions. Hazardous polymerization does not occur. Avoid temperatures exceeding the flash point.Contact with incompatible materials. Strong oxidizing agents. No hazardous decomposition products are known. 11.Toxicological information Information on likely routes of exposure Ingestion Inhalation Skin contact Eye contact Symptoms related to the physical,chemical and toxicological characteristics Information on toxicological effects Expected to be a low ingestion hazard. May causedrowsiness and dizziness.Headache.Nausea,vomiting.Prolonged inhalation may be harmful. No adverse effects due to skin contact are expected. Causes serious eye irritation. May cause drowsiness and dizziness.Headache.Nausea,vomiting. Irritation of nose and throat. Severe eye irritation.Symptoms may include stinging,tearing,redness,swelling,and blurred vision. Product name:64014 SSSALERO MICRO WHITE LINEN Product #:1000023615 Version #:03 Revision date:03-06-2015 Issue date:12-05-2014 SDSUS 4/9 Acute toxicity Narcotic effects. Components Species Acetone (CAS 67-64-1) Acute Dermal LD50 Guinea pig Rabbit Inhalation LC50 Oral LD50 Rat Rat Diethylene Glycol Monoethyl Ether (CAS 111-90-0) Acute Dermal LD50 Guinea pig Rabbit Oral LD50 Guinea pig Mouse Rabbit Rat Propane (CAS 74-98-6) Acute Inhalation LC50 Mouse Rat Estimates for product may be based on additional component data not shown. Test Results >7426 mg/kg,24 Hours >9.4 ml/kg,24 Hours >7426 mg/kg,24 Hours >9.4 ml/kg,24 Hours 55700 ppm,3 Hours 132mg/l,3 Hours 50.1 mg/l 5800 mg/kg 2.2 ml/kg 5900 mg/kg,Days 8500 mg/kg, 2 Hours 8476 mg/kg, 24 Hours 7714 mg/kg 4970 mg/kg 6031 mg/kg 5600 mg/kg 5600 mg/kg 5.4 ml/kg 1237 mg/l,120 Minutes 52 %,120 Minutes 1355 mg/l 658 mg/l/4h Skin corrosion/irritation Serious eye damage/eye irritation Prolonged skin contactmay cause temporary irritation. Causesserious eye irritation. Respiratory or skin sensitization Respiratory sensitization Skin sensitization Germ cell mutagenicity Not available. This product is not expected to cause skin sensitization. No data available to indicate product or any components present at greaterthan 0.1%are mutagenicor genotoxic. Carcinogenicity Thisproductisnotconsideredtobe a carcinogen byIARC,ACGIH,NTP,or OSHA. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity This product is notexpected to cause reproductiveor developmental effects. Product name:64014 SSS ALERO MICRO WHITE LINEN Product#:1000023615 Version #:03 Revision date:03-06-2015 Issue date:12-05-2014 sosus 5/9 Specific target organ toxicity - May cause drowsiness and dizziness, single exposure Specifictarget organ toxicity - Not classified, repeated exposure Aspiration hazard Not likely,due to the form ofthe product. Chronic effects Prolonged inhalation may be harmful. 12.Ecological information Ecotoxicity Toxicto aquatic lifewithlong lastingeffects. Components Species Test Results Acetone (CAS 67-64-1) Aquatic Crustacea EC50 Waterflea (Daphnia magna)21.6-23.9 mg/l, 48 hours Fish LC50 Rainbow troutdonaldson trout 4740 -6330 mg/l, 96 hours (Oncorhynchus mykiss) Diethylene Glycol Monoethyl Ether (CAS 111-90-0) Aquatic Fish LC50 Bluegill (Lepomis macrochirus)>10000mg/l, 96 hours *Estimates for product may be based on additional component data not shown. Persistence and degradability No data is available on the degradability ofthis product. Bioaccumulative potential No data available. Partition coefficient n-octanol /water (log Kow) Acetone -0.24 Diethylene Glycol Monoethyl Ether -0.54 Propane 2.36 Mobility in soil No data available. Other adverse effects No otheradverse environmental effects (e.g.ozone depletion,photochemical ozone creation potential,endocrine disruption,global warming potential)are expected from this component. 13.Disposal considerations Disposalinstructions Collect and reclaim or dispose insealed containers at licensed waste disposal site.Contents under pressure.Do not puncture,incinerate or crush.Do not allow this material to drain into sewers/watersupplies.Do not contaminate ponds,waterways or ditches with chemical or used container.Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations Dispose in accordance withall applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user,the producer and the waste disposal company. US RCRA Hazardous Waste U List:Reference Acetone (CAS 67-64-1)U002 Waste from residues /unused Dispose of in accordance with local regulations.Empty containers or liners may retain some products product residues.This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue,follow label warnings even after container is emptied.Do not re-use empty containers. 14.Transport information DOT UN number UN1950 UN proper shipping name Aerosols,flami Transport hazard class(es) Class 2.1 Subsidiary risk - Label(s)2.1 Packing group Not applicable. Product name:64014 SSS ALERO MICRO WHITE LINEN sds us Product#:1000023615 Version #: 03 Revision date:03-06-2015 Issue date:12-05-2014 6 / 9 Special precautions for user Read safety instructions, SDS and emergency procedures before handling.Read safety instructions,SDS and emergency procedures before handling. Special provisions N82 Packaging exceptions 306 Packaging non bulk None Packaging bulk None This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity. Until 12/31/2020,the "Consumer Commodity -ORM-D"marking may stillbe used in place of the new limited quantity diamond mark for packages of UN 1950Aerosols.Limited quantities require the limited quantity diamond mark on cartons after12/31/20 and may be used now in place of the "Consumer Commodity ORM-D"marking and both may be displayed concurrently. IATA Read safety instructions,SDS and emergency procedures before handling.Read safety UN number UN1950 UNproper shipping name Aerosols,flammable Transport hazard class(es) Class 2.1 Subsidiary risk - Label(s)Packing 2.1 group Environmental Not applicable. hazards ERG Code Yes 10L Special precautions for user Read safety instructk instructions,SDS am Other information Passenger and cargo Allowed. aircraft Cargo aircraftonly Allowed. Packaging Exceptions LTDQTY IMDG UN number UN1950 UN proper shipping name AEROSOLS Transport hazard class(es) Class 2.1 Subsidiary risk - Label(s)Packing 2.1 group Environmental Not applicable. hazards Marine pollutant Yes EmS F-D,S-U Special precautions for user Readsafetyinstructions,SDS andemergency procedures before handling.Readsafety instructions,SDS and emergency procedures before handling. LTDQTY Not applicable. Packaging Exceptions Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code DOT A FLAMMABLE v GAS / Product name:64014 SSS ALERO MICRO WHITE LINEN Product #:1000023615 Version #:03 Revision date:03-06-2015 Issue date:12-05-2014 SDS US 7/9 IATA;IMDG Marine pollutant General information IMDG Regulated Marine Pollutant. 15.Regulatory information US federal regulations This product is a "Hazardous Chemical"as defined by the OSHA Hazard Communication Standard,29 CFR 1910.1200. Allcomponents are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b)Export Notification (40 CFR 707,Subpt.D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Acetone (CAS 67-64-1)Listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard -Yes Delayed Hazard - No Fire Hazard -Yes Pressure Hazard -No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous No chemical SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA)Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA)Section 112(r)Accidental Release Prevention (40 CFR 68.130) Propane (CAS 74-98-6) Safe Drinking Water Act Not regulated. (SDWA) Drug EnforcementAdministration (DEA). List 2,Essential Chemicals (21 CFR 1310.02(b)and 1310.04(0(2)and Chemical Code Number Acetone (CAS 67-64-1)6532 Product name:64014 SSS ALERO MICRO WHITE LINEN SDS us Product #:1000023615 Version #:03 Revision date:03-06-2015 Issue date:12-05-2014 8 / 9 Drug EnforcementAdministration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) Acetone (CAS 67-64-1)35 %WV DEA Exempt Chemical Mixtures Code Number Acetone (CAS 67-64-1)6532 US state regulations US.Massachusetts RTK -Substance List Acetone (CAS 67-64-1) Propane (CAS 74-98-6) US. New Jersey Worker and Community Right-to-Know Act Acetone (CAS 67-64-1) Propane (CAS 74-98-6) US.Pennsylvania Worker and Community Right-to-Know Law Acetone (CAS 67-64-1) Propane (CAS 74-98-6) US.Rhode Island RTK Acetone (CAS 67-64-1) Propane (CAS 74-98-6) US.California Proposition 65 California Safe Drinking WaterandToxic Enforcement Act of1986(Proposition 65):Thismaterial isnotknown tocontain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Inventoryname On inventory (yes/no)* Australian Inventory of Chemical Substances (AICS)Yes DomesticSubstances List (DSL)Yes Non-Domestic Substances List (NDSL)No Inventory ofExisting Chemical Substancesin China (IECSC)Yes European Inventory ofExisting Commercial Chemical Yes Substances (EINECS) European List ofNotified Chemical Substances (ELINCS)No Inventory ofExisting and New Chemical Substances (ENCS)Yes Existing Chemicals List (ECL)No New Zealand Inventory No Philippine Inventory ofChemicals and Chemical Substances No (PICCS) United States &Puerto Rico ToxicSubstances ControlAct (TSCA)Inventory Yes *A "Yes"indicates thatallcomponentsofthisproduct comply with the inventory requirements administered bythe governing country(s) A"No"indicatesthat one ormorecomponentsofthe productare notlistedorexemptfrom listing on the inventory administeredbythe governing country(s). 16. Other information,including date of preparation or last revision Issue date 12-05-2014 Revision date 03-06-2015 Version #03 Country(s)or region Australia Canada Canada China Europe Europe Japan Korea New Zealand Philippines Disclaimer Revision Information The informationprovided inthis Safety Data Sheet is correct to the best ofour knowledge, informationand beliefat the date of its publication. The information given is designed only as a guidance forsafe handling,use, processing, storage, transportation, disposal and release and is not to be considered a warranty or qualityspecification. The information relates onlyto the specific material designated and may notbe validforsuch material used in combinationwithany other materials or in any process,unless specified inthe text. GHS:Classification Product name:64014 SSS ALERO MICROWHITE LINEN Product#:1000023615 Version #:03 Revision date:03-06-2015 Issue date:12-05-2014 SDSUS 9/9