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HomeMy WebLinkAbout64007 SSS Alero 3000 Metered Dry Air Freshener, White LinenTRIPLE S 1.Identification Product number Product identifier Revision date Company information Company phone Version # Supersedes date Recommended use Recommended restrictions 2.Hazard(s)identification Physical hazards Health hazards Environmental hazards OSHA defined hazards Label elements Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal Hazard(s)not otherwise classified (HNOC) Supplemental information SAFETY DATA SHEET 64007 (1000023633) SSS ALERO 3000 METERED DRY AIR FRESHENER,WHITE LINEN 03-06-2015 Triple S 2 Executive Park Drive, Billerica,MA 01862 United States General 978-667-7900 /Emergency 888-779-1339 03 03-05-2015 Air Freshener None known. Flammable aerosols Category 1 Serious eye damage/eye irritation Category 2A Specific target organ toxicity,single exposure NQbtegory 3 narcotic effects classified. Not classified. ^> Danger Extremely flammable aerosol.Causes serious eye irritation.May cause drowsiness or dizziness. Keep away from heat/sparks/open flames/hot surfaces.- No smoking. Do not sprayon an open flame or other ignitionsource.Pressurized container: Do not pierce or burn,even after use. Avoid breathing mistor vapor. Wash thoroughlyafter handling. Use onlyoutdoors or ina well-ventilated area.Weareye/face protection. Ifinhaled: Remove person to fresh air and keep comfortable for breathing.Ifin eyes:Rinse cautiously with waterfor several minutes.Remove contact lenses,ifpresentand easy to do. Continue rinsing. Calla poison center/doctor ifyou feel unwell. Ifeye irritation persists:Get medical advice/attention.Collectspillage. Store in a well-ventilated place. Keep container tightlyclosed.Store locked up.Protectfrom sunlight. Do not expose to temperatures exceeding 50°C/122°F. Dispose of contents/container in accordance with local/regional/national/international regulations. None known. None. 3.Composition/information on ingredients Mixtures Chemical name Common name and synonyms CAS number % Acetone 67-64-1 40-60 Diethylene Glycol Monoethyl Ether 111-90-0 10-20 Propane 74-98-6 10-20 Product name:64007 SSS ALERO 3000 WHITE LINEN Product#:1000023633 Version #:02 Revision date:03-27-2015 Issue date:12-05-2014 SDSUS 1/10 Chemical name Common name and synonyms CAS number Isobutane 75-28-5 2.5-10 Other components below reportable levels 2.5 'Designates that a specific chemical identityand/or percentage of composition has been withheld as a trade secret 10 4.First-aid measures Inhalation Skin contact Eye contact Ingestion Most important symptoms/effects,acute and delayed Indication of immediate medical attention and special treatment needed General information 5.Fire-fighting measures Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire-fighting equipment/instructions Specific methods General fire hazards Remove victimto fresh air and keep at rest in a position comfortable for breathing.Call a POISON CENTER or doctor/physician ifyou feel unwell. Wash off with soap and water.Get medical attention ifirritation develops and persists. Immediately flush eyeswith plenty of waterfor at least 15 minutes.Remove contact lenses,if present and easy to do.Continue rinsing.Ifeye irritation persists:Get medical advice/attention. In the unlikely eventof swallowing contact a physician or poison control center.Rinse mouth. May cause drowsiness and dizziness.Headache.Nausea,vomiting. Irritationof nose and throat. Severe eye irritation.Symptoms may include stinging, tearing,redness,swelling, and blurred vision. Provide general supportive measures and treat symptomatically.Keep victim under observation. Symptoms may be delayed. Ensure that medical personnel are aware of the material(s)involved,and take precautions to protectthemselves. Alcohol resistant foam.Water fog. Dry chemical powder.Carbon dioxide (C02). Do not use water jet as an extinguisher,as this willspread the fire. Contents under pressure.Pressurized container may explode when exposed to heat or flame. Firefighters must use standard protective equipment including flame retardant coat,helmetwith face shield,gloves,rubber boots,and in enclosed spaces,SCBA. Move containers from fire area ifyou can do so without risk.Containers should be cooled with waterto prevent vapor pressure build up. For massive fire in cargo area,use unmanned hose holder or monitor nozzles,if possible.Ifnot,withdraw and let fire burn out. Use standard firefighting procedures and considerthe hazards of other involved materials.Move containers from fire area ifyou can do sowithout risk. In the eventof fire and/or explosion do not breathe fumes. Extremely flammable aerosol. 6.Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containmentand cleaning up Environmental precautions Keep unnecessary personnel away.Keep people away from and upwind of spill/leak.Keep out of low areas.Wear appropriate protective equipmentand clothing during clean-up.Avoid breathing mist or vapor.Do not touch damaged containers or spilled material unlesswearing appropriate protective clothing.Ventilate closed spaces before entering them.Local authorities should be advised if significant spillages cannotbe contained.For personal protection,see section 8 of the SDS. Referto attached safety data sheets and/or instructions for use.Eliminate all ignition sources (no smoking,flares,sparks,or flames in immediate area).Keep combustibles (wood,paper,oil,etc.) awayfrom spilled material.Stop leak ifyou can do so without risk. Move the cylinder to a safe and open area ifthe leak is irreparable.Use water spray to reduce vapors or divert vapor cloud drift. Coverwith plastic sheetto prevent spreading.Absorb in vermiculite,dry sand or earth and place into containers.Prevent entry into waterways,sewer,basements or confined areas.Following product recovery,flush area with water. Small Spills:Wipe up with absorbent material (e.g.cloth,fleece).Clean surface thoroughly to remove residual contamination.Forwaste disposal,see section 13 of the SDS. Avoid release to the environment.Informappropriate managerial or supervisory personnel of all environmental releases.Prevent further leakage or spillage ifsafe to do so. Avoid discharge into drains,watercourses or onto the ground. Product name:64007 SSSALERO 3000WHITE LINEN Product#:1000023633 Version #:02 Revision date:03-27-2015 Issue date:12-05-2014 SDSUS 2/10 7.Handling and storage Precautions for safe handling Conditions for safe storage, including any incompatibilities Pressurized container Do not pierce or burn,even after use.Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld,solder,drill,grind, or expose containers to heat,flame,sparks,or othersources of ignition. Allequipment used when handling the product must be grounded.Do not re-use empty containers.Avoid breathing mist or vapor.Avoid contact with eyes.Avoid prolonged exposure.Use only in well-ventilated areas.Wear appropriate personal protective equipment.Avoid release to the environment.Observe good industrial hygiene practices. Level 2 Aerosol. Store locked up.Pressurized container.Protect from sunlight and do not expose to temperatures exceeding 50°C/122 °F. Do not puncture,incinerate or crush.Do not handle or store near an open flame,heator othersources of ignition. This material can accumulate static charge which may cause spark and become an ignition source.Refrigeration recommended.Store away from incompatible materials (see Section 10 of the SDS). 8.Exposure controls/personal protection Occupational exposure limits US.OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Acetone (CAS 67-64-1)PEL Propane (CAS 74-98-6)PEL US.ACGIH Threshold LimitValues Components Type Acetone (CAS 67-64-1)STEL TWA Isobutane (CAS 75-28-5)STEL US.NIOSH:Pocket Guide to Chemical Hazards Components Type Acetone (CAS 67-64-1) Isobutane (CAS 75-28-5) Propane (CAS 74-98-6) TWA TWA TWA US.Workplace Environmental Exposure Level (WEEL)Guides Components Type Value 2400 mg/m3 1000 ppm 1800mg/m3 1000 ppm Value 750 ppm 500 ppm 1000 ppm Value 590 mg/m3 250 ppm 1900mg/m3 800 ppm 1800 mg/m3 1000 ppm Value Diethylene Glycol Monoethyl Ether (CAS 111-90-0) Biological limit values ACGIH Biological Exposure Indices Components Value TWA 140 mg/m3 25 ppm Determinant Specimen Sampling Time Acetone (CAS 67-64-1)50 mg/l Acetone Urine * *- For sampling details,please see the source document Appropriate engineering Good general ventilation(typically 10 air changes per hour) should be used. Ventilationrates controls should be matched to conditions.If applicable,use process enclosures,local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limitshave not been established,maintain airborne levels to an acceptable level. Provide eyewash station. Individual protection measures,such as personal protective equipment Eye/face protection Chemical respirator with organic vapor cartridge and fullfacepiece. Hand protection Wear appropriate chemical resistant gloves. Product name:64007 SSS ALERO 3000 WHITE LINEN Product #:1000023633 Version #:02 Revision date:03-27-2015 Issue date:12-05-2014 SDSUS 3/10 Skin protection Other Respiratory protection Thermal hazards General hygiene considerations Wear suitable protective clothing. Chemical respirator with organic vapor cartridge and fullfacepiece. Wear appropriate thermal protective clothing,when necessary. When using do not smoke. Alwaysobserve good personal hygiene measures,such as washing after handling the material and before eating, drinking,and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9.Physical and chemical properties Appearance Physical state Form Color Odor Odor threshold PH Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid,gas) Upper/lower flammability orexplosive limits Flammability limit -lower 1.6%estimated (%) Flammability limit -upper (%) Explosive limit -lower (%) Explosive limit -upper(%) Vapor pressure Vapor density Relative density Solubility(ies) Solubility (water) Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity Other information Specific gravity Gas. Aerosol. Not available. Not available. Notavailable. Notavailable. Not available. 132.89 °F (56.05 °C)estimated -3.8 °F (-19.9 °C)estimated Not available. Not available. 14.5%estimated Not available. Not available. 270.47 psig @70F estimated Not available. Not available. Not available. Not available. Not available. Not available. Not available. 0.314 estimated 10.Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products The product is stable and non-reactive under normal conditions of use,storage and transport. Material is stable under normal conditions. Hazardous polymerization does not occur. Avoid temperatures exceeding the flash point.Contactwith incompatible materials. Strong oxidizing agents.Nitrates. Fluorine. Chlorine. No hazardous decomposition products are known. Product name:64007 SSSALERO 3000WHITE LINEN Product#:1000023633 Version #:02 Revision date:03-27-2015 Issue date:12-05-2014 SOSus 4/10 11.Toxicological information Information on likely routes of exposure Ingestion Inhalation Skin contact Eye contact Symptoms related to the physical,chemical and toxicological characteristics Expected to be a low ingestion hazard. May cause drowsiness and dizziness.Headache.Nausea,vomiting.Prolonged inhalation may be harmful. No adverse effects due to skin contact are expected. Causes serious eye irritation. May cause drowsiness and dizziness.Headache.Nausea,vomiting. Irritationof nose and throat. Severe eye irritation.Symptoms may include stinging, tearing,redness,swelling, and blurred vision. Information on toxicological effects Acutetoxicity Narcotic effects. Components Species Acetone (CAS 67-64-1) Acute Dermal LD50 Guinea pig Rabbit Inhalation LC50 Oral LD50 Rat Rat Diethylene Glycol Monoethyl Ether (CAS 111-90-0) Acute Dermal LD50 Guinea pig Rabbit Oral LD50 Guinea pig Mouse Rabbit Rat Isobutane (CAS 75-28-5) Acute Inhalation LC50 Mouse Rat Product name:64007 SSS ALERO 3000 WHITE LINEN Product #:1000023633 Version #:02 Revision date:03-27-2015 Issue date:12-05-2014 Test Results >7426 mg/kg,24 Hours >9.4 ml/kg, 24 Hours >7426 mg/kg,24 Hours >9.4 ml/kg,24 Hours 55700 ppm,3 Hours 132mg/l,3 Hours 50.1 mg/l 5800 mg/kg 2.2 ml/kg 5900 mg/kg,Days 8500 mg/kg, 2 Hours 8476 mg/kg,24 Hours 7714 mg/kg 4970 mg/kg 6031 mg/kg 5600 mg/kg 5600 mg/kg 5.4 ml/kg 1237 mg/l,120 Minutes 52%,120 Minutes 1355 mg/l SDS US 5/10 Components Propane (CAS 74-98-6) Acute Inhalation LC50 Species Mouse Rat Test Results 1237 mg/l,120 Minutes 52%,120 Minutes 1355 mg/l 658 mg/l/4h *Estimates for product may be Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Skin sensitization Germ cell mutagenicity Carcinogenicity OSHA Specifically Regulated Not listed. Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Chronic effects 12.Ecological information Ecotoxicity Components based on additional component data not shown. Prolonged skin contactmay cause temporary irritation. Causes serious eye irritation. Not available. This product is not expected to cause skin sensitization. No data available to indicate productor any components present at greater than 0.1%are mutagenic or genotoxic. This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. Substances (29 CFR 1910.1001-1050) This product is not expected to cause reproductive or developmental effects. May cause drowsiness and dizziness. Not classified. Not available. Prolonged inhalation may be harmful. Toxic to aquaticlifewith long lasting effects. Species Acetone (CAS 67-64-1) Aquatic Crustacea EC50 Water flea (Daphnia magna) Fish LC50 Rainbow troutdonaldson trout (Oncorhynchus mykiss) Diethylene Glycol Monoethyl Ether(CAS 111-90-0) Aquatic Fish LC50 Bluegill (Lepomis macrochirus) Test Results 21.6-23.9 mg/l,48 hours 4740 -6330 mg/l, 96 hours 10000 mg/l, 96 hours *Estimates for product may be based on additional componentdata not shown. Persistence and degradability No data is available on thedegradability of this product. Bioaccumulative potential No data available. Partition coefficient n-octanol /water (log Kow) Acetone -0.24 Diethylene Glycol Monoethyl Ether -0.54 Isobutane 2.76 Propane 2.36 Mobility in soil No data available. Otheradverse effects No other adverse environmental effects (e.g.ozone depletion,photochemical ozone creation potential,endocrine disruption,global warming potential)are expected from this component. Product name:64007 SSS ALERO 3000 WHITE LINEN Product#:1000023633 Version #:02 Revision date:03-27-2015 Issuedate:12-05-2014 SDS US 6/10 13.Disposal considerations Disposal instructions Collectand reclaim ordispose insealed containersat licensedwaste disposal site. Contents under pressure.Donot puncture, incinerate or crush. Donot allowthis materialto drain into sewers/watersupplies. Donotcontaminate ponds, waterways or ditches withchemical or used container. Dispose ofcontents/container in accordance with local/regional/national/international regulations. Dispose in accordance with all applicable regulations. The waste code should be assigned indiscussion between the user, the producer and the waste disposal company. US RCRA Hazardous Waste U List:Reference Local disposal regulations Hazardous waste code Acetone (CAS 67-64-1) Waste from residues /unused products Contaminated packaging 14.Transport information DOT UN number UN propershipping name Transport hazard class(es) Class Subsidiary risk Label(s) Packing group UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Label(s) Packing group Environmental hazards ERG Code U002 Dispose of in accordance withlocal regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of ina safe manner (see: Disposal instructions). Emptycontainers should be taken to an approved waste handlingsite for recyclingor disposal. Since emptied containers may retain product residue,follow labelwarnings even after container is emptied.Do not re-use empty containers. UN1950 Aerosols,flammable,(each not exceeding 1 L capacity) 2.1 2.1 Not applicable. Special precautionsforuser Readsafetyinstructions,SDSand emergency procedures beforehandling.Readsafety instructions,SDS and emergency procedures before handling. Special provisions N82 Packaging exceptions 306 Packaging non bulk None Packaging bulk None This product meetsthe exception requirements ofsection 173.306 as a limited quantity and maybe shippedas a limited quantity. Until 12/31/2020,the "ConsumerCommodity -ORM-D"marking may still be used inplace ofthe new limited quantitydiamond mark for packagesofUN 1950Aerosols.Limited quantities require the limited quantity diamond mark oncartonsafter12/31/20 andmay beused now inplaceofthe "Consumer Commodity ORM-D"marking and both may be displayed concurrently. IATA UN1950 Aerosols,flammable 2.1 2.1 Not applicable. Yes 10L Special precautions foruser Readsafetyinstructions,SDS and emergency procedures before handling.Readsafety instructions, SDS and emergency procedures before handling. Other information Passengerand cargo Allowed. aircraft Cargo aircraft only Allowed. Packaging Exceptions LTD QTY IMDG UN number UN1950 UN proper shipping name AEROSOLS Transport hazard class(es) Class 2.1 Subsidiary risk Label(s)2.1 Product name:64007 SSSALERO 3000WHITE LINEN Product#:1000023633 Version #:02 Revision date:03-27-2015 Issue date:12-05-2014 SDSus 7/10 Packing group Not applicable. Environmental hazards Marine pollutant Yes EmS F-D,S-U Special precautions for user Read safety instructions,SDS and emergency procedures before handling.Read safety instructions,SDS and emergency procedures before handling. Packaging Exceptions LTD QTY Transport in bulk according to Not applicable. Annex II of MARPOL 73/78 and the IBC Code DOT A. FLAMMABLE v GAS y IATA;IMDG Marine pollutant General information IMDG Regulated Marine Pollutant. 15.Regulatory information US federal regulations This productis a "Hazardous Chemical"asdefined by the OSHA Hazard Communication Standard,29 CFR 1910.1200. Allcomponents are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b)Export Notification (40 CFR 707,SubpL D) Not regulated. CERCLA Hazardous Substance List(40 CFR 302.4) Acetone (CAS 67-64-1)Listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Product name:64007 SSSALERO 3000WHITE LINEN Product#:1000023633 Version #:02 Revision date:03-27-2015 Issue date:12-05-2014 SDSUS 8/10 Superfund Amendments and Reauthorization Act of1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - No Fire Hazard -Yes Pressure Hazard -No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous No chemical SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act(CAA)Section 112 Hazardous Air Pollutants (HAPs)List Not regulated. Clean Air Act(CAA)Section 112(r)Accidental Release Prevention (40 CFR 68.130) Isobutane (CAS 75-28-5) Propane (CAS 74-98-6) Safe Drinking Water Act Not regulated. (SDWA) Drug Enforcement Administration (DEA).List 2,Essential Chemicals (21 CFR 1310.02(b)and 1310.04(f)(2)and Chemical Code Number Acetone (CAS 67-64-1)6532 Drug Enforcement Administration (DEA).List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) Acetone (CAS 67-64-1)35 %WV DEA Exempt Chemical Mixtures Code Number Acetone (CAS 67-64-1)6532 US state regulations US.Massachusetts RTK -Substance List Acetone (CAS 67-64-1) Isobutane (CAS 75-28-5) Propane (CAS 74-98-6) US.New Jersey Worker and Community Right-to-KnowAct Acetone (CAS 67-64-1) Isobutane (CAS 75-28-5) Propane (CAS 74-98-6) US.Pennsylvania Worker and Community Right-to-Know Law Acetone (CAS 67-64-1) Isobutane (CAS 75-28-5) Propane (CAS 74-98-6) US.Rhode Island RTK Acetone (CAS 67-64-1) Isobutane (CAS 75-28-5) Propane (CAS 74-98-6) US.California Proposition 65 California Safe DrinkingWater and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s)or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS)Yes Canada DomesticSubstances List (DSL)Yes Canada Non-Domestic Substances List (NDSL)No China Inventory of Existing Chemical Substances in China (IECSC)Yes Europe European Inventory of Existing Commercial Chemical Yes Substances (EINECS) Europe European List of Notified Chemical Substances (ELINCS)No Japan Inventory of Existing and New Chemical Substances (ENCS)Yes Product name:64007 SSS ALERO 3000 WHITE LINEN sdsus Product #:1000023633 Version #:02 Revision date:03-27-2015 Issue date:12-05-2014 9/10 Country(s)or region Inventory name On inventory (yes/no)* Korea Existing Chemicals List (ECL)No New Zealand New Zealand Inventory No Philippines Philippine Inventory of Chemicals and Chemical Substances No (PICCS) United States &Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes *A"Yes"indicates thatall components of this product comply with the inventory requirements administered by the governing country(s) A"No"indicatesthat one or more componentsof the product are not listed or exemptfrom listing on the inventory administered by the governing country(s). 16.Other information,including date of preparation or last revision Issue date 12-05-2014 Revision date 03-27-2015 Version #02 Disclaimer The information provided in this Safety Data Sheet is correctto the best of ourknowledge, information and beliefat the date of its publication.The information given is designed only as a guidance for safe handling,use,processing,storage,transportation,disposal and release and is not to be considered a warranty or quality specification.The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials orin any process,unless specified in the text. Revision Information Product and Company Identification:Product Uses Physical &Chemical Properties:Multiple Properties Transport Information: Material Transportation Information GHS:Classification Product name:64007 SSSALERO 3000WHITE LINEN sosus Product#:1000023633 Version#:02 Revision date:03-27-2015 Issue date:12-05-2014 10/10