HomeMy WebLinkAbout64007 SSS Alero 3000 Metered Dry Air Freshener, White LinenTRIPLE S
1.Identification
Product number
Product identifier
Revision date
Company information
Company phone
Version #
Supersedes date
Recommended use
Recommended restrictions
2.Hazard(s)identification
Physical hazards
Health hazards
Environmental hazards
OSHA defined hazards
Label elements
Signal word
Hazard statement
Precautionary statement
Prevention
Response
Storage
Disposal
Hazard(s)not otherwise
classified (HNOC)
Supplemental information
SAFETY DATA SHEET
64007 (1000023633)
SSS ALERO 3000 METERED DRY AIR FRESHENER,WHITE LINEN
03-06-2015
Triple S
2 Executive Park Drive,
Billerica,MA 01862 United States
General 978-667-7900 /Emergency 888-779-1339
03
03-05-2015
Air Freshener
None known.
Flammable aerosols Category 1
Serious eye damage/eye irritation Category 2A
Specific target organ toxicity,single exposure NQbtegory 3 narcotic effects
classified.
Not classified.
^>
Danger
Extremely flammable aerosol.Causes serious eye irritation.May cause drowsiness or dizziness.
Keep away from heat/sparks/open flames/hot surfaces.- No smoking. Do not sprayon an open
flame or other ignitionsource.Pressurized container: Do not pierce or burn,even after use. Avoid
breathing mistor vapor. Wash thoroughlyafter handling. Use onlyoutdoors or ina well-ventilated
area.Weareye/face protection.
Ifinhaled: Remove person to fresh air and keep comfortable for breathing.Ifin eyes:Rinse
cautiously with waterfor several minutes.Remove contact lenses,ifpresentand easy to do.
Continue rinsing. Calla poison center/doctor ifyou feel unwell. Ifeye irritation persists:Get
medical advice/attention.Collectspillage.
Store in a well-ventilated place. Keep container tightlyclosed.Store locked up.Protectfrom
sunlight. Do not expose to temperatures exceeding 50°C/122°F.
Dispose of contents/container in accordance with local/regional/national/international regulations.
None known.
None.
3.Composition/information on ingredients
Mixtures
Chemical name Common name and synonyms CAS number %
Acetone 67-64-1 40-60
Diethylene Glycol Monoethyl Ether 111-90-0 10-20
Propane 74-98-6 10-20
Product name:64007 SSS ALERO 3000 WHITE LINEN
Product#:1000023633 Version #:02 Revision date:03-27-2015 Issue date:12-05-2014
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Chemical name Common name and synonyms CAS number
Isobutane 75-28-5 2.5-10
Other components below reportable levels 2.5
'Designates that a specific chemical identityand/or percentage of composition has been withheld as a trade secret
10
4.First-aid measures
Inhalation
Skin contact
Eye contact
Ingestion
Most important
symptoms/effects,acute and
delayed
Indication of immediate
medical attention and special
treatment needed
General information
5.Fire-fighting measures
Suitable extinguishing media
Unsuitable extinguishing
media
Specific hazards arising from
the chemical
Special protective equipment
and precautions for firefighters
Fire-fighting
equipment/instructions
Specific methods
General fire hazards
Remove victimto fresh air and keep at rest in a position comfortable for breathing.Call a POISON
CENTER or doctor/physician ifyou feel unwell.
Wash off with soap and water.Get medical attention ifirritation develops and persists.
Immediately flush eyeswith plenty of waterfor at least 15 minutes.Remove contact lenses,if
present and easy to do.Continue rinsing.Ifeye irritation persists:Get medical advice/attention.
In the unlikely eventof swallowing contact a physician or poison control center.Rinse mouth.
May cause drowsiness and dizziness.Headache.Nausea,vomiting. Irritationof nose and throat.
Severe eye irritation.Symptoms may include stinging, tearing,redness,swelling, and blurred
vision.
Provide general supportive measures and treat symptomatically.Keep victim under observation.
Symptoms may be delayed.
Ensure that medical personnel are aware of the material(s)involved,and take precautions to
protectthemselves.
Alcohol resistant foam.Water fog. Dry chemical powder.Carbon dioxide (C02).
Do not use water jet as an extinguisher,as this willspread the fire.
Contents under pressure.Pressurized container may explode when exposed to heat or flame.
Firefighters must use standard protective equipment including flame retardant coat,helmetwith
face shield,gloves,rubber boots,and in enclosed spaces,SCBA.
Move containers from fire area ifyou can do so without risk.Containers should be cooled with
waterto prevent vapor pressure build up. For massive fire in cargo area,use unmanned hose
holder or monitor nozzles,if possible.Ifnot,withdraw and let fire burn out.
Use standard firefighting procedures and considerthe hazards of other involved materials.Move
containers from fire area ifyou can do sowithout risk. In the eventof fire and/or explosion do not
breathe fumes.
Extremely flammable aerosol.
6.Accidental release measures
Personal precautions,
protective equipment and
emergency procedures
Methods and materials for
containmentand cleaning up
Environmental precautions
Keep unnecessary personnel away.Keep people away from and upwind of spill/leak.Keep out of
low areas.Wear appropriate protective equipmentand clothing during clean-up.Avoid breathing
mist or vapor.Do not touch damaged containers or spilled material unlesswearing appropriate
protective clothing.Ventilate closed spaces before entering them.Local authorities should be
advised if significant spillages cannotbe contained.For personal protection,see section 8 of the
SDS.
Referto attached safety data sheets and/or instructions for use.Eliminate all ignition sources (no
smoking,flares,sparks,or flames in immediate area).Keep combustibles (wood,paper,oil,etc.)
awayfrom spilled material.Stop leak ifyou can do so without risk. Move the cylinder to a safe and
open area ifthe leak is irreparable.Use water spray to reduce vapors or divert vapor cloud drift.
Coverwith plastic sheetto prevent spreading.Absorb in vermiculite,dry sand or earth and place
into containers.Prevent entry into waterways,sewer,basements or confined areas.Following
product recovery,flush area with water.
Small Spills:Wipe up with absorbent material (e.g.cloth,fleece).Clean surface thoroughly to
remove residual contamination.Forwaste disposal,see section 13 of the SDS.
Avoid release to the environment.Informappropriate managerial or supervisory personnel of all
environmental releases.Prevent further leakage or spillage ifsafe to do so. Avoid discharge into
drains,watercourses or onto the ground.
Product name:64007 SSSALERO 3000WHITE LINEN
Product#:1000023633 Version #:02 Revision date:03-27-2015 Issue date:12-05-2014
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7.Handling and storage
Precautions for safe handling
Conditions for safe storage,
including any incompatibilities
Pressurized container Do not pierce or burn,even after use.Do not use if spray button is missing
or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke
while using or until sprayed surface is thoroughly dry. Do not cut, weld,solder,drill,grind, or
expose containers to heat,flame,sparks,or othersources of ignition. Allequipment used when
handling the product must be grounded.Do not re-use empty containers.Avoid breathing mist or
vapor.Avoid contact with eyes.Avoid prolonged exposure.Use only in well-ventilated areas.Wear
appropriate personal protective equipment.Avoid release to the environment.Observe good
industrial hygiene practices.
Level 2 Aerosol.
Store locked up.Pressurized container.Protect from sunlight and do not expose to temperatures
exceeding 50°C/122 °F. Do not puncture,incinerate or crush.Do not handle or store near an open
flame,heator othersources of ignition. This material can accumulate static charge which may
cause spark and become an ignition source.Refrigeration recommended.Store away from
incompatible materials (see Section 10 of the SDS).
8.Exposure controls/personal protection
Occupational exposure limits
US.OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components Type
Acetone (CAS 67-64-1)PEL
Propane (CAS 74-98-6)PEL
US.ACGIH Threshold LimitValues
Components Type
Acetone (CAS 67-64-1)STEL
TWA
Isobutane (CAS 75-28-5)STEL
US.NIOSH:Pocket Guide to Chemical Hazards
Components Type
Acetone (CAS 67-64-1)
Isobutane (CAS 75-28-5)
Propane (CAS 74-98-6)
TWA
TWA
TWA
US.Workplace Environmental Exposure Level (WEEL)Guides
Components Type
Value
2400 mg/m3
1000 ppm
1800mg/m3
1000 ppm
Value
750 ppm
500 ppm
1000 ppm
Value
590 mg/m3
250 ppm
1900mg/m3
800 ppm
1800 mg/m3
1000 ppm
Value
Diethylene Glycol
Monoethyl Ether (CAS
111-90-0)
Biological limit values
ACGIH Biological Exposure Indices
Components Value
TWA 140 mg/m3
25 ppm
Determinant Specimen Sampling Time
Acetone (CAS 67-64-1)50 mg/l Acetone Urine *
*- For sampling details,please see the source document
Appropriate engineering Good general ventilation(typically 10 air changes per hour) should be used. Ventilationrates
controls should be matched to conditions.If applicable,use process enclosures,local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limitshave not been established,maintain airborne levels to an acceptable level. Provide
eyewash station.
Individual protection measures,such as personal protective equipment
Eye/face protection Chemical respirator with organic vapor cartridge and fullfacepiece.
Hand protection Wear appropriate chemical resistant gloves.
Product name:64007 SSS ALERO 3000 WHITE LINEN
Product #:1000023633 Version #:02 Revision date:03-27-2015 Issue date:12-05-2014
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Skin protection
Other
Respiratory protection
Thermal hazards
General hygiene
considerations
Wear suitable protective clothing.
Chemical respirator with organic vapor cartridge and fullfacepiece.
Wear appropriate thermal protective clothing,when necessary.
When using do not smoke. Alwaysobserve good personal hygiene measures,such as washing
after handling the material and before eating, drinking,and/or smoking. Routinely wash work
clothing and protective equipment to remove contaminants.
9.Physical and chemical properties
Appearance
Physical state
Form
Color
Odor
Odor threshold
PH
Melting point/freezing point
Initial boiling point and boiling
range
Flash point
Evaporation rate
Flammability (solid,gas)
Upper/lower flammability orexplosive limits
Flammability limit -lower 1.6%estimated
(%)
Flammability limit -upper
(%)
Explosive limit -lower (%)
Explosive limit -upper(%)
Vapor pressure
Vapor density
Relative density
Solubility(ies)
Solubility (water)
Partition coefficient
(n-octanol/water)
Auto-ignition temperature
Decomposition temperature
Viscosity
Other information
Specific gravity
Gas.
Aerosol.
Not available.
Not available.
Notavailable.
Notavailable.
Not available.
132.89 °F (56.05 °C)estimated
-3.8 °F (-19.9 °C)estimated
Not available.
Not available.
14.5%estimated
Not available.
Not available.
270.47 psig @70F estimated
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
0.314 estimated
10.Stability and reactivity
Reactivity
Chemical stability
Possibility of hazardous
reactions
Conditions to avoid
Incompatible materials
Hazardous decomposition
products
The product is stable and non-reactive under normal conditions of use,storage and transport.
Material is stable under normal conditions.
Hazardous polymerization does not occur.
Avoid temperatures exceeding the flash point.Contactwith incompatible materials.
Strong oxidizing agents.Nitrates. Fluorine. Chlorine.
No hazardous decomposition products are known.
Product name:64007 SSSALERO 3000WHITE LINEN
Product#:1000023633 Version #:02 Revision date:03-27-2015 Issue date:12-05-2014
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11.Toxicological information
Information on likely routes of exposure
Ingestion
Inhalation
Skin contact
Eye contact
Symptoms related to the
physical,chemical and
toxicological characteristics
Expected to be a low ingestion hazard.
May cause drowsiness and dizziness.Headache.Nausea,vomiting.Prolonged inhalation may be
harmful.
No adverse effects due to skin contact are expected.
Causes serious eye irritation.
May cause drowsiness and dizziness.Headache.Nausea,vomiting. Irritationof nose and throat.
Severe eye irritation.Symptoms may include stinging, tearing,redness,swelling, and blurred
vision.
Information on toxicological effects
Acutetoxicity Narcotic effects.
Components Species
Acetone (CAS 67-64-1)
Acute
Dermal
LD50 Guinea pig
Rabbit
Inhalation
LC50
Oral
LD50
Rat
Rat
Diethylene Glycol Monoethyl Ether (CAS 111-90-0)
Acute
Dermal
LD50 Guinea pig
Rabbit
Oral
LD50 Guinea pig
Mouse
Rabbit
Rat
Isobutane (CAS 75-28-5)
Acute
Inhalation
LC50 Mouse
Rat
Product name:64007 SSS ALERO 3000 WHITE LINEN
Product #:1000023633 Version #:02 Revision date:03-27-2015 Issue date:12-05-2014
Test Results
>7426 mg/kg,24 Hours
>9.4 ml/kg, 24 Hours
>7426 mg/kg,24 Hours
>9.4 ml/kg,24 Hours
55700 ppm,3 Hours
132mg/l,3 Hours
50.1 mg/l
5800 mg/kg
2.2 ml/kg
5900 mg/kg,Days
8500 mg/kg, 2 Hours
8476 mg/kg,24 Hours
7714 mg/kg
4970 mg/kg
6031 mg/kg
5600 mg/kg
5600 mg/kg
5.4 ml/kg
1237 mg/l,120 Minutes
52%,120 Minutes
1355 mg/l
SDS US
5/10
Components
Propane (CAS 74-98-6)
Acute
Inhalation
LC50
Species
Mouse
Rat
Test Results
1237 mg/l,120 Minutes
52%,120 Minutes
1355 mg/l
658 mg/l/4h
*Estimates for product may be
Skin corrosion/irritation
Serious eye damage/eye
irritation
Respiratory or skin sensitization
Respiratory sensitization
Skin sensitization
Germ cell mutagenicity
Carcinogenicity
OSHA Specifically Regulated
Not listed.
Reproductive toxicity
Specific target organ toxicity -
single exposure
Specific target organ toxicity -
repeated exposure
Aspiration hazard
Chronic effects
12.Ecological information
Ecotoxicity
Components
based on additional component data not shown.
Prolonged skin contactmay cause temporary irritation.
Causes serious eye irritation.
Not available.
This product is not expected to cause skin sensitization.
No data available to indicate productor any components present at greater than 0.1%are
mutagenic or genotoxic.
This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
Substances (29 CFR 1910.1001-1050)
This product is not expected to cause reproductive or developmental effects.
May cause drowsiness and dizziness.
Not classified.
Not available.
Prolonged inhalation may be harmful.
Toxic to aquaticlifewith long lasting effects.
Species
Acetone (CAS 67-64-1)
Aquatic
Crustacea EC50 Water flea (Daphnia magna)
Fish LC50 Rainbow troutdonaldson trout
(Oncorhynchus mykiss)
Diethylene Glycol Monoethyl Ether(CAS 111-90-0)
Aquatic
Fish LC50 Bluegill (Lepomis macrochirus)
Test Results
21.6-23.9 mg/l,48 hours
4740 -6330 mg/l, 96 hours
10000 mg/l, 96 hours
*Estimates for product may be based on additional componentdata not shown.
Persistence and degradability No data is available on thedegradability of this product.
Bioaccumulative potential No data available.
Partition coefficient n-octanol /water (log Kow)
Acetone -0.24
Diethylene Glycol Monoethyl Ether -0.54
Isobutane 2.76
Propane 2.36
Mobility in soil No data available.
Otheradverse effects No other adverse environmental effects (e.g.ozone depletion,photochemical ozone creation
potential,endocrine disruption,global warming potential)are expected from this component.
Product name:64007 SSS ALERO 3000 WHITE LINEN
Product#:1000023633 Version #:02 Revision date:03-27-2015 Issuedate:12-05-2014
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13.Disposal considerations
Disposal instructions Collectand reclaim ordispose insealed containersat licensedwaste disposal site. Contents
under pressure.Donot puncture, incinerate or crush. Donot allowthis materialto drain into
sewers/watersupplies. Donotcontaminate ponds, waterways or ditches withchemical or used
container. Dispose ofcontents/container in accordance with local/regional/national/international
regulations.
Dispose in accordance with all applicable regulations.
The waste code should be assigned indiscussion between the user, the producer and the waste
disposal company.
US RCRA Hazardous Waste U List:Reference
Local disposal regulations
Hazardous waste code
Acetone (CAS 67-64-1)
Waste from residues /unused
products
Contaminated packaging
14.Transport information
DOT
UN number
UN propershipping name
Transport hazard class(es)
Class
Subsidiary risk
Label(s)
Packing group
UN number
UN proper shipping name
Transport hazard class(es)
Class
Subsidiary risk
Label(s)
Packing group
Environmental hazards
ERG Code
U002
Dispose of in accordance withlocal regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of ina safe manner (see:
Disposal instructions).
Emptycontainers should be taken to an approved waste handlingsite for recyclingor disposal.
Since emptied containers may retain product residue,follow labelwarnings even after container is
emptied.Do not re-use empty containers.
UN1950
Aerosols,flammable,(each not exceeding 1 L capacity)
2.1
2.1
Not applicable.
Special precautionsforuser Readsafetyinstructions,SDSand emergency procedures beforehandling.Readsafety
instructions,SDS and emergency procedures before handling.
Special provisions N82
Packaging exceptions 306
Packaging non bulk None
Packaging bulk None
This product meetsthe exception requirements ofsection 173.306 as a limited quantity and maybe shippedas a limited quantity.
Until 12/31/2020,the "ConsumerCommodity -ORM-D"marking may still be used inplace ofthe new limited quantitydiamond
mark for packagesofUN 1950Aerosols.Limited quantities require the limited quantity diamond mark oncartonsafter12/31/20
andmay beused now inplaceofthe "Consumer Commodity ORM-D"marking and both may be displayed concurrently.
IATA
UN1950
Aerosols,flammable
2.1
2.1
Not applicable.
Yes
10L
Special precautions foruser Readsafetyinstructions,SDS and emergency procedures before handling.Readsafety
instructions, SDS and emergency procedures before handling.
Other information
Passengerand cargo Allowed.
aircraft
Cargo aircraft only Allowed.
Packaging Exceptions LTD QTY
IMDG
UN number UN1950
UN proper shipping name AEROSOLS
Transport hazard class(es)
Class 2.1
Subsidiary risk
Label(s)2.1
Product name:64007 SSSALERO 3000WHITE LINEN
Product#:1000023633 Version #:02 Revision date:03-27-2015 Issue date:12-05-2014
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Packing group Not applicable.
Environmental hazards
Marine pollutant Yes
EmS F-D,S-U
Special precautions for user Read safety instructions,SDS and emergency procedures before handling.Read safety
instructions,SDS and emergency procedures before handling.
Packaging Exceptions LTD QTY
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78 and
the IBC Code
DOT
A.
FLAMMABLE
v GAS y
IATA;IMDG
Marine pollutant
General information IMDG Regulated Marine Pollutant.
15.Regulatory information
US federal regulations This productis a "Hazardous Chemical"asdefined by the OSHA Hazard Communication
Standard,29 CFR 1910.1200.
Allcomponents are on the U.S. EPA TSCA Inventory List.
TSCA Section 12(b)Export Notification (40 CFR 707,SubpL D)
Not regulated.
CERCLA Hazardous Substance List(40 CFR 302.4)
Acetone (CAS 67-64-1)Listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Product name:64007 SSSALERO 3000WHITE LINEN
Product#:1000023633 Version #:02 Revision date:03-27-2015 Issue date:12-05-2014
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Superfund Amendments and Reauthorization Act of1986 (SARA)
Hazard categories Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard -Yes
Pressure Hazard -No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous No
chemical
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act(CAA)Section 112 Hazardous Air Pollutants (HAPs)List
Not regulated.
Clean Air Act(CAA)Section 112(r)Accidental Release Prevention (40 CFR 68.130)
Isobutane (CAS 75-28-5)
Propane (CAS 74-98-6)
Safe Drinking Water Act Not regulated.
(SDWA)
Drug Enforcement Administration (DEA).List 2,Essential Chemicals (21 CFR 1310.02(b)and 1310.04(f)(2)and
Chemical Code Number
Acetone (CAS 67-64-1)6532
Drug Enforcement Administration (DEA).List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c))
Acetone (CAS 67-64-1)35 %WV
DEA Exempt Chemical Mixtures Code Number
Acetone (CAS 67-64-1)6532
US state regulations
US.Massachusetts RTK -Substance List
Acetone (CAS 67-64-1)
Isobutane (CAS 75-28-5)
Propane (CAS 74-98-6)
US.New Jersey Worker and Community Right-to-KnowAct
Acetone (CAS 67-64-1)
Isobutane (CAS 75-28-5)
Propane (CAS 74-98-6)
US.Pennsylvania Worker and Community Right-to-Know Law
Acetone (CAS 67-64-1)
Isobutane (CAS 75-28-5)
Propane (CAS 74-98-6)
US.Rhode Island RTK
Acetone (CAS 67-64-1)
Isobutane (CAS 75-28-5)
Propane (CAS 74-98-6)
US.California Proposition 65
California Safe DrinkingWater and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
Country(s)or region Inventory name On inventory (yes/no)*
Australia Australian Inventory of Chemical Substances (AICS)Yes
Canada DomesticSubstances List (DSL)Yes
Canada Non-Domestic Substances List (NDSL)No
China Inventory of Existing Chemical Substances in China (IECSC)Yes
Europe European Inventory of Existing Commercial Chemical Yes
Substances (EINECS)
Europe European List of Notified Chemical Substances (ELINCS)No
Japan Inventory of Existing and New Chemical Substances (ENCS)Yes
Product name:64007 SSS ALERO 3000 WHITE LINEN sdsus
Product #:1000023633 Version #:02 Revision date:03-27-2015 Issue date:12-05-2014 9/10
Country(s)or region Inventory name On inventory (yes/no)*
Korea Existing Chemicals List (ECL)No
New Zealand New Zealand Inventory No
Philippines Philippine Inventory of Chemicals and Chemical Substances No
(PICCS)
United States &Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A"Yes"indicates thatall components of this product comply with the inventory requirements administered by the governing country(s)
A"No"indicatesthat one or more componentsof the product are not listed or exemptfrom listing on the inventory administered by the governing
country(s).
16.Other information,including date of preparation or last revision
Issue date 12-05-2014
Revision date 03-27-2015
Version #02
Disclaimer The information provided in this Safety Data Sheet is correctto the best of ourknowledge,
information and beliefat the date of its publication.The information given is designed only as a
guidance for safe handling,use,processing,storage,transportation,disposal and release and is
not to be considered a warranty or quality specification.The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials orin any process,unless specified in the text.
Revision Information Product and Company Identification:Product Uses
Physical &Chemical Properties:Multiple Properties
Transport Information: Material Transportation Information
GHS:Classification
Product name:64007 SSSALERO 3000WHITE LINEN sosus
Product#:1000023633 Version#:02 Revision date:03-27-2015 Issue date:12-05-2014 10/10